Demonstrating through examples, this book presents a mechanism-based perspective on the broad range of deformation and fracture response of solid polymers. It draws on the results of probing experiments and considers the similar mechanical responses of amorphous metals and inorganic compounds to develop advanced methodology for generating more precise forms of modelling. This, in turn, provides a better fundamental understanding of deformation and fracture phenomena in solid polymers. Such mechanism-based constitutive response forms have far-reaching application potential in the prediction of structural responses and in tailoring special microstructures for tough behaviour. Moreover, they can guide the development of computational codes for deformation processing of polymers at any level. Applications are wide-ranging, from large strain industrial deformation texturing to production of precision micro-fluidic devices, making this book of interest to both advanced graduate students and to practising professionals.

Fracture in structural materials remains a vital consideration in engineering systems, affecting the reliability of machines throughout their lives. Impressive advances in both the theoretical understanding of fracture mechanisms and practical developments that offer possibilities of control have re-shaped the subject over the past four decades. The contributors to this volume, including some of the most prominent researchers in the field, give their long-range perspectives of the research on the fracture of solids and its achievements. The subjects covered in this volume include: statistics of brittle fracture, transition of fracture from brittle to ductile, mechanics and mechanisms of ductile separation of heterogenous solids, the crack tip environment in ductile fracture, and mechanisms and mechanics of fatigue. Materials considered range from the usual structural solids to composites. The chapters include both theoretical points of view and discussions of key experiments. Contributors include: from MIT, A.S. Argon, D.M. Parks; from Cambridge, M.F. Ashby; from U.C. Santa Barbara, A.G. Evans, R. McMeeking; from Glasgow, J. Hancock; from Harvard, J.W. Hutchinson, J.R. Rice; from Sheffield, K.J. Miller; from Brown, A. Needleman; from the Ecole des Mines, A. Pineau; from U.C. Berkeley, R. O. Ritchie; and from Copenhagen, V. Tvergaard.