This textbook gives a thorough treatment of engineering thermodynamics with applications to classical and modern energy conversion devices. Some emphasis lies on the description of irreversible processes, such as friction, heat transfer and mixing and the evaluation of the related work losses. Better use of resources requires high efficiencies therefore the reduction of irreversible losses should be seen as one of the main goals of a thermal engineer. This book provides the necessary tools. Topics include: car and aircraft engines, including Otto, Diesel and Atkinson cycles, by-pass turbofan engines, ramjet and scramjet; steam and gas power plants, including advanced regenerative systems, solar tower and compressed air energy storage; mixing and separation, including reverse osmosis, osmotic power plants and carbon sequestration; phase equilibrium and chemical equilibrium, distillation, chemical reactors, combustion processes and fuel cells; the microscopic definition of entropy. The book includes about 300 end-of-chapter problems for homework assignments and exams. The material presented suffices for two or three full-term courses on thermodynamics and energy conversion.

The well known transport laws of Navier-Stokes and Fourier fail for the simulation of processes on lengthscales in the order of the mean free path of a particle that is when the Knudsen number is not small enough. Thus, the proper simulation of flows in rarefied gases requires a more detailed description.

This book discusses classical and modern methods to derive macroscopic transport equations for rarefied gases from the Boltzmann equation, for small and moderate Knudsen numbers, i.e. at and above the Navier-Stokes-Fourier level. The main methods discussed are the classical Chapman-Enskog and Grad approaches, as well as the new order of magnitude method, which avoids the short-comings of the classical methods, but retains their benefits. The relations between the various methods are carefully examined, and the resulting equations are compared and tested for a variety of standard problems.

The book develops the topic starting from the basic description of an ideal gas, over the derivation of the Boltzmann equation, towards the various methods for deriving macroscopic transport equations, and the test problems which include stability of the equations, shock waves, and Couette flow.