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This book provides a comprehensive review of the application of 17O
NMR spectroscopy to organic chemistry. Topics include the
theoretical aspects of chemical shift, quadrupolar and J coupling;
17O enrichment; the effect of steric interactions on 17O chemical
shifts of functional groups in flexible and rigid systems; the
application of 17O NMR spectroscopy to hydrogen bonding
investigations; mechanistic problems in organic and bioorganic
chemistry; and 17O NMR spectroscopy of oxygen monocoordinated to
carbon in alcohols, ethers, and derivatives. Recent results that
show correlations between molecular geometry, determined by X-ray
studies and estimated by molecular mechanics calculations, and 17O
chemical shifts are also covered. 17O Spectroscopy in Organic
Chemistry provides important reference information for organic
chemists and other scientists interested in 17O NMR spectroscopy as
a tool for obtaining new structural and chemical data about organic
molecules.
This book provides a comprehensive review of the application of 17O
NMR spectroscopy to organic chemistry. Topics include the
theoretical aspects of chemical shift, quadrupolar and J coupling;
17O enrichment; the effect of steric interactions on 17O chemical
shifts of functional groups in flexible and rigid systems; the
application of 17O NMR spectroscopy to hydrogen bonding
investigations; mechanistic problems in organic and bioorganic
chemistry; and 17O NMR spectroscopy of oxygen monocoordinated to
carbon in alcohols, ethers, and derivatives. Recent results that
show correlations between molecular geometry, determined by X-ray
studies and estimated by molecular mechanics calculations, and 17O
chemical shifts are also covered. 17O Spectroscopy in Organic
Chemistry provides important reference information for organic
chemists and other scientists interested in 17O NMR spectroscopy as
a tool for obtaining new structural and chemical data about organic
molecules.
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