|
Showing 1 - 25 of
109 matches in All Departments
TheprototypicalcatalyticreductiveC-Cbondformations,theFischer-Tropsch
reaction [1] and alkene hydroformylation [2], were discovered in
1922 and 1938, respectively [3,4]. These processes, which involve
reductive coupling to carbon monoxide, have long been applied to
the industrial manufacture of commodity chemicals [5]. Notably,
alkene hydroformylation, also known as the oxo-synthesis, has
emerged as the largest volume application of homo- neous metal
catalysis, accounting for the production of over 7 million metric
tons of aldehyde annually. Despite the impact of these prototypical
reductive C-C bond formations, this ?eld of research lay fallow for
several decades. Eventually, the increased availability of mild
terminal reductants, in part- ular silanes, led to a renaissance in
the area of catalytic reductive C-C bond
formation.Forexample,the?rstcatalyticreductiveC-Ccouplingsbeyond-
droformylation, which involve the hydrosilylative dimerization of
conjugated dienes [6-12], appeared in 1969 - approximately 16 years
after the ?rst - ported metal-catalyzed alkene hydrosilylation
[13]. Following these seminal studies, the ?eld of catalytic
reductive C-C bond formation underwent exp-
sivegrowth,culminatingintheemergenceofanevergrowingbodyofresearch
encompassing a powerful set of transformations. To our knowledge,
no thematic volumes devoted solely to metal-catalyzed reductive C-C
bond formationhave been assembled. For the ?rst time, in this issue
of Topics in Current Chemistry,wepresent acompilation ofmonographs
from several leaders in this burgeoning area of research. This
collection of reviews serves to capture the diversity of catalytic
reductive C-C couplings presently available and, in turn, the
remarkable range of reactivity embodied by such transformations.
There is no indication that this ?eld has reached its
zenithanditisthehopeofthepresentauthorthatthisvolumewillfuelfurther
progress.
The World Court Digest continues the Fontes Iuris Gentium, a series that presents the decisions of the Permanent Court of International Justice, up to 1990. The new volume covers the period from 1996 to 2000. All important pronouncements of the Court in its judgments and advisory opinions, are systematically arranged under specific topics taken from substantive and procedural international law. The World Court Digest provides reliable access to the decisions of the most significant international judicial organ on questions as important as the aerial incident at Lockerbie, the crimes of genocide in Bosnia and Herzegovina, as well as the use of nuclear weapons and the use of force in the Yugoslavian context.
This important new overview of the German Democratic Republic
focuses on the country's search for identity and legitimacy
throughout its history. Dr. Henry Krisch analyzes major aspects of
East German life-political, economic, cultural, and societal-to
answer the fundamental question of the nature of the GDR. Arguing
that East Germany has been shaped by history to an unusual degree,
he explores the country's historical background, including the
Soviet Zone, the origins of the GDR, and the leadership of Ulbricht
and Honecker, and examines the role and structure of the party,
state, and military and security forces. The main emphasis of this
book, however, is upon current problems and on likely responses to
them in the near future. Issues such as the viability of communist
politics in a technologically advanced society, the relationship of
the GDR to a common German heritage and a competing West German
state, and the country's role within the Soviet alliance system are
examined in detail, and current social concerns, including the
peace movement, cultural trends, the role of women and youth, and
the prime importance of sports, are discussed.
This important new overview of the German Democratic Republic
focuses on the country's search for identity and legitimacy
throughout its history. Dr. Henry Krisch analyzes major aspects of
East German life-political, economic, cultural, and societal-to
answer the fundamental question of the nature of the GDR. Arguing
that East Germany has been shaped by history to an unusual degree,
he explores the country's historical background, including the
Soviet Zone, the origins of the GDR, and the leadership of Ulbricht
and Honecker, and examines the role and structure of the party,
state, and military and security forces. The main emphasis of this
book, however, is upon current problems and on likely responses to
them in the near future. Issues such as the viability of communist
politics in a technologically advanced society, the relationship of
the GDR to a common German heritage and a competing West German
state, and the country's role within the Soviet alliance system are
examined in detail, and current social concerns, including the
peace movement, cultural trends, the role of women and youth, and
the prime importance of sports, are discussed.
Under pressure from globalization, the classical distinction
between domestic and international law has become increasingly
blurred, spurring demand for new paradigms to construe the emerging
postnational legal order. The typical response of constitutional
and international lawyers as well as political theorists has been
to extend domestic concepts - especially constitutionalism - beyond
the state. Yet as this book argues, proposals for postnational
constitutionalism not only fail to provide a plausible account of
the changing shape of postnational law but also fall short as a
normative vision. They either dilute constitutionalism's origins
and appeal to 'fit' the postnational space; or they create tensions
with the radical diversity of postnational society.
This book explores an alternative, pluralist vision of postnational
law. Pluralism does not rely on an overarching legal framework but
is characterized by the heterarchical interaction of various
suborders of different levels - an interaction that is governed by
a multiplicity of conflict rules whose mutual relationship remains
legally open. A pluralist model can account for the fragmented
structure of the European and global legal orders and it reflects
the competing (and often equally legitimate) claims for control of
postnational politics. However, it typically provokes concerns
about stability, power and the rule of law.
This book analyzes the promise and problems of pluralism through a
theoretical enquiry and empirical research on major global
governance regimes, including the European human rights regime, the
contestation around UN sanctions and human rights, and the
structure of global risk regulation. The empirical research reveals
how prevalent pluralist structures are in postnational law and what
advantages they possess over constitutionalist models. Despite the
problems it also reveals, the analysis suggests cautious optimism
about the possibility of stable and fair cooperation in pluralist
settings.
Law is usually understood as an orderly, coherent system, but this
volume shows that it is often better understood as an entangled
web. Bringing together eminent contributors from law, political
science, sociology, anthropology, history and political theory, it
also suggests that entanglement has been characteristic of law for
much of its history. The book shifts the focus to the ways in which
actors create connections and distance between different legalities
in domestic, transnational and international law. It examines a
wide range of issue areas, from the relationship of state and
indigenous orders to the regulation of global financial markets,
from corporate social responsibility to struggles over human
rights. The book uses these empirical insights to inform new
theoretical approaches to law, and by placing the entanglements
between norms from different origins at the centre of the study of
law, it opens up new avenues for future legal research. This title
is also available as Open Access.
Law is usually understood as an orderly, coherent system, but this
volume shows that it is often better understood as an entangled
web. Bringing together eminent contributors from law, political
science, sociology, anthropology, history and political theory, it
also suggests that entanglement has been characteristic of law for
much of its history. The book shifts the focus to the ways in which
actors create connections and distance between different legalities
in domestic, transnational and international law. It examines a
wide range of issue areas, from the relationship of state and
indigenous orders to the regulation of global financial markets,
from corporate social responsibility to struggles over human
rights. The book uses these empirical insights to inform new
theoretical approaches to law, and by placing the entanglements
between norms from different origins at the centre of the study of
law, it opens up new avenues for future legal research. This title
is also available as Open Access.
|
|