This book aims to rehabilitate kinetic modeling in the domain of
polymer ageing, where it has been almost abandoned by the research
community. Kinetic modeling is a key step for lifetime prediction,
a crucial problem in many industrial domains in which needs cannot
be satisfied by the common empirical methods. This book proposes a
renewed approach of lifetime prediction in polymer oxidative
ageing. This approach is based on kinetic models built from
relatively simple mechanistic schemes but integrating physical
processes (oxygen diffusion and stabilizer transport), and use
property (for instance mechanical failure) changes. An important
chapter is dedicated to radiation-induced oxidation and its most
important applications: radiochemical ageing at low dose rates and
photo-chemical ageing under solar radiation. There is also a
chapter devoted to the problem of ageing under coupled oxidation
and mechanical loading.
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