Written and edited by experts on specialty elastomers applications in the mechanical and automotive products industries, the Handbook of Specialty Elastomers provides a single source reference for the design of compounds using specialty elastomers.

This book defines specialty elastomers as heat-, oil-, fuel-, and solvent-resistant polymers. Each chapter examines individual elastomers in terms of development history, chemical composition, structure, and properties as well as processing methods, applications, and commercially available products. Covering their applications in the rubber, energy, chemicals, and oil industries, the book also discusses the use of antioxidants, antiozonants, vulcanization agents, plasticizers, and process aids for specialty elastomers. The concluding chapter details considerations and relevant processes-such as molding operations-involved in designing application-specific rubber components.

The Handbook of Specialty Elastomers provides comprehensive insight into the processes and challenges of designing rubber formulations and specialty elastomeric components.

Constitutive Models for Rubber XI is a comprehensive compilation of both the oral and poster contributions to the European Conference on Constitutive Models for Rubber. This 11th edition, held in Nantes (France) 25-27th June 2019, is the occasion to celebrate the 20th anniversary of the ECCMR series. Around 100 contributions reflect the state-of-the-art in the mechanics of elastomers. They cover the fields of: Material testing Constitutive modelling and finite element implementation Micromechanical aspects, and Durability (failure, fatigue and ageing) Constitutive Models for Rubber XI is of interest for developers and researchers involved in the rubber processing and CAE software industries, as well as for academics in nearly all disciplines of elastomer mechanics and technology.

This revised and expanded single-source reference analyzes all compounding material classes of dry rubber compounds, such as carbon blacks, platicizers and age resisters, integrating detailed information on how elastomers are built up. The work provides practical compounding tips on how to avoid oil or antioxidant bloom, how to adjust electrical conductivity and how to meet volume swell requirements.;This second edition: provides material on government regulations regarding rubber waste; presents current insights into the fast-growing polymer technology of thermoplastic elastomers; discusses the ramifications of the commercial availability of epoxidized natural rubber; and offers a comprehensive tabular chart on the properties of polymers.

Castable Polyurethane Elastomers is a practical guide to the production of castable polyurethane articles, from simple doorstops to complex items used in the military and nuclear industries. The book shows the progression from raw materials to prepolymer production, including the chemistry and functionality of the production processes. It provides a comprehensive look at various problem-solving and processing techniques, examining the selection of different types of systems on both the micro and macro levels. It also discusses curing and post-curing operations, conveying the importance of using the correct property for the application. Reorganized for better flow, this Second Edition: Describes new methods in the processing of castable polyurethanes Expands coverage of health and safety aspects Brings all standards up to date Castable Polyurethane Elastomers, Second Edition explains the production of polyurethane components, filling the gap between pure chemistry and trade information.

All aspects of our lives, industry, health, travel and leisure, are utterly reliant on rubber materials, yet typically this notion rarely occurs to us. Increasingly, greater demands are made on elastomeric compounds and we seek elevated performance in terms of improved physical and chemical properties. In particular, we have come to expect rubber components (tyres, vibration isolators, seals etc) to exhibit exceptional wear and fatigue resistance, often at elevated temperatures. Unsurprisingly then, the emphasis in characterising isochoric materials has shifted significantly away from understanding and modelling hyperelastic material behaviour, to a position where we can confi dently design and manufacture rubber components having the functionality and resilience to meet the dynamic loading and harsh environmental conditions that are prevalent today. In consequence, state-of-the-art technology in terms of dynamic response and fatigue resistance are strongly represented here along with numerous insights into advanced elastomers used in novel applications. This development is not at the expense of research devoted to current test procedures and the constitutive equations and algorithms that underpin finite element methods. As a result, Constitutive Models for Rubber VII is not only essential reading for undergraduates, postgraduates, academics and researchers working in the discipline, but also for all those designers and engineers involved in the improvement of machines and devices by introducing new and novel elastomers possessing elevated properties.

Due to their unique properties, rubber materials are found in multiple engineering applications such as tires, engine mounts, shock absorbers, flexible joints, seals, etc. Nevertheless, the complex nature of the behavior of such material makes it difficult to accurately model and predict the performance of these units. The challenge to correctly reproduce the observed characteristics of rubber elements necessitates detailed experimental investigations, development of accurate constitutive models, validation of techniques to identify material parameters and efficient numerical methods. Aspects regarding fatigue and damage in elastomers are not to be left aside, as they influence the durability of the products. State-of-the-art technology in terms of constitutive modeling, numerical implementation, damage and fatigue resistance are strongly represented in these Proceedings, along with insights into advanced elastomers to be used in novel applications. Topics included in this volume are: Ageing, Friction and abrasion, Adhesion, Swelling, Continuum mechanical models and numerical implementation, Hyperelasticity, Micro-mechanical approaches, Fracture and fatigue, Mullins effect, Strain induced crystallization, Thermal effects, Reinforcement and vulcanization, Design and applications, Smart elastomers. Constitutive Models for Rubber VIII is of interest not only for undergraduates, postgraduates, academics and researchers in the discipline, but also for all those design and development engineers in the industry.

