Nanoscale electrochemistry has revolutionized electrochemical research and technologies and has made broad impacts in other fields, including nanotechnology and nanoscience, biology, and materials chemistry. Nanoelectrochemistry examines well-established concepts and principles and provides an updated overview of the field and its applications. This book covers three integral aspects of nanoelectrochemistry. The first two chapters contain theoretical background, which is essential for everyone working in the field-specifically, theories of electron transfer, transport, and double-layer processes at nanoscale electrochemical interfaces. The next chapters are dedicated to the electrochemical studies of nanomaterials and nanosystems, as well as the development and applications of nanoelectrochemical techniques. Each chapter is self-contained and can be read independently to provide readers with a compact, up-to-date critical review of the subfield of interest. At the same time, the presented collection of chapters serves as a serious introduction to nanoelectrochemistry for graduate students or scientists who wish to enter this emerging field. The applications discussed range from studies of biological systems to nanoparticles and from electrocatalysis to molecular electronics, nanopores, and membranes. The book demonstrates how electrochemistry has contributed to the advancement of nanotechnology and nanoscience. It also explores how electrochemistry has transformed itself by leading to the discovery of new phenomena, enabling unprecedented electrochemical measurements and creating novel electrochemical systems.

Because of its simplicity of use and quantitative results, Scanning Electrochemical Microscopy (SECM) has become an indispensable tool for the study of surface reactivity. The fast expansion of the SECM field over several years has been fueled by the introduction of new probes, commercially available instrumentation, and new practical applications. Scanning Electrochemical Microscopy, Third Edition offers essential background and in-depth overviews of specific applications in self-contained chapters. The vitality and growing popularity of SECM over the past 30+ years have largely been determined by its versatility and capability to remain useful in the changing scientific and technological environments. New applications reported during the last decade reflect significant current activity in biomedical and energy-related research. This thoroughly updated edition provides up-to-date comprehensive reviews of different aspects of SECM. New chapters by renowned professionals in the field cover recent advances in different areas of SECM including nanoSECM, surface reactions and films, batteries, and fuel cells. Expanded coverage of electrocatalysis and surface interrogation as well as photoelectrochemistry and photoelectrocatalysis are also provided. Useful for a broad range of interdisciplinary research-from biological systems to nanopatterning-this book is invaluable to all interested in learning and applying SECM.

Nanoscale electrochemistry has revolutionized electrochemical research and technologies and has made broad impacts in other fields, including nanotechnology and nanoscience, biology, and materials chemistry. Nanoelectrochemistry examines well-established concepts and principles and provides an updated overview of the field and its applications. This book covers three integral aspects of nanoelectrochemistry. The first two chapters contain theoretical background, which is essential for everyone working in the field-specifically, theories of electron transfer, transport, and double-layer processes at nanoscale electrochemical interfaces. The next chapters are dedicated to the electrochemical studies of nanomaterials and nanosystems, as well as the development and applications of nanoelectrochemical techniques. Each chapter is self-contained and can be read independently to provide readers with a compact, up-to-date critical review of the subfield of interest. At the same time, the presented collection of chapters serves as a serious introduction to nanoelectrochemistry for graduate students or scientists who wish to enter this emerging field. The applications discussed range from studies of biological systems to nanoparticles and from electrocatalysis to molecular electronics, nanopores, and membranes. The book demonstrates how electrochemistry has contributed to the advancement of nanotechnology and nanoscience. It also explores how electrochemistry has transformed itself by leading to the discovery of new phenomena, enabling unprecedented electrochemical measurements and creating novel electrochemical systems.