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Worldwide concern in scientific, industrial, and governmental com
munities over traces of toxic chemicals in foodstuffs and in both
abiotic and biotic environments has justified the present
triumvirate of specialized publications in this field:
comprehensive reviews, rapidly published progress reports, and
archival documentations. These three publications are integrated
and scheduled to provide in international communication the
coherency essential for nonduplicative and current progress in a
field as dynamic and complex as environmental contamination and
toxicology. Until now there has been no journal or other
publication series reserved exclusively for the diversified
literature on "toxic" chemicals in our foods, our feeds, our
geographical surroundings, our domestic animals, our wild life, and
ourselves. Around the world immense efforts and many talents have
been mobilized to technical and other evaluations of natures,
locales, magnitudes, fates, and toxicology of the persisting
residues of these chemicals loosed upon the world. Among the
sequelae of this broad new emphasis has been an inescapable need
for an articulated set of authorita tive publications where one
could expect to find the latest important world literature produced
by this emerging area of science together with documentation of
pertinent ancillary legislation."
Tension-tension fatigue behavior of a prototype Silicon
Carbide/Silicon Carbide (SiC/SiC) ceramic matrix composite (CMC)
material was investigated at 1000 C in laboratory air and in steam
environments. The material consists of a SiC matrix reinforced with
CG NICALON fibers woven in an eight harness satin weave (8HSW) and
coated with a BN/SiC dual-layer interphase. The composite was
manufactured by a Polymer Infiltration and Pyrolysis (PIP) process.
A seal coat of SiC and elemental boron was applied to the test
specimens after machining. The tensile stress-strain behavior was
investigated and the tensile properties were measured at 1000 C.
Tension-tension fatigue behavior was studied for fatigue stresses
ranging from 60 to 100 MPa. The fatigue limit (based on a run-out
condition of 2 x 10 cycles) was 80 MPa, which is 59% of the
Ultimate Tensile Strength (UTS). The material retained 82% of its
tensile strength. The presence of steam significantly degraded the
fatigue performance at 1000 C. In steam the fatigue limit dropped
below 60 MPa (44% UTS). Microstructural analysis revealed severe
oxidation occurring in the specimens tested in steam, which
resulted in accelerated damage development and failure. Through
quantitative and qualitative analysis, the damage and premature
failure of the composite in the steam environment is believed to be
due to oxidation embrittlement. This material also showed
considerably worse performance than similar SiC/SiC composites with
a great deal of variability between specimens cut from different
panels. The possibility exists that inadequate process control may
be behind the degraded performance of the material and the
panel-to-panel variability in performance.
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