All aspects of our lives, industry, health, travel and leisure, are utterly reliant on rubber materials, yet typically this notion rarely occurs to us. Increasingly, greater demands are made on elastomeric compounds and we seek elevated performance in terms of improved physical and chemical properties. In particular, we have come to expect rubber components (tyres, vibration isolators, seals etc) to exhibit exceptional wear and fatigue resistance, often at elevated temperatures. Unsurprisingly then, the emphasis in characterising isochoric materials has shifted significantly away from understanding and modelling hyperelastic material behaviour, to a position where we can confi dently design and manufacture rubber components having the functionality and resilience to meet the dynamic loading and harsh environmental conditions that are prevalent today. In consequence, state-of-the-art technology in terms of dynamic response and fatigue resistance are strongly represented here along with numerous insights into advanced elastomers used in novel applications. This development is not at the expense of research devoted to current test procedures and the constitutive equations and algorithms that underpin finite element methods. As a result, Constitutive Models for Rubber VII is not only essential reading for undergraduates, postgraduates, academics and researchers working in the discipline, but also for all those designers and engineers involved in the improvement of machines and devices by introducing new and novel elastomers possessing elevated properties.

Featuring the work one of the worlda (TM)s foremost authorities on rubber curing, this uniquely comprehensive resource provides valuable data that will allow researchers and engineers to find solutions to their own curing problems. It delves into a variety of current evaluation practices for unvulcanized and vulcanized rubber and curing methods, including the use of molds and injection molding. It also explores a number of solutions to on-going challenges with recycling scrap rubber. In all cases, theoretical treatments are offered in a didactic manner, so that readers not fully familiar with the terms can, nevertheless, easily understand the developments in this field.

Due to their unique properties, rubber materials are widely used for engineering applications such as tires, engine mounts, seals, shock absorbers, etc. The design of these highly technical parts frequently necessitates a great control of their response and high guarantees of reliability. These objectives are severe because they cover multiple physical phenomena. In addition, the complexity of these parts requires the use of powerful simulation methods such as the finite element method. In this context, the formulation of relevant constitutive equations and the development of relevant algorithms are essential prerequisites for the prediction of the mechanical response of elastomeric parts. The latest developments concerning constitutive modelling of rubber materials, and more generally the mechanics of elastomers, are collected in the present volume, including: constitutive modelling, physical mechanisms, fatigue and fracture, structural and industrial applications. Constitutive Models for Rubber V will be of interest to undergraduates, postgraduates and researchers in mechanical engineering and rubber mechanics.

"Provides the latest authoritative research on the developments, technology, and applications of rubbery materials. Presents structures, manufacturing techniques, and processing details for natural and synthetic rubbers, rubber-blends, rubber composites, and thermoplastic elastomers. 80% revised and rewritten material covers major advances since publication of the previous edition."

Elastomer Technology Handbook is a major new reference on the science and technology of engineered elastomers. This contributed volume features some of the latest work by international experts in polymer science and rubber technology. Topics covered include theoretical and practical information on characterizing rubbers, designing engineering elastomers for consumer and engineering applications, properties testing, chemical and physical property characterization, polymerization chemistry, rubber processing and fabrication methods, and rheological characterization. The book also highlights both conventional and emerging market applications for synthetic rubber products and emphasizes the latest technology advancements.
Elastomer Technology Handbook is a "must have" book for polymer researchers and engineers. It will also benefit anyone involved in the handling, manufacturing, processing, and designing of synthetic rubbers.

Reverse engineering is widely practiced in the rubber industry. Companies routinely analyze competitors' products to gather information about specifications or compositions. In a competitive market, introducing new products with better features and at a faster pace is critical for any manufacturer. Reverse Engineering of Rubber Products: Concepts, Tools, and Techniques explains the principles and science behind rubber formulation development by reverse engineering methods. The book describes the tools and analytical techniques used to discover which materials and processes were used to produce a particular vulcanized rubber compound from a combination of raw rubber, chemicals, and pigments. A Compendium of Chemical, Analytical, and Physical Test Methods Organized into five chapters, the book first reviews the construction of compounding ingredients and formulations, from elastomers, fillers, and protective agents to vulcanizing chemicals and processing aids. It then discusses chemical and analytical methods, including infrared spectroscopy, thermal analysis, chromatography, and microscopy. It also examines physical test methods for visco-elastic behavior, heat aging, hardness, and other features. A chapter presents important reverse engineering concepts. In addition, the book includes a wide variety of case studies of formula reconstruction, covering large products such as tires and belts as well as smaller products like seals and hoses. Get Practical Insights on Reverse Engineering from the Book's Case Studies Combining scientific principles and practical advice, this book brings together helpful insights on reverse engineering in the rubber industry. It is an invaluable reference for scientists, engineers, and researchers who want to produce comparative benchmark information, discover formulations used throughout the industry, improve product performance, and shorten the product development cycle.

