Nitrogen is an essential nutrient for life, and its sources and
cycling have varied over earth history. Stable isotope ratios of
nitrogen compounds (expressed as 15N, in 0/00) are preserved in the
sedimentary record and track these changes, providing important
insights into associated biogeochemical feedbacks. Here we review
the use of nitrogen stable isotope geochemistry in unravelling the
evolution of the global N cycle in deep time. We highlight
difficulties with preservation, unambiguous interpretations, and
local versus global effects. We end with several case studies
illustrating how depositional and stratigraphic context is crucial
in reliably interpreting 15N records in ancient marine sediments,
both in ancient anoxic (Archean) and more recent well oxygenated
(Phanerozoic) environments.
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