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The research of unitary concepts in solid state and molecular
chemistry is of current interest for both chemist and physicist
communities. It is clear that due to their relative simplicity, low
dimensional materials have attracted most of the attention. Thus,
many non-trivial problems were solved in chain systems, giving some
insight into the behavior of real systems which would otherwise be
untractable. The NATO Advanced Research Workshop on "Organic and
Inorganic Low-Dimensional Crystalline Materials" was organized to
review the most striking electronic properties exhibited by organic
and inorganic sytems whose space dimensionality ranges from zero
(Od) to one (1d), and to discuss related scientific and
technological potentials. The initial objectives of this Workshop
were, respectively: i) To research unitary concepts in solid state
physics, in particular for one dimensional compounds, ii) To
reinforce, through a close coupling between theory and experiment,
the interplay between organic and inorganic chemistry, on the one
hand, and solid state physics on the other, iii) To get a salient
understanding of new low-dimensional materials showing "exotic"
physical properties, in conjunction with structural features."
This book considers advanced composite materials based on carbon fibers and several kinds of matrices and is divided into three main parts. The first presents an alternative way to process and prepare carbon fibers issued from either natural or artificial precursors. Recent achievements in carbon fiber technologies are introduced, including their main physical characteristics as high modulus or high strength type. In the second part both classical and novel ways to prepare carbon matrices are presented. The chemical vapor deposition (CVD) technique as well as chemical vapor infiltration (CVI) inside a porous preform are analysed. In addition, the liquid impregnation of a preform by a pitch or some other precursor is described. The associated C-C composites exhibit high thermal and mechanical properties, useful, for example, in aeroplane brakes and space rockets. Finally, other carbon based composites, with polymers or cement as matrices are explained including the role of interfacial characteristics as wetting or adhesions for their final application. This book will be of interest to engineers, graduate students and researchers in the field of solid state physics, chemistry and materials science. eBook available with sample pages: 0203166787
Humans first used carbon as chars from firewood in ritual paintings
and primitive metallurgical processes. Natural forms of carbon have
been known since antiquity, yet the knowledge of the carbon element
in chemistry and its technical applications on a larger scale are a
relatively recent development. The industrial revolution in Europe
two centuries ago led the way to the numerous applications of these
graphitic forms that are still used today. Graphite and Precursors
features short tutorial articles on different topics related to the
science and technology of carbons intended for engineers, students
of Materials Science and scientists who are seeking a fundamental
understanding without "reinventing the wheel." This first volume of
the World of Carbon book series focuses on graphite and its
precursors, including its origin and various implications. The
basic properties of hexagonal graphite are developed, and several
theoretical and experimental approaches explain why this
crystalline solid is fascinating in solid state physics. Also
featured are the numerous applications connected to thermal,
mechanical and chemical graphites, as well as their various
industrial uses in polycrystalline form. Finally, carbon precursors
are introduced.
Molecular Magnetism: From Molecular Assemblies to the Devices
reviews the state of the art in the area. It is organized in two
parts, the first of which introduces the basic concepts, theories
and physical techniques required for the investigation of the
magnetic molecular materials, comparing them with those used in the
study of classical magnetic materials. Here the reader will find:
(i) a detailed discussion of the electronic processes involved in
the magnetic interaction mechanisms of molecular systems, including
electron delocalization and spin polarization effects; (ii) a
presentation of the available theoretical models based on spin and
Hubbard Hamiltonians; and (iii) a description of the specific
physical investigative techniques used to characterize the
materials. The second part presents the different classes of
existing magnetic molecular materials, focusing on the possible
synthetic strategies developed to date to assemble the molecular
building blocks ranging from purely organic to inorganic materials,
as well as on their physical properties and potential applications.
These materials comprise inorganic and organic ferro- and
ferrimagnets, high nuclearity organic molecules and magnetic and
metallic clusters, spin crossover systems, charge transfer salts
(including fulleride salts and organic conductors and
superconductors), and organized soft media (magnetic liquid
crystals and Langmuir-Blodgett films).
Humans first used carbon as chars from firewood in ritual paintings
and primitive metallurgical processes. Natural forms of carbon have
been known since antiquity, yet the knowledge of the carbon element
in chemistry and its technical applications on a larger scale are a
relatively recent development. The industrial revolution in Europe
two centuries ago led the way to the numerous applications of these
graphitic forms that are still used today. Graphite and Precursors
features short tutorial articles on different topics related to the
science and technology of carbons intended for engineers, students
of Materials Science and scientists who are seeking a fundamental
understanding without "reinventing the wheel." This first volume of
the World of Carbon book series focuses on graphite and its
precursors, including its origin and various implications. The
basic properties of hexagonal graphite are developed, and several
theoretical and experimental approaches explain why this
crystalline solid is fascinating in solid state physics. Also
featured are the numerous applications connected to thermal,
mechanical and chemical graphites, as well as their various
industrial uses in polycrystalline form. Finally, carbon precursors
are introduced.
The research of unitary concepts in solid state and molecular
chemistry is of current interest for both chemist and physicist
communities. It is clear that due to their relative simplicity, low
dimensional materials have attracted most of the attention. Thus,
many non-trivial problems were solved in chain systems, giving some
insight into the behavior of real systems which would otherwise be
untractable. The NATO Advanced Research Workshop on "Organic and
Inorganic Low-Dimensional Crystalline Materials" was organized to
review the most striking electronic properties exhibited by organic
and inorganic sytems whose space dimensionality ranges from zero
(Od) to one (1d), and to discuss related scientific and
technological potentials. The initial objectives of this Workshop
were, respectively: i) To research unitary concepts in solid state
physics, in particular for one dimensional compounds, ii) To
reinforce, through a close coupling between theory and experiment,
the interplay between organic and inorganic chemistry, on the one
hand, and solid state physics on the other, iii) To get a salient
understanding of new low-dimensional materials showing "exotic"
physical properties, in conjunction with structural features.
Molecular Magnetism: From Molecular Assemblies to the Devices
reviews the state of the art in the area. It is organized in two
parts, the first of which introduces the basic concepts, theories
and physical techniques required for the investigation of the
magnetic molecular materials, comparing them with those used in the
study of classical magnetic materials. Here the reader will find:
(i) a detailed discussion of the electronic processes involved in
the magnetic interaction mechanisms of molecular systems, including
electron delocalization and spin polarization effects; (ii) a
presentation of the available theoretical models based on spin and
Hubbard Hamiltonians; and (iii) a description of the specific
physical investigative techniques used to characterize the
materials. The second part presents the different classes of
existing magnetic molecular materials, focusing on the possible
synthetic strategies developed to date to assemble the molecular
building blocks ranging from purely organic to inorganic materials,
as well as on their physical properties and potential applications.
These materials comprise inorganic and organic ferro- and
ferrimagnets, high nuclearity organic molecules and magnetic and
metallic clusters, spin crossover systems, charge transfer salts
(including fulleride salts and organic conductors and
superconductors), and organized soft media (magnetic liquid
crystals and Langmuir-Blodgett films).
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