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The literature on cavitation chemistry is ripe with conjectures, possibilities, heuris tic arguments, and intelligent guesses. The chemical effects of cavitation have been explained by means of many theories, consisting of empirical constants, adjustable parameters, and the like. The chemists working with cavitation chemistry agree that the phenomenon is very complex and system specific. Mathematicians and physi cists have offered partial solutions to the observed phenomena on the basis of cavitation parameters, whereas chemists have attempted explanations based on the modes of reaction and the detection of intermediate chemical species. Nevertheless, no one has been able to formulate a unified theme, however crude, for its effects on the basis of the known parameters, such as cavitation and transient chemistry involving extremely high temperatures of nanosecond durations. When one surveys the literature on cavitation-assisted reactions, it is clear that the approach so far has been "Edisonian" in nature. While a large number of reactions have showed either enhanced yields or reduced reaction times, many reactions have remained unaffected in the presence of cavitation. The success or failure of cavitation reactions ultimately depends on the collapse of the cavity. Cavitation chemistry is based on the principles of the formation of small transient cavities, their growth and implosion, which produce chemical reactions caused by the generation of extreme pressures and temperatures and a high degree of micro turbulence."
The literature on cavitation chemistry is ripe with conjectures, possibilities, heuris tic arguments, and intelligent guesses. The chemical effects of cavitation have been explained by means of many theories, consisting of empirical constants, adjustable parameters, and the like. The chemists working with cavitation chemistry agree that the phenomenon is very complex and system specific. Mathematicians and physi cists have offered partial solutions to the observed phenomena on the basis of cavitation parameters, whereas chemists have attempted explanations based on the modes of reaction and the detection of intermediate chemical species. Nevertheless, no one has been able to formulate a unified theme, however crude, for its effects on the basis of the known parameters, such as cavitation and transient chemistry involving extremely high temperatures of nanosecond durations. When one surveys the literature on cavitation-assisted reactions, it is clear that the approach so far has been "Edisonian" in nature. While a large number of reactions have showed either enhanced yields or reduced reaction times, many reactions have remained unaffected in the presence of cavitation. The success or failure of cavitation reactions ultimately depends on the collapse of the cavity. Cavitation chemistry is based on the principles of the formation of small transient cavities, their growth and implosion, which produce chemical reactions caused by the generation of extreme pressures and temperatures and a high degree of micro turbulence.
The newest addition to the "Green Chemistry and Chemical Engineering" series from CRC Press, Biofuels and Bioenergy: Processes and Technologies provides a succinct but in-depth introduction to methods of development and use of biofuels and bioenergy. The book illustrates their great appeal as tools for solving the economic and environmental challenges associated with achieving energy sustainability and independence through the use of clean, renewable alternative energy. Taking a process engineering approach rooted in the fuel and petrochemical fields, this book masterfully integrates coverage of current conventional processes and emerging techniques. Topics covered include:
After an overview of the subject, the book discusses crop oils, biodiesel, and algae fuels. It examines ethanol from corn and from lignocelluloses and then explores fast pyrolysis and gasification of biomass. Discussing the future of biofuel production, it also describes the conversion of waste to biofuels, bioproducts, and bioenergy and concludes with a discussion of mixed feedstock. Written for readers with college-level backgrounds in chemistry, biology, physics, and engineering, this reference explores the science and technology involved in developing biofuels and bioenergy. It addresses the application of these and other disciplines, covering key issues of special interest to fuel process engineers, fuel scientists, and energy technologists, among others.
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