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Immobilisation of high level toxic wastes by vitrification is a
well established process that has been studied extensively over
last 40 years. A suitable glass host is used to dissolve the high
level nuclear waste to form a glassy (vitreous) homogeneous product
that can be cast into suitable forms, including large glass blocks.
The main advantages of the vitrification route include the fact
glass is a good solvent for waste, glasses can be processed at
reasonably low temperatures, glass is very tolerant of variations
in waste composition, glass exhibits reasonable chemical
durability, glass is radiation resistant and can accommodate
changes occurring during decay of high level nuclear waste
constituents. This book analyses the immobilisation of high level
toxic wastes through the use of an appropriate glass host.
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