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Over the past twenty years, Catalysis by Heteropolyacids (HPAs) has
received wide attention and led to new and promising developments
both at academic and industrial level. In particular, heterogeneous
catalysis is particularly attractive because it generally satisfies
most of green chemistry's requirements. By emphasizing the
development of third generation catalysts, this volume presents
trends and opportunities in academic and industrial research. The
book appeals to postgraduates, researchers, and chemists working in
the field of environmentally benign catalysts as well as catalytic
processes.
Over the past twenty years, Catalysis by Heteropolyacids (HPAs) has
received wide attention and led to new and promising developments
both at academic and industrial level. In particular, heterogeneous
catalysis is particularly attractive because it generally satisfies
most of green chemistry's requirements. By emphasizing the
development of third generation catalysts, this volume presents
trends and opportunities in academic and industrial research. The
book appeals to postgraduates, researchers, and chemists working in
the field of environmentally benign catalysts as well as catalytic
processes.
Heterogeneously catalyzed selective oxidations of alcohols is a
highly topical field. The first chapter of this brief describes the
importance of the selective oxidation of alcohols and advantages of
heterogeneous catalysts over conventional catalysts, use of
environmentally benign oxidants, and the design of selective
catalysts by tailoring of polyoxometalates at the molecular level.
Chapter 2 describes synthesis, characterization 11-molybdophosphate
based supported materials and their use as heterogeneous catalysts
for oxidation of alcohols with molecular oxygen under solvent free
mild reaction condition. ZrO2, Al2O3, MCM-41 and zeolite H were
used as supports. Chapter 3 describes synthesis, characterization
of transition metals (Mn, Co, Ni, Cu)- substituted
phosphomolybdates and their use as heterogeneous catalysts for
oxidation of alcohols with molecular oxygen under solvent free mild
reaction condition. Chapter 4 describes conclusive remarks for
present catalytic systems.
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