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An understanding of statistical thermodynamic molecular theory is fundamental to the appreciation of molecular solutions. This complex subject has been simplified by the authors with down-to-earth presentations of molecular theory. Using the potential distribution theorem (PDT) as the basis, the text provides a discussion of practical theories in conjunction with simulation results. The authors discuss the field in a concise and simple manner, illustrating the text with useful models of solution thermodynamics and numerous exercises. Modern quasi-chemical theories that permit statistical thermodynamic properties to be studied on the basis of electronic structure calculations are given extended development, as is the testing of those theoretical results with ab initio molecular dynamics simulations. The book is intended for students taking up research problems of molecular science in chemistry, chemical engineering, biochemistry, pharmaceutical chemistry, nanotechnology and biotechnology.
'We are a very rich and a very vulnerable Empire, and there are plenty of poor adventurers not very far away who look upon us with hungry eyes.' This is how Prime Minister Neville Chamberlain underlined England's acute imperial predicament in 1938 when he was about to launch his policy of European appeasement. What was the relationship between Empire and appeasement in British foreign policy in the last years of the inter-war peace? How did Britain's exposed overseas interests in the Far East, in the Middle East and in the Mediterranean influence diplomatic policies taken in London at the time of the Rhineland occupation, the Anschluss, the Munich crisis, the Prague coup of March 1939, or the invasion of Poland six months later? How closely was the policy of appeasement tied to the burden of global military weakness, and what was the impact of strategic advice on Cabinet decision-making in the Chamberlain era?
An understanding of statistical thermodynamic molecular theory is fundamental to the appreciation of molecular solutions. This complex subject has been simplified by the authors with down-to-earth presentations of molecular theory. Using the potential distribution theorem (PDT) as the basis, the text provides an up-to-date discussion of practical theories in conjunction with simulation results. The authors discuss the field in a concise and simple manner, illustrating the text with useful models of solution thermodynamics and numerous exercises. Modern quasi-chemical theories that permit statistical thermodynamic properties to be studied on the basis of electronic structure calculations are given extended development, as is the testing of those theoretical results with ab initio molecular dynamics simulations. The book is intended for students taking up research problems of molecular science in chemistry, chemical engineering, biochemistry, pharmaceutical chemistry, nanotechnology and biotechnology.
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