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The development and the study of both ionic and electronically
conducting polymers have been. in the past few years. areas of*
increasing interest. These new materials are. in fact. being
considered for many technological applications. namely low weight.
high energy density batteries and sensors. This volume contains the
proceedings of a workshop on this subject. sponsored by the U.S.
Army Research. Development and Standardization Group (U.K.). which
took place in Sintra - Portugal from July 27 to July 31. 1986. The
workshop. which included lectures. communications and discussion
panels. was very sucessfull and the combination of ionic with
electronically conducting polymers and their applications. not
usually together in workshops or conferences. proved to be an
excellent idea. Lisbon December. 1986 Luis Alcacer ix THE
ELECTROCHEMISTRY OF ELECTRONICALLY CONDUCTING POLYMERS J. O'M.
Bockris and David Miller Department of Chemistry Texas A&M
University College Station, Texas 77843 USA ABSTRACT. The new field
of the electrochemistry of electronically conducting polymers is
reviewed. A brief historical account traces the beginning of
organic electrodes to Ka11mann and Pope, who, in 1960, observed
charge injection and conductance in anthracene electrodes.
The development and the study of both ionic and electronically
conducting polymers have been. in the past few years. areas of.
increasing interest. These new materials are. in fact. being
considered for many technological applications. namely low weight.
high energy density batteries and sensors. This volume contains the
proceedings of a workshop on this subject. sponsored by the U.S.
Army Research. Development and Standardization Group (U.K.). which
took place in Sintra - Portugal from July 27 to July 31. 1986. The
workshop. which included lectures. communications and discussion
panels. was very sucessfull and the combination of ionic with
electronically conducting polymers and their applications. not
usually together in workshops or conferences. proved to be an
excellent idea. Lisbon December. 1986 Luis Alcacer ix THE
ELECTROCHEMISTRY OF ELECTRONICALLY CONDUCTING POLYMERS J. O'M.
Bockris and David Miller Department of Chemistry Texas A&M
University College Station, Texas 77843 USA ABSTRACT. The new field
of the electrochemistry of electronically conducting polymers is
reviewed. A brief historical account traces the beginning of
organic electrodes to Ka11mann and Pope, who, in 1960, observed
charge injection and conductance in anthracene electrodes."
Written in the perspective of an experimental chemist, this book
puts together some fundamentals from chemistry, solid state physics
and quantum chemistry, to help with understanding and predicting
the electronic and optical properties of organic semiconductors,
both polymers and small molecules. The text is intended to assist
graduate students and researchers in the field of organic
electronics to use theory to design more efficient materials for
organic electronic devices such as organic solar cells, light
emitting diodes and field effect transistors. After addressing some
basic topics in solid state physics, a comprehensive introduction
to molecular orbitals and band theory leads to a description of
computational methods based on Hartree-Fock and density functional
theory (DFT), for predicting geometry conformations, frontier
levels and energy band structures. Topological defects and
transport and optical properties are then addressed, and one of the
most commonly used transparent conducting polymers, PEDOT:PSS, is
described in some detail as a case study.
Written in the perspective of an experimental chemist, this book
puts together some fundamentals from chemistry, solid state physics
and quantum chemistry, to help with understanding and predicting
the electronic and optical properties of organic semiconductors,
both polymers and small molecules. The text is intended to assist
graduate students and researchers in the field of organic
electronics to use theory to design more efficient materials for
organic electronic devices such as organic solar cells, light
emitting diodes and field effect transistors. After addressing some
basic topics in solid state physics, a comprehensive introduction
to molecular orbitals and band theory leads to a description of
computational methods based on Hartree-Fock and density functional
theory (DFT), for predicting geometry conformations, frontier
levels and energy band structures. Topological defects and
transport and optical properties are then addressed, and one of the
most commonly used transparent conducting polymers, PEDOT:PSS, is
described in some detail as a case study.
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