This volume gives background knowledge about the difficult matter of electrochemical behaviour of glass melts and solid glasses, laying the foundations for- a sound understanding of physicochemical redox and ion transfer processes in solid or liquid glasses and the interpretation of experimental results;- control of production processes, including fining, interface reactions and thermodynamic equilibria of glass melts with refractories and the surrounding atmosphere;- the field-driven ion exchange between solutions and glasses or within electrochromic thin-film systems; - fundamentals and application of glass electrodes for PH measurements, as well as information about the presently ongoing redefinition by a IUPAC committee;- mechanisms responsible for glass corrosion;- the concept of optical basicity.

This volume presents background information on the electrochemical behaviour of glass melts and solid glasses. The text lays the foundations for a sound understanding of physicochemical redox and ion transfer processes in solid or liquid glasses and the interpretation of experimental results. Other topics discussed include: control of production processes, the field-driven ion exchange between solutions and glasses or within electrochromic thin-film systems, mechanisms responsible for glass corrosion, the concept of optical basicity, and others. Throughout, the text contains practical examples enabling readers to study the various aspects of electrochemical processes in ion-conducting materials.