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This volume is the latest of the "Kirchberg-Proceedings". The
previous 11 International Winterschools on Electronic Properties of
Novel Materials, all held in Kirchberg, Austria, were devoted to
conducting polymers, high temperature superconductors, fullerenes,
and carbon nanotubes. Fullerenes and nanotubes are still in the
center of interest, but the topic of the school and the proceedings
is molecular nanostructures in general. The organizers have
attempted to treat carbon nanostructures as a special case of
molecular nanostructures, which also include silicon clusters, gold
clusters, vanadium oxide tubes, and many others. The Winterschool
provides a platform for reviewing and discussing new developments
in the field of molecular nanostructures and their applications.
Materials discussed include fullerenes, fullerene-derived
structures, carbonaceous nanotubes, non-carbonaceous nanotubes,
layer by layer systems, molecular clusters, new phases of carbon,
endohedral compounds and related materials. The book aims to give
an overview of the current status of fullerenes, carbon-nanotubes
and related molecular nanostructures. The majority of the
contributions present the latest results of experiments and
calculations conducted in the field. However, about a dozen contain
some degree of instructional material which even newcomers will
benefit from.
This volume contains the proceedings of the NATO Advanced Research
Workshop on "Atomic and Molecular Wires". It was sponsored by the
Ministry of Scientific Affairs Division special program on
Nanoscale Science with the support of the CNRS and the Max Planck
Institute. Scientists working or interested in the properties of
wires at a subnanoscale were brought together in Les Houches
(France) from 6 to 10 May 1996. Subnanoscale wires can be
fabricated either by surface physicists (atomic wires) or by
synthetic chemists (molecular wires). Both communities present
their foremost advances using, for example, STM to assemble atomic
lines atom for atom, to fabricate a mask for such a line or using
the wide range of chemical synthesis techniques to obtain long,
rigid and conjugated oligomers. Interconnecting such tiny wires to
sources (voltage, current) continues to demand a great
technological effort. But nanolithography associated with
microfabrication or STM are now clearly identified paths for
measuring the electrical resistance of an atomic or a molecular
wire. The first measurements have been reported on Xe , benzene, C
' di(phenylene-ethynylene) showing 2 60 the need for a deeper
understanding of transport phenomena through subnanowires. Such
transport phenomena like tunnel (off-resonance) transport and
Coulomb blockade have been discussed by theorists with an emphasis
on the exponential decrease of the tunnel current with the wire
length versus the ballistic regime of transport.
The International Winter School on Electronic Properties of
Conjugated Polymers held March 14-21,1987, in Kirchberg (Austria)
was a sequel to a meeting held in Kirchberg two years before on a
similar subject. The 1987 winter school was organized in
cooperation with the "Bundesministerium fiir Wissenschaft und
Forschung" in Austria and the "Bundesministerium fiir Forschung und
Technologie" in the Federal Republic of Germany. The basic idea of
the meeting was to provide an opportunity for experienced
scientists from universities and industry to discuss their most
recent re- sults and for students and young scientists to inform
themselves about the present state of the research in this field.
As in 1985, the scientific interest was concentrated on the
electronic structure of various conjugated polymers and related
compounds. The focus of interest in the field now appears to have
broadened and cov- ers not only conductivity and relaxation
phenomena of polyacetylene but also nonlinear optical properties,
highly oriented and single-crystal poly- mers, and electrochemical
and opto-electrochemical properties of special materials such as
polypyrrole and polyaniline. Exciting results on conduc- tivity -
the mass specific conductivity (i.e., the conductivity divided by
the density) of polyacetylene is more than twice that of copper (!)
- and a detailed interpretation of the meaning of conjugation
length are reported.
This volume contains the proceedings of the NATO Advanced Research
Workshop on "Atomic and Molecular Wires". It was sponsored by the
Ministry of Scientific Affairs Division special program on
Nanoscale Science with the support of the CNRS and the Max Planck
Institute. Scientists working or interested in the properties of
wires at a subnanoscale were brought together in Les Houches
(France) from 6 to 10 May 1996. Subnanoscale wires can be
fabricated either by surface physicists (atomic wires) or by
synthetic chemists (molecular wires). Both communities present
their foremost advances using, for example, STM to assemble atomic
lines atom for atom, to fabricate a mask for such a line or using
the wide range of chemical synthesis techniques to obtain long,
rigid and conjugated oligomers. Interconnecting such tiny wires to
sources (voltage, current) continues to demand a great
technological effort. But nanolithography associated with
microfabrication or STM are now clearly identified paths for
measuring the electrical resistance of an atomic or a molecular
wire. The first measurements have been reported on Xe , benzene, C
' di(phenylene-ethynylene) showing 2 60 the need for a deeper
understanding of transport phenomena through subnanowires. Such
transport phenomena like tunnel (off-resonance) transport and
Coulomb blockade have been discussed by theorists with an emphasis
on the exponential decrease of the tunnel current with the wire
length versus the ballistic regime of transport.
