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This book presents a large number of organic reactions performed
under green conditions, which were earlier performed using
anhydrous conditions and various volatile organic solvents. The
conditions used involve green solvents like water, super critical
carbon dioxide, ionic liquids, polymer-supported reagents,
polyethylene glycol and perfluorous liquids. A number of reactions
have been conducted in solid state without using any solvent. Most
of the reactions have been conducted under microwave irradiations
and sonication. In large number of reactions, catalysts like phase
transfer catalysts, crown ethers and biocatalysts have been used.
Providing the protocols that every laboratory should adopt, this
book elaborates the principles of green chemistry and discusses the
planning and preparations required to convert to green laboratory
techniques. It includes applications relevant to practicing
researchers, students and environmental chemists. This book is
useful for students (graduate and postgraduate), researchers and
industry professionals in the area of chemical engineering,
chemistry and allied fields.
Organic chemistry has played a vital role in the development of
diverse molecules which are used in medicines, agrochemicals and
polymers. Most ofthe chemicals are produced on an industrial scale.
The industrial houses adopt a synthesis for a particular molecule
which should be cost-effective. No attention is paid to avoid the
release of harmful chemicals in the atmosphere, land and sea.
During the past decade special emphasis has been made towards green
synthesis which circumvents the above problems. Prof. V. K.
Ahluwalia and Dr. M. Kidwai have made a sincere effort in this
direction. This book discusses the basic principles of green
chemistry incorporating the use of green reagents, green catalysts,
phase transfer catalysis, green synthesis using microwaves,
ultrasound and biocatalysis in detail. Special emphasis is given to
liquid phase reactions and organic synthesis in the solid phase. I
must congratulate both the authors for their pioneering efforts to
write this book. Careful selection of various topics in the book
will serve the rightful purpose for the chemistry community and the
industrial houses at all levels. PROF. JAVED IQBAL, PhD, FNA
Distinguished Research Scientist & Head Discovery Research Dr.
Reddy's Laboratories Ltd.
This textbook provides a simple approach to understand the various
complex aspects of stereochemistry. It deals with basic static
stereochemistry and gives an overview of the different isomeric
forms and nomenclatures. With simple writing style and many
examples, this book covers the topics such as stereochemistry of
hydrocarbons, alkenes, cycloalkenes, optically active compounds,
trivalent carbon, fused, bridged and caged rings and related
compounds. This textbook also covers the additional topics such as
optical rotatory dispersion and circular dichroism, steroechemistry
of elimination reactions, substitution reactions, rearrangement
reactions and pericyclic reactions. The book includes pedagogical
features like end-of-chapter problems and key concepts to help
students in self-learning. The textbook is extremely useful for the
senior undergraduate and postgraduate students pursuing course in
chemistry, especially organic chemistry. Besides, this book will
also be a useful reference book for professionals working in
various chemical industries, biotechnology, bioscience and
pharmacy.
This book presents a large number of organic reactions performed
under green conditions, which were earlier performed using
anhydrous conditions and various volatile organic solvents. The
conditions used involve green solvents like water, super critical
carbon dioxide, ionic liquids, polymer-supported reagents,
polyethylene glycol and perfluorous liquids. A number of reactions
have been conducted in solid state without using any solvent. Most
of the reactions have been conducted under microwave irradiations
and sonication. In large number of reactions, catalysts like phase
transfer catalysts, crown ethers and biocatalysts have been used.
Providing the protocols that every laboratory should adopt, this
book elaborates the principles of green chemistry and discusses the
planning and preparations required to convert to green laboratory
techniques. It includes applications relevant to practicing
researchers, students and environmental chemists. This book is
useful for students (graduate and postgraduate), researchers and
industry professionals in the area of chemical engineering,
chemistry and allied fields.
This textbook provides a simple approach to understand the various
complex aspects of stereochemistry. It deals with basic static
stereochemistry and gives an overview of the different isomeric
forms and nomenclatures. With simple writing style and many
examples, this book covers the topics such as stereochemistry of
hydrocarbons, alkenes, cycloalkenes, optically active compounds,
trivalent carbon, fused, bridged and caged rings and related
compounds. This textbook also covers the additional topics such as
optical rotatory dispersion and circular dichroism, steroechemistry
of elimination reactions, substitution reactions, rearrangement
reactions and pericyclic reactions. The book includes pedagogical
features like end-of-chapter problems and key concepts to help
students in self-learning. The textbook is extremely useful for the
senior undergraduate and postgraduate students pursuing course in
chemistry, especially organic chemistry. Besides, this book will
also be a useful reference book for professionals working in
various chemical industries, biotechnology, bioscience and
pharmacy.
