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++++ The below data was compiled from various identification fields
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++++ The Significance Of Changing Atomic Volume, Parts 1-4; The
Significance Of Changing Atomic Volume; Theodore William Richards
Theodore William Richards Science; History; Atomic volume; Atomic
weights; Science / History; Social Science / Methodology
This scarce antiquarian book is a selection from Kessinger
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imperfections such as marks, notations, marginalia and flawed
pages. Because we believe this work is culturally important, we
have made it available as part of our commitment to protecting,
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Publishing is the place to find hundreds of thousands of rare and
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This scarce antiquarian book is a selection from Kessinger
Publishing's Legacy Reprint Series. Due to its age, it may contain
imperfections such as marks, notations, marginalia and flawed
pages. Because we believe this work is culturally important, we
have made it available as part of our commitment to protecting,
preserving, and promoting the world's literature. Kessinger
Publishing is the place to find hundreds of thousands of rare and
hard-to-find books with something of interest for everyone!
This scarce antiquarian book is a selection from Kessinger
Publishing's Legacy Reprint Series. Due to its age, it may contain
imperfections such as marks, notations, marginalia and flawed
pages. Because we believe this work is culturally important, we
have made it available as part of our commitment to protecting,
preserving, and promoting the world's literature. Kessinger
Publishing is the place to find hundreds of thousands of rare and
hard-to-find books with something of interest for everyone!
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for free. This is an OCR edition with typos. Excerpt from book:
that capable of being performed by the chemical affinity alone. The
result would be a cooling reaction and an excess of free energy.
This behavior would not be a contradiction of the second law of
thermodynamics, because the law states only that heat cannot of
itself do work at constant temperature. Thus the hypothesis of
compressible atoms not only is consistent with the ordinary
applications of the two laws of energy, but also affords a
conceivable picture of the cause of the newly discovered relation
oU dA of 3r to Tr- On the basis of the present data it is
unprofitable to attempt the calcu- 1 TT 0 A lation of the
mathematical relation of -, to 0 .. or to probe further into the
mechanism of the change. When more exact data have been obtained,
it may well be possible to arrive at more definite conclusions. If
the contraction of volume on combination could only be interpreted
in the light of accurate determination of the compressibilities
involved, it seems reasonable that this contraction might be a more
exact measure of the affinity than either the free or the total
energy change. The foregoing facts and logic seem to lead to the
conclusion that the change of free energy of a process does not
really represent the attractive energy at work in the process,
unless the heat capacity of the system remains unchanged during the
reaction. If the heat capacity diminishes during the reaction, the
free energy is less than the affinity, and vice versa. This
conclusion is contrary to tho common belief. If warranted, it shows
that the free energy change is a no more satisfactory guide to the
affinity than is the heat evolved in the reaction, even when no
concentration effect is present. The free energy seems to represent
rather the remainder left after a resisting energ...
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