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Physical properties and models of electronic structure are analyzed for a new class of high-TC superconductors which belong to iron-based layered compounds. Despite their variable chemical composition and differences in the crystal structure, these compounds possess similar physical characteristics, due to electron carriers in the FeAs layers and the interaction of these carriers with fluctuations of the magnetic order. A tremendous interest towards these materials is explained by the prospects of their practical use. In this monograph, a full picture of the formation of physical properties of these materials, in the context of existing theory models and electron structure studies, is given. The book is aimed at a broad circle of readers: physicists who study electronic properties of the FeAs compounds, chemists who synthesize them and specialists in the field of electronic structure calculations in solids. It is helpful not only to researchers active in the fields of superconductivity and magnetism, but also for graduate and postgraduate students and all those who would like to get acquaintained with this vivid area of the materials science.
Electronic structure and physical properties of strongly correlated materials containing elements with partially filled 3d, 4d, 4f and 5f electronic shells is analyzed by Dynamical Mean-Field Theory (DMFT). DMFT is the most universal and effective tool used for the theoretical investigation of electronic states with strong correlation effects. In the present book the basics of the method are given and its application to various material classes is shown. The book is aimed at a broad readership: theoretical physicists and experimentalists studying strongly correlated systems. It also serves as a handbook for students and all those who want to be acquainted with fast developing filed of condensed matter physics.
About half a century ago Landau formulated the central principles of the phe nomenological second-order phase transition theory which is based on the idea of spontaneous symmetry breaking at phase transition. By means of this ap proach it has been possible to treat phase transitions of different nature in altogether distinct systems from a unified viewpoint, to embrace the aforemen tioned transitions by a unified body of mathematics and to show that, in a certain sense, physical systems in the vicinity of second-order phase transitions exhibit universal behavior. For several decades the Landau method has been extensively used to an alyze specific phase transitions in systems and has been providing a basis for interpreting experimental data on the behavior of physical characteristics near the phase transition, including the behavior of these characteristics in systems subject to various external effects such as pressure, electric and magnetic fields, deformation, etc. The symmetry aspects of Landau's theory are perhaps most effective in analyzing phase transitions in crystals because the relevant body of mathemat ics for this symmetry, namely, the crystal space group representation, has been worked out in great detail. Since particular phase transitions in crystals often call for a subtle symmetry analysis, the Landau method has been continually refined and developed over the past ten or fifteen years."
This volume analyzes both the theoretical and experimental aspects of neutron spectroscopy of solids, whereby complex crystals may be analyzed in relation to the theories of symmetry and neutron scattering near a structural or magnetic transition.
Handsomely produced monograph provides graduate students and researchers with elegantly lucid accounts of some modern aspects of the topic to which the title refers. The five chapters bear these titles: Statistical mechanics of the Heisenberg ferromagnet; Statistical mechanics of electronic models o
Physical properties and models of electronic structure are analyzed for a new class of high-TC superconductors which belong to iron-based layered compounds. Despite their variable chemical composition and differences in the crystal structure, these compounds possess similar physical characteristics, due to electron carriers in the FeAs layers and the interaction of these carriers with fluctuations of the magnetic order. A tremendous interest towards these materials is explained by the prospects of their practical use. In this monograph, a full picture of the formation of physical properties of these materials, in the context of existing theory models and electron structure studies, is given. The book is aimed at a broad circle of readers: physicists who study electronic properties of the FeAs compounds, chemists who synthesize them and specialists in the field of electronic structure calculations in solids. It is helpful not only to researchers active in the fields of superconductivity and magnetism, but also for graduate and postgraduate students and all those who would like to get acquaintained with this vivid area of the materials science.
Electronic structure and physical properties of strongly correlated materials containing elements with partially filled 3d, 4d, 4f and 5f electronic shells is analyzed by Dynamical Mean-Field Theory (DMFT). DMFT is the most universal and effective tool used for the theoretical investigation of electronic states with strong correlation effects. In the present book the basics of the method are given and its application to various material classes is shown. The book is aimed at a broad readership: theoretical physicists and experimentalists studying strongly correlated systems. It also serves as a handbook for students and all those who want to be acquainted with fast developing filed of condensed matter physics.
