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P-Type Transparent Semiconducting Delafossite CuA102+x Thin Film (Paperback)
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P-Type Transparent Semiconducting Delafossite CuA102+x Thin Film (Paperback)
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Copper based delafossite transparent semiconducting oxide thin
films have recently gained tremendous interest in the field of
optoelectronic technology, after the discovery of p-type
conductivity in a transparent thin film of copper aluminium oxide
(CuAlO2). Most of the well-known and widely used transparent
conducting oxide thin films such as ZnO, SnO2, ITO etc. and their
doped versions are n-type material, but corresponding p-type
transparent conducting oxides were surprisingly missing for a long
time until the fabrication of above-mentioned p-CuAlO2 thin film
have been published (Nature 1997, 389, 939). This has opened up a
new field in opto-electronics device technology, the so-called
"Transparent Electronics", where a combination of the two types of
transparent conducting oxides in the form of a p-n junction could
lead to a 'functional' window, which transmits visible portion of
solar radiation yet generates electricity by the absorption of UV
part of it. Non-stoichiometric and doped versions of various new
types of p-type transparent conducting oxides with improved optical
and electrical properties have been synthesised in the last few
years in this direction. Wide range of deposition techniques have
been adopted to prepare the films. But fabrication of device
quality films by cost-effective deposition techniques such as
sputtering, chemical vapour deposition, wet-chemical dip-coating
technique etc. are the need of the hour for large-scale production
of these films for diverse device applications. Here the authors
have discussed the fabrication and opto-electrical characterisation
of p-CuAlO2+x thin films by cost-effective and scalable deposition
routes such as sputtering and wet-chemical dip-coating technique.
The authors have also discussed briefly some of the new
developments in the field of p-type transparent conducting oxide
thin film technology and an up-to-date and comprehensive
description of different Cu-based p-type transparent conducting
oxide thin films is presented. Also the origin of p-type
conductivity in these transparent oxides has been dealt with
considerable attention. Fabrication of all-transparent junctions is
also discussed which is most important in the development of
'Transparent Electronics'. Field emission properties of thin films
are currently of much interest due to the potential application in
field emission displays (FEDs), which are considered to be strong
candidate for low-power panel applications. The low-threshold field
emission properties of wide-bandgap CuAlO2 thin films have been
investigated for its potential applications in FED technology. The
films showed considerable low turn-on field. This finding might
open up a new direction in the field-emission technology, and a new
group of materials (such as, different transparent conducting
oxides) might become a promising candidate for low-threshold field
emitter. Also, recently, the research on nanostructured materials
generates great interest in the scientific community and offers
tremendous opportunities in the field of science and technology.
Here, the authors have also discussed in brief, the formation of
nanocrystalline p-CuAlO2 films, which may open up an extremely
important and interesting field of research for the fabrication of
all-transparent nano-active devices. This will not only give a new
dimension in the field of 'Transparent Electronics', but new
avenues may open up in the nanoparticle research keeping an eye on
its tremendous applications in optoelectronics technology.
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