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Theory of Copper Oxide Superconductors (Hardcover, 2005 ed.)
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Theory of Copper Oxide Superconductors (Hardcover, 2005 ed.)
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The objective of this book is to provide an up-to-date
comprehensive descr- tion of the Kamimura-Suwa model, which is the
?rst of the present rep- sentative two-component theories in high
temperature superconductivity. In 1986 George Bednorz and Karl Alex
Muller .. made the remarkable discovery
ofsuperconductivitywithanunbelievinglyhighvalueofT = 35K,bysubs- c
2+ 3+ tuting Ba ions for La ions in the antiferromagnetic insulator
La CuO . 2 4 Soon after this discoveryT rose to 90K by synthesizing
YBa Cu O with c 2 3 7?? ade?citinoxygen.
Furtherexplorationfornewcopperoxidesuperconducting materials with
higherT led to the discovery of Bi-Sr-Ca-Cu-O, Tl-Ba-Ca- c Cu-O and
Hg-Ba-Ca-Cu-O compounds in subsequent years. The new class of
copper oxide compounds mentioned above is called "cuprates". At
present T = 135K under ambient pressure andT = 164K under 31 GPa
observed c c in HgBa Ca Cu O are the highest value so far obtained.
The Kamimura- 2 2 3 8 Suwa model, which was originally developed in
1993, is a theory of these real copper oxide superconducting
materials. Since undoped La CuO is a 2 4 Mott-Hubbard
antiferromagnetic insulator, its electronic structure can not
beexplained bytheordinaryone-electron energybandtheory.
Inthiscontext the important role of electron-correlation was
pointed out. 2+ On theother hand, ad-hole state in each Cu ion in
theligand ?eld with octahedral symmetry is orbitally
doubly-degenerate so that it is subject to strong Jahn-Teller
interaction in La CuO. Asaresult,aCuO octahedron 2 4 6 in La CuO is
elongated along thec-axis due to the Jahn-Teller distortion.
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