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The Spanish language and Hispanic culture have left indelible
impressions on the landscape of the southwestern United States. The
role of cultural and geographical influence has had dramatic
effects on the sustainability of the Spanish language and also its
development and change. In a linguistic exploration that delves
into a language as it is spoken by the Hispanic population of New
Mexico and southern Colorado, historical substantiation shows the
condition of New Mexican Spanish and what the future holds for its
speakers. With two major dialect regions, one in the north and one
in the south, detailed maps illustrate the geography of linguistic
variation for the Spanish spoken in the region, whose generations
of speakers were not only influenced by other languages, but also
developed their own variations of words and structure out of need
or innovation.
This diverse language has evolved since its origin in Spain with
influences that include Native American languages, exposure to
English, and Mexican immigration in the twentieth century. Snippets
of New Mexican folklore and folk etymology give voice to that
evolution. Though this work doesn't attempt to save the New Mexican
Spanish language, Bills and Vigil detail the effects of inevitable
encroachment that intensified during the twentieth century and
seriously threaten the continued viability of this unique
dialect.
A comprehensive, in-depth presentation of theoretical underpinnings
and mathematical techniques
This is the first book of its kind to combine all the theories of
molecular reaction dynamics and chemical kinetics in a single
source. It provides a sophisticated treatment of the material that
functions both as a professional reference and a high-level text
for PhD and postdoctoral researchers.
Advanced Molecular Dynamics and Chemical Kinetics offers
exceptional, in-depth coverage and includes a complete discussion
of the theoretical as well as mathematical presentation of
techniques. It features relevant exercises as well as comprehensive
coverage of:
* Second Quantization
* Semiclassical Theory
* Quantum Theory of Reaction Rates
* Feynman Path Integrals
* Wavepacket Propagation and Grid Methods
* Photodissociation
* Molecular Properties of Solvated Molecules
* Quantum Model for Electron Transfer
* Electron Transfer Coupling Elements
* Proton Transfer Reactions in Solution
This is the ideal reference for seasoned professionals in
molecular reaction dynamics as well as for younger researchers who
may want to enter the field or simply wish to learn more about it.
Also available: Introduction to Molecular Dynamics and Chemical
Kinetics
Gert D. Billing and Kurt V. Mikkelsen
The most complete introduction available to molecular dynamics and
the calculation of rate of reaction
This unique textbook provides a unified treatment of molecular
reaction dynamics and chemical kinetics in the gas phase, on
surfaces, and in solution. It goes beyond the standard textbook
topics related to reactions to include concepts from molecular
dynamics calculations as well as methods for treating reactions in
solution.
Featuring a thorough mathematical presentation that fosters
understanding and mastery of all topics covered, Introduction to
Molecular Dynamics and Chemical Kinetics:
* Covers all the basic concepts and practices related to
mathematical model systems used to calculate probability for
chemical reactions
* Provides complete theoretical discussions, including areas of
Kramers' theory and Marcus theory dealing with reactions in
solutions
* Introduces an innovative system of molecular units for molecular
dynamics calculations--provides conventional units as well
* Describes all mathematical derivations necessary for obtaining
formulas
* Uses numerous exercises to clarify both the derivations in the
text and the effects being studied
* Explains how to solve the exercises in its appended "Answers"
section
* Includes special appendices that summarize background
information needed to perform required mathematical calculations
and understand relevant theories
This text is now available as a two-volume set. Volume 1 covers
both molecular reaction dynamics and chemical kinetics, and their
respective theories in a single source. It also includes problems
and solved exercises. Volume 2 concerns molecular reaction dynamics
- the use of mathematical model systems based on statistical
assumptions to calculate the probability of a chemical reaction and
chemical kinetics. It combines all the theories of chemical
kinetics and molecular reaction dynamics into a single location.
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