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This book presents the most comprehensive analysis of bonding in
polyoxometalates and related oxides based on classical bonding
concepts and the bond valence model. Numerous tables and figures
underline and illuminate the results, making it a valuable
resource.
This book presents the fundamentals of bonding in polyoxometalates
and related oxides based on classical bonding concepts and the bond
valence model. The in-depth treatment includes a revision of the
procedure for the determination of the parameters of bond
length-bond valence functions, the application of the bond valence
model to polyoxometalates and related oxides, and the explanation
of the distribution of the bond valences, and hence of the bond
lengths, over the metal-oxygen bond and of the ionic charge on the
oxygen atoms. Numerous tables and figures underline and illuminate
the results. The principal author is a leader in the field of
polyoxometalate chemistry. This work provides for the first time a
comprehensive analysis of the structure and bonding in
polyoxometalates, based on classical chemical concepts and the bond
valence approach, and as such is a valuable resource for chemists,
physicists and material scientists working in the field.
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