Introducing the application of free energy correlations to elucidating the mechanisms of organic and bio-organic reactions, this book provides a new and illuminating way of approaching a potentially complex topic. The idea of how free energy correlations derive from polar substituent change is introduced, and common pitfalls encountered in the application of free energy relationships are described, along with the use of these anomalies in mechanistic studies. The concept of effective charge is described in detail, with examples of its application. Throughout, worked answers are provided for the problems posed. Databases of parameters, an extensive bibliography and comprehensive lists of further reading are also included. The text provides an invaluable source of information to senior undergraduates, postgraduates and to industrial researchers with an interest in mechanistic studies. It is the first such book in more than thirty years.

There is nothing 'little' about the history of Essex! However, this small volume condenses that fascinating, rich history into a collection of stories and facts that will make you marvel at the events our county has witnessed. Discover the development of ship building at Harwich, the silk and woollen industries in central Essex, the fortunes of Chelmsford and Colchester and the rise of seaside resorts at Southend and Clacton. Take a journey through Essex's historic struggles and celebrations or jump in to the era of your choice to discover the who, what and why of our county's history.

Advice for women from women for negotiating their own leadership careers

This is a practical guide for any woman dealing with a demanding role. Drawing on extensive interviews with women leaders, the authors isolate five key challenges: Intelligence; Backing; Resources; Buy-In; and Making a Difference. The three expert authors reveal what women have to teach us about the challenges and opportunities of leadership. As Tom Peters said of this book, "Women roar . . . . will help individual women negotiate what they need to success as leaders and help their firms support them in their efforts. That way we all win "Describes five key actions for leadership success: Drill Deep, Start from Strength, Assemble the Building Blocks, Gather Momentum, and Make Your MarkFilled with prescriptive advice and a wide range of approaches for helping women with leadership challengesLead authors wrote the "The ShadowNegotiation," which was then released in paperback as "Everyday Negotiation"

The book includes interviews with high-profile women leaders including Ann Moore (CEO of Time Inc.), Ann Mulcahy (CEO of Xerox), and Harvard's Rosabeth Moss Kanter.

Everyday Negotiation shows how to recognize the shadow negotiation— where the unspoken attitudes, hidden assumptions, and conflicting agendas that drive the bargaining process play out— and how to put that knowledge to work. Originally titled The Shadow Negotiation and named by Harvard Business Review as one the Ten Best Books of 2000, this best-selling book revealed how women could master the hidden agendas that determine bargaining success. Now, the new edition, Everyday Negotiation, broadens the scope and offers the same illuminating advice for both men and women. Everyday Negotiation lays out simple steps to

• Overcome acts of self-sabotage
• Increase your bargaining power
• Establish the terms of your advocacy and encourage a collaborative discussion
• Encourage a collaborative discussion
• Think about the negotiation process in a whole new way

In the history of New Orleans, there are those who make policy and those who are forced to live by policy. To help balance the scales, " Voice of the Poor: Citizen Participation Informing Public Policy for Rebuilding New Orleans" focuses on low-income residents, mostly African Americans, whose views are needed to help rebuild the shattered city in a way that will make it more sustainable, inclusive, and economically competitive than it was before Hurricane Katrina.

Through citizen participation, everyone's voice can be heard. As a result, New Orleans will become more equitable. "Voice of the Poor" offers a process for arriving at an acceptable solution for those who are interested in individual and community self-determination. Input of both current "and" displaced residents is vitally important in the rebuilding of the city. However, participation has generally been limited to those who have had the resources to return to New Orleans and continue their lives there. A variety of outlets for the participation of those who have returned have been available, and their contributions are integral in developing the plan to rebuild New Orleans.

Ironically, low-income citizens-those most impacted by the storm-have largely been excluded from this discussion. "Voice of the Poor" seeks to bridge this gap.