The inter action between the magnetic field generated by the neutron and the magnetic moment of atoms containing unpaired electrons was experimentally demonstrated for the first time about twenty years ago. The basic theory describing such an in teraction had already been developed and the first nuclear reactors with large available thermal neutron fluxes had recently been con structed. The power of the magnetic neutron interaction for in vestigating the structure of magnetic materials was immediately recognized and put to use where possible. Neutron diffraction, however, was practicable only in countries with nuclear reactors. The earliest neutron determinations of magnetic ordering were hence primarily carried out at Oak Ridge and Brookhaven in the US, at Chalk River in Canada and at Harwell in England. Diffraction patterns from polycrystalline ferromagnets and antiferromagnets are interpretable if produced by simple spin arrays. More complex magnetic scattering patterns could often be unravelled, in terms of a three-dimensional array of atomic moments, if the specimen studied is a single crystal. The devel opment of sophisticated cryogenic equipment, with independently alignable magnetic fields, opened the way to greater complexity in the magnetic structures that could be successfully determined, as did also the introduction of polarized neutron beams. By the end of the 'sixties, many countries were contributing significantly to neutron diffraction studies of a wide variety of magnetic materials."
About half a century ago Landau formulated the central principles of the phe nomenological second-order phase transition theory which is based on the idea of spontaneous symmetry breaking at phase transition. By means of this ap proach it has been possible to treat phase transitions of different nature in altogether distinct systems from a unified viewpoint, to embrace the aforemen tioned transitions by a unified body of mathematics and to show that, in a certain sense, physical systems in the vicinity of second-order phase transitions exhibit universal behavior. For several decades the Landau method has been extensively used to an alyze specific phase transitions in systems and has been providing a basis for interpreting experimental data on the behavior of physical characteristics near the phase transition, including the behavior of these characteristics in systems subject to various external effects such as pressure, electric and magnetic fields, deformation, etc. The symmetry aspects of Landau's theory are perhaps most effective in analyzing phase transitions in crystals because the relevant body of mathemat ics for this symmetry, namely, the crystal space group representation, has been worked out in great detail. Since particular phase transitions in crystals often call for a subtle symmetry analysis, the Landau method has been continually refined and developed over the past ten or fifteen years."
This book should fill a gap which has existed in the literature on supercon ductivity. There have been a number of excellent textbooks available on the phenomenon of superconductivity, which describe in detail the variety of ef fects connected with it and the mathematical techniques to deal with them properly. However, until now there has not been a textbook available in English which concentrates on the mate ial aspects of superconductivity. This is a major shortcoming since most physicists working in the field of superconduc tivity are mainly concerned with specific materials and subsequently often need to know more about the interplay of superconductivity and material prop erties. On the other hand, people working in the field know that a competent and well-written book by S. V. Vonsovsky, V. A. Izyumov, and E. Z. Kurmaev has been available in Russian. It presents a thorough discussion of superconducting transition-metal alloys and compounds. This volume is a translation of an updated version of the Russian edition. The translation was done by A. P. Zavarnitsyn of the authors' institution and by Dr. E. H. Brandt of the Max-Planck-Institut fur Metallforschung in Stuttgart. The master manuscript was ably typed by Mrs. C. Pendl. I would like to take this opportunity to thank each of them. I sincerely hope that the book will turn out to be useful to physicists working in the field of superconductivity as well as to nonspecialists and interested graduate students."
Cerium is the most abundant of the rare earth elements, making up about 0.0046% of the Earth's crust by weight. It is found in a number of minerals, the most important being monazite and bastnasite. Commercial applications of cerium include catalysts, additives to fuel to reduce emissions and to glass and enamels to change their colour. In this book, the authors study the molecular structure, technological applications and health effects of cerium. Topics include the synthetic and structural features of ceriopolyoxotungstates; cerium-based corrosion inhibitors; tetravalent cerium chemistry; comparative toxicity of cerium and other rare earth elements (REEs) in plant and invertebrate test systems; cerium-based catalysts for the selective catalytic reduction of NOx with NH3; cerium oxide and its reduction in composite materials under hydrogen containing atmosphere; cerium as fertiliser for soils in Russia; and the structure and reactivity of cerium IV complexes with aliphatic organic compounds.
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