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It is the belief of the editors of this book that the recognition
of block copolymers as being amphiphilic molecules and sharing
common features with other well-studied amphiphiles will prove
beneficial to both the surfactant and the polymer communities. An
aim of this book is to bridge the two communities and
cross-fertilise the different fields. To this end, leading
researchers in the field of amphiphilic block copolymer
self-assembly, some having a background in surfactant chemistry,
and others with polymer physics roots, have agreed to join forces
and contribute to this book.
The book consists of four entities. The first part discusses
theoretical considerations behind the block copolymer self-assembly
in solution and in the melt. The second part provides case studies
of self-assembly in different classes of block copolymers (e.g.,
polyethers, polyelectrolytes) and in different environments (e.g.,
in water, in non-aqueous solvents, or in the absence of solvents).
The third part presents experimental tools, ranging from static
(e.g., small angle neutron scattering) to dynamic (e.g., rheology),
which can prove valuable in the characterization of block copolymer
self-assemblies. The fourth part offers a sampling of current
applications of block copolymers in, e.g., formulations,
pharmaceutics, and separations, applications which are based on the
unique self-assembly properties of block copolymers.
This and its companion Volumes 2 and 3 document the proceed- ings
of the 4th International Symposium on Surfactants in Solution held
in Lund, Sweden, June 27-July 2, 1982. This biennial event was
christened as the 4th Symposium as this was a continuation of ear-
li er conferences dealing with surfactants held in 1976 (Albany)
under the title "Micellization, Solubilization, and
Microemulsions"; in 1978 (Knoxville) under the title "Solution
Chemistry of Surfac- tants"; and in 1980 (Potsdam) where it was
dubbed as "Solution Be- bavior of Surfactants: Theoretical and
Applied Aspects:' The Pl02 3 ceedings of all these symposia have
been properly chronicled. ' , The Lund Symposium was bi lIed as
"Surfactants in Solution" as both the aggregation and adsorption
aspects of surfactants were covered, and furthermore we were
interested in a general title which could be used for future
conferences in this series. As these biennial events bave become a
weIl recognized forum for bringing together researchers with varied
interests in the arena of surfactants, so it is amply vindicated to
continue these, and the next meeting is planned for July 9-13, 1984
in Bordeaux, France under the cochair- manship of K. L. Mittal and
P. Bothorel. The venue for 1986 is still open, although India,
inter alia, is a good possibility. Apropos, we would be delighted
to entertain suggestions regarding where and when these biennial
symposia should be held in the future and you may direct your
response to Kk~.
The renewed and increasing interest in lipid self-assembly, phase
behaviour and interfacial properties can be related to both a much
improved insight in biological systems and the applications of
lipids in food and pharmaceutical industry; in the latter, the
development of drug delivery systems based on lipids has become in
focus. Amphiphilic systems comprise lipids, surfactants as well as
different types of polymers, including block and graft copolymers.
Research on biological amphiphiles has often been conducted
separate from research on synthetic ones. However, in recent years
a very fruitful convergence between the two fields has evolved.
These new perspectives on fundamental research and applications of
lipids are discussed in these proceedings from an international
symposium on "Lipid and Polymer Lipid-systems," October 2000 in
Chia Laguna in Italy - a joint undertaking of Prof. Maura Monduzzi
at Cagliari University, Italy and Camurus Lipid Research
Foundation, Lund, Sweden.
Leading Nordic-Baltic scientists and their colleagues from other
countries present recent research on a broad range of topics in
surface and colloid science: adhesion, adsorption processes,
characterization of solid/liquid and solid/polymer interfaces,
chemical and particle depositions, colloid stability,
emulsification and encapsulation, interfacial reactions, new
surfactants, polymer-surfactant interactions, self-assembly
processes, and functionalized surfaces for bio- and chemosensors.
The papers were presented at the 1st Nordic-Baltic Meeting on
Surface and Colloid Science, which was held in Vilnius, Lithuania
on August 21-25, 1999, as a continuation of the traditional
Scandinavian Symposium on Surface Chemistry.
The increasing interest in NMR spectroscopy of what in some confer
ences in this field is commonly termed "other nuclei" is
unmistakable. Chemists and biologists who employ NMR spectroscopy
to study their problems have, however, been somewhat reluctant to
study nuclei with electric quadrupole moments. These nuclei
frequently give rise to broad NMR signals, sometimes too broad to
be detectable with ordinary high resolution NMR spectrometers.
Spectrometers that could cope with broad NMR signals of low
intensity, "wide-line" spectrometers, have been available since the
mid 1950: s but it appears that most of these instruments ended up
in physical laboratories where the research was primarily directed
towards solid state problems. The study of quadrupolar nuclei can
provide unique and very valuable information on a variety of
physico-chemical and biological systems. For one thing the
relaxation of quadrupolar nuclei is in many ways easier to
interpret than the relaxation of non-quadrupolar nuclei, since the
former is in many cases caused by purely intramolecular
interactions modulated by the molecular motion. Studies of
quadrupolar relaxation have therefore furnished important
information about molec ular reorientation and association in
liquids and have played - and will certainly play for many years -
an important role in testing new theoretical models of molecular
motion in liquids."
Due to the potential benefits of biotechnology, interest in the
interaction between DNA and surfactants and polymers has become
increasingly significant. Now, "DNA Interactions with Polymers and
Surfactants" provides an extensive, up-to-date overview of the
subject, giving readers a basis for understanding the factors
leading to complexation between DNA and different cosolutes,
including metal ions, polyelectrolytes, spermine, spermidine,
surfactants and lipids, and proteins.
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