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From the late-1960's, perfluorosulfonic acid (PFSAs) ionomers have dominated the PEM fuel cell industry as the membrane material of choice. The "gold standard' amongst the many variations that exist today has been, and to a great extent still is, DuPont's Nafion (R) family of materials. However, there is significant concern in the industry that these materials will not meet the cost, performance, and durability requirementsnecessary to drive commercialization in key market segments - es- cially automotive. Indeed, Honda has already put fuel cell vehicles in the hands of real end users that have home-grown fuel cell stack technology incorporating hydrocarbon-based ionomers. "Polymer Membranes in Fuel Cells" takes an in-depth look at the new chem- tries and membrane technologies that have been developed over the years to address the concerns associated with the materials currently in use. Unlike the PFSAs, which were originally developed for the chlor-alkali industry, the more recent hydrocarbon and composite materials have been developed to meet the specific requirements of PEM Fuel Cells. Having said this, most of the work has been based on derivatives of known polymers, such as poly(ether-ether ketones), to ensure that the critical requirement of low cost is met. More aggressive operational requi- ments have also spurred the development on new materials; for example, the need for operation at higher temperature under low relative humidity has spawned the creation of a plethora of new polymers with potential application in PEM Fuel Cells.
From the late-1960's, perfluorosulfonic acid (PFSAs) ionomers have dominated the PEM fuel cell industry as the membrane material of choice. The "gold standard' amongst the many variations that exist today has been, and to a great extent still is, DuPont's Nafion (R) family of materials. However, there is significant concern in the industry that these materials will not meet the cost, performance, and durability requirementsnecessary to drive commercialization in key market segments - es- cially automotive. Indeed, Honda has already put fuel cell vehicles in the hands of real end users that have home-grown fuel cell stack technology incorporating hydrocarbon-based ionomers. "Polymer Membranes in Fuel Cells" takes an in-depth look at the new chem- tries and membrane technologies that have been developed over the years to address the concerns associated with the materials currently in use. Unlike the PFSAs, which were originally developed for the chlor-alkali industry, the more recent hydrocarbon and composite materials have been developed to meet the specific requirements of PEM Fuel Cells. Having said this, most of the work has been based on derivatives of known polymers, such as poly(ether-ether ketones), to ensure that the critical requirement of low cost is met. More aggressive operational requi- ments have also spurred the development on new materials; for example, the need for operation at higher temperature under low relative humidity has spawned the creation of a plethora of new polymers with potential application in PEM Fuel Cells.
Reverse Osmosis Systems: Design, Optimization and Troubleshooting Guide describes in depth knowledge of designing and operating reverse osmosis (RO) systems for water desalination, and covers issues which will effect the probability for the long-standing success of the application. It also provides guidelines that will increase the performance of seawater RO desalination systems by avoiding errors in the design and operation and suggest corrective measures and troubleshooting of the problems encountered during RO operation. This book also provides guidelines for the best RO design and operational performance. In the introductory section, the book covers the history of RO along with the fundamentals, principles, transport models, and equations. Following sections cover the practical areas such as pretreatment processes, design parameters, design software programs (WAVE, IMSDesign, TORAYDS2, Lewaplus, ROAM Ver. 2.0, Winflows etc.), RO performance monitoring, normalization software programs (RODataXL and TorayTrak), troubleshooting as well as system engineering. Simplified methods to use the design software programs are also properly illustrated and the screenshots of the results, methods etc. are also given here along with a video tutorial.The final section of the book includes the frequently asked questions along with their answers. Moreover, various case studies carried out and recent developments related to RO system performance, membrane fouling, scaling, and degradation studies have been analyzed. The book also has several work out examples, which are detailed in a careful as well as simple manner that help the reader to understand and follow it properly. The information presented in some of the case studies are obtained from existing commercial RO desalination plants. These topics enable the book to become a perfect tool for engineers and plant operators/technicians, who are responsible for RO system design, operation, maintenance, and troubleshooting. With the right system design, proper operation, and maintenance program, the RO system can offer high purity water for several years.
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