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This book focuses on the creative use of chemistry in the
fabrication of a variety of oxide and non-oxide materials which are
likely to play a crucial role in the development of the next
generation of microelectronics devices. It includes inorganic
precursor chemistry, gas-phase and solid-state chemistry, materials
science, chemical physics and chemical engineering. Highlights
include the deposition of high-k dielectric gate oxides,
ferroelectric oxide films for infrared and memory applications,
low-k dielectrics, TiN and TaN diffusion barriers, and fresh
precursors for III-V nitrides. The emphasis is on chemical methods
for the controlled deposition of thin films, for which chemical
vapor deposition (CVD) has proven to be a useful and versatile
technique. Of particular interest is the use of liquid-injection
MOCVD for the deposition of oxide multilayers and superlattices.
Solution deposition techniques such as sol-gel, metalorganic
decomposition (MOD), hydrothermal processing are also prominently
featured. Topics include: CVD of oxide ceramics; CVD of nonoxide
ceramics; solution deposition of electronic ceramics; alternative
chemical processing methods and characterization of electronic
ceramics..
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