Electronic Properties of Fullerenes and other Novel Materials gives
an overview of the state-of-the-art research. It presents most
recent results on preparation, experimental analysis by electron
spectroscopy, infrared and Raman spectroscopy, luminescence, and
nonlinear optical, as well as possible technological applications.
Emphasis is also placed on the superconducting properties of
Fullerenes. The introductory and advanced contributions provide a
good survey of the current status of this rapidly developing field.
The International Winter School on Electronic Properties of
Polymers and Re- lated Compounds, held March 11-18, 1989, in
Kirchberg (Austria), was a sequel to two meetings on similar
subjects held there two and four years be- fore. The 1989 winter
school was again organized in cooperation with the
"Bundesministerium flir Wissenschaft und Forschung" in Austria, and
with the "Bundesministerium fUr Forschung und Technologie" in the
Federal Republic of Germany. The basic idea of the meeting was to
provide an opportunity for experienced scientists from universities
and industry to discuss their most recent results and for students
and young scientists to become familiar with the present status of
research and applications in the field. Like the previous winter
schools, this one concentrated on the electronic structure and
application potentialities of polymers. A purely tutorial contribu-
tion on high-temperature supercondutors was included. Special
attention was paid this time to our present theoretical
understanding of the electronic struc- ture of polymers in general,
the role of disorder and the nature of the doping process in
particular. Accordingly, two discussion meetings were held on the
stability of quasiparticles in conjugated polymers and on the
thermochromic phase transition in alkylated thiophenes. As a
general result, disorder and con- jugation length were recognized
as fundamental properties, not only for the stability of the
quasiparticles but also for linear and nonlinear optics, transport,
phototransport, magnetic properties, lattice dynamics, etc.
The International Winter School on Electronic Properties of
Polymers Orien tation and Dimensionality of Conjugated Systems,
held March 9-16, 1991, in Kirchberg, ('lYrol) Austria, was a sequel
to three meetings on similar subjects held there. The 1991 winter
school was again organized in cooperation with the
"Bundesministerium fUr Wissenschaft und Forschung" in Austria, and
with the "Bundesministerium fUr Forschung und Technologie" in the
Federal Republic of Germany. The basic idea of the meeting was to
provide an opportunity for experienced scientists from universities
and industry to discuss their most re cent results and for students
and young scientists to become familiar with the present status of
research and applications in the field. Like the previous winter
schools on polymers, this one concentrated on the electronic
structure and potential for application of polymers with conjugated
double bonds. This time, however, special attention was paid to the
effects of orientation and dimensionality. Anisotropy of the
electric conductivity in stretch-oriented samples and whether the
transport mechanisms are one-, two-, or three-dimensional or might
even have a "fractal dimensionality" were there fore central
topics. The problem of orientation was extended to systems such as
Langmuir-Blodgett films and other layered structures. Accordingly,
thin films were the focus of most of the application oriented
contributions. Whereas in the previous winter schools discussions
on applications dealt with "large volume applications" such as
electromagnetic shielding and energy storage, this time "molecular
materials for electronics" and prospects of "molecular electronics"
were at the center of interest."
At the International Winter School on "Electronic Properties of
Polymers and Related Compounds" particular attention was paid to a
very new and special field in polymer research. It is concerned
with the study of the electronic structure of polymers and with
physical and chemical properties directly re lated to this
structure. In particular, tutorial and research contributions on
electrical, electrochemical, optical, magnetic, lattice dynamical
and structural properties were presented. In addition, review
reports on related topics such as charge transfer complexes and
linear-chain compounds (transi tion-metal trichalcogenides) were
included. In two discussion meEjtings, the special role of
polyacetylene and possible present and future applications of the
electronic properties of polymers, as e.g. conductors or as
electrodes in electrochemical cells, were elucidated. The
electronic properties of polymers cover a wide range of research
problems which are of particular interest for polymers with a
1T-electron system. Thus, a great part of the work presented was
concerned with conjuga ted systems. Additional presentations dealt
with other systems such as bio polymers, photopolymers or
electrets, which are of significant scientific and technical
importance. It was demonstrated how their electronic proper ties
are increasingly being investigated from a fundamental point of
view by applying known concepts of snlid-state science."
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