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This volume is prepared from lecture notes for the course
"Intercalation in Layered Materials" which was held at the Ettore
Majorana Centre for Scientific Culture at Erice, Sicily in July,
1986, as part of the International School of Materials Science and
Tech nology. The course itself consisted of formal tutorial
lectures, workshops, and informal discussions. Lecture notes were
prepared for the formal lectures, and short summaries of many of
the workshop presentations were prepared. This volume is based on
these lecture notes and research summaries. The material is
addressed to advanced graduate students and postdoctoral
researchers and assumes a background in basic solid state physics.
The goals of this volume on Intercalation in Layered Materials
include an introduc tion to the field for potential new
participants, an in-depth and broad exposure for stu dents and
young investigators already working in the field, a basis for
cross-fertilization between workers on various layered host
materials and with various intercalants, and an elaboration of the
complementarity of intercalated layered materials with deliberately
structured superlattices."
Carbon has always been a unique and intriguing material from a
funda mental standpoint and, at the same time, a material with many
technological uses. Carbon-based materials, diamond, graphite and
their many deriva tives, have attracted much attention in recent
years for many reasons. Ion implantation, which has proven to be
most useful in modifying the near surface properties of many kinds
of materials, in particular semiconductors, has also been applied
to carbon-based materials. This has yielded, mainly in the last
decade, many scientifically interesting and technologically impor
tant results. Reports on these studies have been published in a
wide variety of journals and topical conferences, which often have
little disciplinary overlap, and which often address very different
audiences. The need for a review to cover in an integrated way the
various diverse aspects of the field has become increasingly
obvious. Such a review should allow the reader to get an overview
of the research that has been done thus far, to gain an ap
preciation of the common features in the response of the various
carbon to ion impact, and to become aware of current research oppor
allotropes tunities and unresolved questions waiting to be
addressed. Realizing this, and having ourselves both contributed to
the field, we decided to write a review paper summarizing the
experimental and theoretical status of ion implantation into
diamond, graphite and related materials."
The research on graphite intercalation compounds often acts as a
forerunner for research in other sciences. For instance, the
concept of staging, which is fundamental to graphite intercalation
compounds, is also relevant to surface science in connection with
adsorbates on metal surfaces and to high-temperature
superconducting oxide layer materials. Phonon-folding and
mode-splitting effects are not only basic to graphite intercalation
compounds but also to polytypical systems such as supercon ductors,
superlattices, and metal and semiconductor superlattices. Charge
transfer effects playa tremendously important role in many areas,
and they can be most easily and fundamentally studied with
intercalated graphite. This list could be augmented with many more
examples. The important message, however, is that graphite inter
calation compounds represent a class of materials that not only can
be used for testing a variety of condensed-matter concepts, but
also stimulates new ideas and approaches. This volume is the second
of a two-volume set. The first volume addressed the structural and
dynamical aspects of graphite intercalation compounds, together
with the chemistry and intercalation of new compounds. This second
volume provides an up-to-date status report from expert researchers
on the transport, magnetic, elec tronic and optical properties
ofthis unique class of materials. The band-structure cal culations
of the various donor and acceptor compounds are discussed in depth,
and detailed reviews are provided ofthe experimental verification
ofthe electronic struc ture in terms of their photoemission spectra
and optical properties."
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