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This volume contains the fourteen papers presented at the NATO-sponsored Ad vanced Research Workshop on the 'Status and Future Developments in the Study of Transport Properties' held in Porto Carras, Halkidiki, Greece from May 29 to May 31, 1991. The Workshop was organised to provide a forum for the discussion among prac titioners of the state-of-the-art in the treatment of the macroscopic, non-equilibrium properties of gases. The macroscopic quantities considered all arise as a result of the pairwise interactions of molecules in states perturbed from an equilibrium, Maxwellian distribution. The non-equilibrium properties of gases have been studied in detail for well over a century following the formulation of the Boltzmann equation in 1872. Since then the range of phenomena amenable to experimental study has expanded greatly from the properties characteristic of a bulk, non-uniform gas, such as the viscosity and thermal conductivity, to the study of differential scattering cross-sections in molecular beams at thermal energies, to studies of spectral-line widths of individual molecules and of Van der Waals complexes and even further. The common thread linking all of these studies is found in the corresponding theory which relates them all to the potential energy function describing the interaction of pairs of molecules. Thus, accompanying the experimental development there has been a corresponding improvement in the theoretical formulation of the quantities characterising the various phenomena."
This title is a revision of Experimental Thermodynamics Volume II,
published in 1975, reflecting the significant technological
developments and new methods introduced into the study of
measurement of thermodynamic quantities.
This volume contains the fourteen papers presented at the NATO-sponsored Ad vanced Research Workshop on the 'Status and Future Developments in the Study of Transport Properties' held in Porto Carras, Halkidiki, Greece from May 29 to May 31, 1991. The Workshop was organised to provide a forum for the discussion among prac titioners of the state-of-the-art in the treatment of the macroscopic, non-equilibrium properties of gases. The macroscopic quantities considered all arise as a result of the pairwise interactions of molecules in states perturbed from an equilibrium, Maxwellian distribution. The non-equilibrium properties of gases have been studied in detail for well over a century following the formulation of the Boltzmann equation in 1872. Since then the range of phenomena amenable to experimental study has expanded greatly from the properties characteristic of a bulk, non-uniform gas, such as the viscosity and thermal conductivity, to the study of differential scattering cross-sections in molecular beams at thermal energies, to studies of spectral-line widths of individual molecules and of Van der Waals complexes and even further. The common thread linking all of these studies is found in the corresponding theory which relates them all to the potential energy function describing the interaction of pairs of molecules. Thus, accompanying the experimental development there has been a corresponding improvement in the theoretical formulation of the quantities characterising the various phenomena."
This comprehensive book describes the most soundly based methods currently available for evaluating the transport properties, particularly viscosity and thermal conductivity, of pure fluids and fluid mixtures. Particular emphasis is placed on recent theoretical advances in our understanding of fluid transport properties in all the different regions of thermodynamic states. Following a general introductory section, the important theoretical tools for describing complete transport property surfaces of fluids are prsented. Different methods of data representation are then covered, followed by a section which demonstrates the application of selected methods under various specific conditions. Case studies of transport property analysis for real fluids are then given for system with increasing complexity, and the book concludes with a discussion of various international data banks and prediction packages. Advanced students of physics, chemistry and chemical engineering, scientists working in the field of kinetic theory, experimental determination and theoretical interpretation of transport properties, as well as engineers involved with the design and optimization of process equipment, will find this book indispensable.
This book describes the most reliable methods for evaluating the transport properties of pure gases and fluid mixtures, such as viscosity, thermal conductivity and diffusion. The authors place particular emphasis on recent theoretical advances in our understanding of fluid transport properties in all the different regions of temperature and pressure. In addition to the important theoretical tools, the authors cover the different methods of data representation, and they follow this with a section that demonstrates the application of selected models in a range of circumstances. They then offer case studies of transport property analysis for real fluids, and the book concludes with a discussion of various international data banks and prediction packages. Advanced students of kinetic theory, as well as engineers and scientists involved with the design of process equipment or the interpretation of measurements of fluid transport properties, will find this book indispensable.
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