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Fate of Estrogenic Compounds during Municipal Sludge Stabilization and Dewatering (Paperback)
Loot Price: R3,231
Discovery Miles 32 310
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Fate of Estrogenic Compounds during Municipal Sludge Stabilization and Dewatering (Paperback)
Series: WERF Research Report Series
Expected to ship within 12 - 17 working days
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This project convened a team of experts in the fields of
environmental engineering (AECOM), analytical chemistry and
hydrogeology (USGS), and biological assay analysis (UA) to evaluate
the occurrence and fate of estrogenic compound, and the
estrogenicity of biosolids derived from wastewater treatment.
Sludge and biosolids samples were collected through the solids
treatment train of four wastewater treatment plants (WWTPs)
operating a range of solids processing, treatment and disposal
options that are typical to facilities across the United States.
Targeted solids processing methods included thickening via gravity,
gravity belt, and dissolved air flotation; stabilization via lime
addition, aerobic digestion and anaerobic digestion; chemical
conditioning; dewatering via centrifuge; and other processes
including composting and pelletization. Targeted disposal options
included beneficial reuse or disposal including land application,
dedicated land disposal and landfilling. Samples were collected
from the study plants between two and five times over two years,
allowing for an assessment of seasonal variation. In some cases,
sampling density was not sufficient to assess seasonal variations,
but for certain compounds interesting seasonal trends were
observed. The solids samples were supplemented by liquid samples at
key locations in the study plants during several sample collection
events. Over the course of the study 15 sample trips were conducted
and a total of 90 samples were collected from the four study
plants. For each sample collected, chemical analysis for steroid
hormones and in vitro biological assay (bioassay) measurements were
conducted to quantify estrogen receptor agonists, antagonists, and
estrogenic activity. In addition to the estrogenic compounds,
samples were analyzed for a suite of trace organic compounds
(TOrCs), including anthropogenic wastewater indicators (AWIs) and
pharmaceuticals, resulting in analysis for over 100 chemical
compounds in each liquid or solid sample. Collection of these data
substantially expanded the scope and value of the study, providing
a more comprehensive evaluation of the effects of solids processing
and treatment on TOrCs. Loads of TOrCs and estrogenic activity were
calculated for each sample point based on flows and solids loadings
data from the study plants. In this exercise, TOrC concentrations
are multiplied by the solids loading (tons per day) to calculate
the daily load of each compound in grams per day (g/day). This
report provides comparisons of the chemical and biological assays
used in this study, the results of select TOrC mass balances as
well as a discussion of the results and areas for future research.
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