Today the world has stopped at COVID-19: envisaging a make or break
moment for the world and its people. In this backdrop, the
overarching thesis of the book is centred on offering an Indian
perspective to COVID-19 and its challenges. This book seeks to
examine the pandemic largely from a 'national security
perspective'. In doing so, it focuses mainly on India`s national
security, which has been studied from a two-fold perspective: the
politico-economic-strategic environment as impacted by COVID-19;
and the criticality of non-traditional and traditional threats to
India's security, in that order of priority. The essence of the
volume lies in assessing the threats, challenges and opportunities
that are likely to shape India's national security strategy in the
post-pandemic world order. With its holistic approach, this book
has nine chapters, which examines the need for India to prioritise:
human security and environmental security in its national security;
economic growth and sustainability in national policy;
self-reliance as the key to success; taking a decisive role in
global arena; re-appraisal of India's military thinking; the
evolving role of the Indian Armed Forces; and use of technology for
maximising security- all aimed to shape a better future for India.
The book would be of interest to politicians, policy makers,
diplomats, academia, medical fraternity, practitioners, security
forces, and the people of the country.
Talks about the lesser known facts and accounts of the intrusions
and the war from various commanders and officers, some of whom have
also served during the conflict. The book has been divided into
five parts. The first part titled, 'Blood, Guts and Glory,' briefly
discusses the actual battles fought in Dras, Mushkoh, Batalik,
Kaksar and Turtuk sub-sectors, to evict the Pakistani intruders
from the dominating heights in the Kargil region. The aim was to
restore the LoC to its originally held positions. The second part
analyses the supporting forces which synergised the effort to
victory, in the true spirit of 'Op Vijay'. In the third part,
individual officers, associated with Kargil, have shared their
perceptions and opinions about the Kargil conflict and the scenario
after 20 years. The fourth part focuses on 'Motivation;' and
reflects the saga of courage and valour of the Indian Armed Forces,
and the junior leadership, during the summer of 1999. The fifth
part, 'Emerging Challenges and the Way Ahead' looks at the emerging
global-cum-regional scenario, the envisaged threats, our
preparedness, and makes substantial recommendations to face the
conflicts of the future. The forecasts provided by some of the most
senior military officers of the country give a sneak peek into the
emerging challenges of the future and India's preparatory responses
to them. Given the emerging world order and the revolutionary
changes in technology and character of conflicts, the book restates
the fundamental focus of the Indian Armed forces: to be prepared to
face the envisaged threats and challenges of the future.
This textbook is intended for undergraduate and graduate students
pursuing courses in chemistry and allied fields. It includes
fundamental concepts, equations involved in organic reactions,
chemical bonds (ionic and covalent bonds), hybridization,
representation of a chemical reaction and mechanism of organic
reactions. The book also discusses the displacement of bonding
electrons involving inductive effect, electromeric effect,
mesomeric effect, hyperconjugative effect and resonance. A number
of organic reactions involving formation of intermediates such as
carbocations, carbanions, free radicals, carbenes, nitrenes and
benzynes have also been included. It also discusses different types
of reagents involved in a chemical reactions along with types of
additional reactions and its detailed mechanism. The book also
includes the use of pedagogical elements such as multiple choice
questions and end of chapter exercises to aid self-learning among
students
Need for this type of material has been strongly felt by the
students studying chemistry at UG and PG levels for quite sometime
and hence this product. Each title of the series is independent by
itself and presupposes only a very little fore-knowledge for use.
The content has been developed following a basic undergraduate and
plus level, avoiding any sophistication and show of expertise.
ORGANIC CHEMISTRY: Fundamental Concepts deals with the basic
concepts which are very helpful for a simple and clear
understanding of Organic Chemistry. These concepts include
nomenclature and classification, hybridization, electronic and
physical effects, hydrogen bonding, reaction intermediates,
chemical reactions-basic principles, stereoisomerism and
aromaticity. This book will be extremely helpful to B.Sc. General
and Hons. Students of all universities and colleges.
GREEN CHEMISTRY: A Textbook is written especially in meet the
requirements and undergraduate and postgraduate students in
chemistry if various universities / Colleges. Green chemistry deals
with environmentally benign chemical synthesis. Basic principles of
green chemistry and how to plan a green synthesis have been
discussed. Organic synthesis using benign green solvents like
water, supercritical carbon dioxide ionic Liquids, polyethylene
glycol and ferrous solvents. Organic synthesis using phase transter
catalysts and ultra sound have also been incorporated. The use of
green catalysts including biocatalysts and polymer supported
reagents and solid state organic synthesis have been discussed. The
book will be at immense use to students and researchers at all
levels and also to chemists working in chemical industries.
