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Developing Ambient Water Quality Criteria for Mercury - A Probabalistic Site-Specific Approach (Paperback, Illustrated Ed)
Loot Price: R3,231
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Developing Ambient Water Quality Criteria for Mercury - A Probabalistic Site-Specific Approach (Paperback, Illustrated Ed)
Series: WERF Research Report Series
Expected to ship within 12 - 17 working days
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This project examined the development of ambient water quality
criteria (AWQC) for the protection of wildlife for mercury. Mercury
is considered a serious risk to wildlife in many areas. As a
result, the Great Lakes Water Quality Initiative and others have
developed AWQC. These AWQC have been controversial, however,
because (1) the AWQC were single values that did not account for
site-specific conditions; (2) derivation of the AWQC relied on a
single NOAEL, and (3) the AWQC had an unknown level of conservatism
because of reliance on both average and conservative assumptions
and uncertainty factors. Rather than develop a single value AWQC
for total mercury, we derive an AWQC model that explicitly
incorporates factors controlling bioavailability, methylation rates
and bioaccumulation in the aquatic environment (e.g., pH, DOC,
sulfate). To derive our AWQC model, field data was collected
including numerous water quality parameters and total mercury and
methylmercury concentrations in whole body fish tissue from 31
lakes in Ontario and an additional 10 lakes in Nova Scotia. An
independent dataset consisting of 51 water bodies in the United
States was then used to confirm the validity and robustness of the
AWQC model. Next we combined the results of chronic-feeding studies
with similar protocols and endpoints, in a meta-analysis to derive
a dose-response curve for mink exposed to mercury in the diet.
Using this approach, one can derive an LD5 or other similar
endpoint that can then be used as the basis for deriving -wildlife
AWQC. In the final step, we used a probabilistic risk model to
estimate the concentrations of methylmercury in water that would
lead to levels in fish sufficient for there to be a 10% probability
of exceeding the mink LD5. This analysis was repeated for various
combinations of pH and DOC. The result is an AWQC model for mercury
for the protection of wildlife that can be used for a variety of
site-specific conditions. This publication can also be purchased
and downloaded via Pay Per View on Water Intelligence Online -
click on the Pay Per View icon below
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