HETEROCYCLIC CHEMISTRY is written keeping in mind the requirements
of graduate and postgraduate students and students appearing in
various competitive examinations. It deals with the fundamentals of
heterocyclic chemistry, including importance, classification and
nomenclature of heterocyclic compounds. The book discusses
chemistry (methods of synthesis, reactions and importance) of
three-membered heterocyclic compounds (containing one or two
heteroatoms), four-membered heterocyclic compounds, five membered
heterocyclic compounds (containing one or two or more than two
hetero atoms) alongwith their benzofused derivatives and
six-membered heterocyclic compounds (containing one or more than O,
N or S heteroatoms) alongwith their benzofused derivatives. The
incorporation of pyridazine, pyrimidine and their derivatives
alongwith their fused derivatives has special importance.
Seven-membered heterocyclic compounds and meso-ionic heterocycles
have also been included.
"Green Chemistry" deals with environmentally benign organic
transformations. The book is divided into two parts. The first part
deals with introduction, principles of green chemistry and planning
a green synthesis. In the second part synthetic organic
transformations in aqueous phase, solid phase, photochemical
transformations, using phase transfer catalysts, using sonication,
microwaves, enzymatic transformations, transformations in ionic
liquids, polyethylene glycol and also transformations using polymer
support reagents are discusses. Besides, some miscellaneous
transformations are also described. The experimental details of a
large number of transformations in all the above heads are given.
This book will be extremely helpful to students at undergraduate
and postgraduate levels and also to research students, chemists and
scientists engaged in research in the colleges, universities and
industries.
This book, written for graduate and post-graduate chemistry
students, provides an extensive coverage of various organic
reactions, rearrangements and reagents, with emphasis on their
applications in organic synthesis. In the chapters on oxidation and
reduction a summary of oxidation and reduction of organic compounds
with the different reagents is given in a tabular form for the
convenience of students. The most commonly encountered reaction
intermediates are discussed in detail. The applications of organic
reagents are illustrated with examples while the chapters on
prericyclic reactions and photochemical reactions were included in
the second and third editions, respectively, in this fourth edition
a new chapter on solved problems has been added, to enable students
evaluate their understanding of the topic. This book is also very
useful for students taking competitive examinations.
This book, written explicitly for graduate and postgraduate
students of chemistry, provides an extensive coverage of various
organic reaction and rearrangements with emphasis on there
application in synthesis. A summary of oxidation and reduction of
organic compounds is given in tabular form (correlation tables) for
the convenience of students. The most commonly encountered reaction
intermediates are dealt with. Applications of organic reagents
illustrated with examples and problems at the end of each chapter
will enable students to evaluate their understanding of the topic.
This book discusses some of the reduction agents and processes
involved in organic synthesis such as catalytic hydrogenation,
homogeneous catalytic hydrogenation, asymmetric catalytic
hydrogenations, hydride transfer reagents, dissolving metal
reductions, and non-metallic reducing agents. It further covers the
topics of photochemical reductions, enzymatic or microbial
reduction, reductions of specific type of organic compounds
including hydrocarbons, hydrogenolysis, enzymatic or microbial
reduction, and some reductions under benign condition. This book is
of immense use to undergraduate and postgraduate students of
organic chemistry. It is also a useful reference book for
researchers involved in organic synthesis.
This textbook is intended for undergraduate and postgraduate
students in organic chemistry. Â It describes the synthesis
and properties of cycloalkanes compounds such as cyclopropane,
cyclobutane, cyclopentane, cyclohexane, cycloheptane and
cycloheptatriene. It further covers the chemistry of ring
compounds. The book also covers the reaction mechanisms of
non-benzenoid aromatic compounds including annulenes, metallocenes
and azulenes. It further contains discussions on tropone,
tropolones, fluxional molecules, catenanes and rotaxanes.
End-of-chapter exercises such as multiple-choice questions and
short answer-questions help students in self-learning. This
textbook is useful for undergraduate and postgraduate students in
organic chemistry.
This book focuses on green conditions, such as reactions under
microwave irradiation, sonication, and the use of different green
solvents and green catalysts including PTC and crown ethers. It
covers two of the most important carbon-carbon bond forming
reactions: the Baylis-Hillman reaction and the Friedal-Crafts
reaction. In addition to discussing normal conditions, the author
also details the use of microwaves in water, ionic liquids, and
PEG. It also details the aqueous phase, super critical CO2, other
green solvents, and microwave irradiation for the Friedal-Crafts
reaction. The text also addresses reactions in the solid state on
photo irradiation and enzymes.
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