This volume, the fourth in a series which began in 1979, covers a greater variety of subjects than any previous single volume. The basis of selection has been topical interest; hence the tailor-making of polymers to develop specific properties, methods of improving com pound processability and the use of rubbers in the oil industry are featured alongside a discussion of safety aspects. We have again sought the cooperation of the foremost authorities on the chosen subjects and have been delighted at the response which has yielded a list of authors of international repute. A. w. K. S. L. CONTENTS Preface v List of Contributors ix 1. Recent Developments in Synthetic Rubbers by Anionic Polymerization 1 I. G. HARGIS, R. A. LIVIGNI and S. L. AGGARWAL 2. Advances in Nitrile Rubber (NBR) 57 P. W. MILNER 3. Epoxidized Natural Rubber. 87 C. S. L. BAKER and I. R. GELLING 4. Process Aids and Plasticizers . 119 B. G. CROWTHER 5. A Review of Elastomers Used for Oilfield Sealing Environments . 159 W. N. K. REVOLTA and G. C. SWEET 6. Using Modern Mill Room Equipment . 193 H. ELLWOOD 7. Quality Requirements and Rubber Mixing . 221 P. S. JOHNSON 8. Health and Safety . . 253 B. G. WILLOUGHBY Index . 307 vii LIST OF CONTRIBUTORS s. L. AGGARWAL Gen Corp, Research Division, 2990 Gilchrist Road, Akron, Ohio 44305, USA C. S. L. BAKER Malaysian Rubber Producers' Research Association, Tun Abdul Razak Laboratory, Brickendonbury, Hertford SG13 8NL, UK B. G."

Imagine a world without rubber - neither tyres for motoring or flying, nor bouncing balls for sports, neither seals for washing machines and dishwashers, nor medical gloves - no elastics. This unique book tells the fascinating story of four thousand years of rubber - from its significance in Mayan religious rituals and culture to its pivotal role in today's world. It is seen through the lives of the adventurers and scientists who promoted it, lusted after it and eventually tamed it into the ubiquitous, yet crucial material of our lives today. It also examines the lives of those who caused the deaths of millions of natives in Africa and South America whilst seeking to satisfy the developing world's demand for this wonderful new material as well as their nemeses. Written in a biographical format, the book examines why rubber ages and deteriorates and how the ravages of time may be ameliorated. It deals with our current concern for the environment and various options for 'waste disposal'. For the majority of people, rubber is mostly an unknown history and even for those who think they know 'the truth' about rubber, this book may offer many surprises.

From weather-proof tires and artificial hearts to the o-rings and valve seals that enable successful space exploration, rubber is an indispensable component of modern civilization. Stiff competition and stringent application requirements foster continuous challenges requiring manufacturers to fund ever-expanding research projects. However, this vast and growing body of knowledge is jealously guarded by the rubber companies and not published in the open literature, leaving the novice or general researcher forced, as it were, to re-invent the wheel. Drawing on the expertise of leading researchers in their fields, Current Topics in Elastomers Research provides the first comprehensive overview of rubber research activities from around the world. Divided into seven sections, this seminal work begins with a general introduction before presenting the chemistry and structure-property relationships of a variety of new materials and composites. The second section covers the most important rubber ingredients along with the current thinking on their mechanism of action. Two important new characterization techniques, 3D-TEM and AFM, are evaluated in the third section, while the fourth considers the physics and engineering aspects of elastomers, including reinforcement mechanisms, viscoelastic properties, fatigue life, abrasion, adhesion, rheology, mixing and processing, and the effects of time, temperature and fluids. The fifth section pays respect to the tire, a driving impetus for research and one of the major applications of rubber. Finally, the book includes two chapters on eco-friendly technology and recycling, perhaps the most important engineering topic in this age of globalization and environmental responsibility. Barring the inaccessibility of truly classified information, Current Topics in Elastomers Research is a complete review of current elastomers research and applications, compiling once-guarded knowledge and

Rubber Compounding: Chemistry and Applications describes the production, processing, and characteristics of a wide range of materials utilized in the modern tire and rubber industry, from natural to butyl rubber, carbon black, silica, silanes, and beyond. Containing contributions from leading specialists in the field, the text investigates the chemistry and modification of raw materials, elastomers, and material compounds for the optimal formulation and engineering of new rubber products. This Second Edition of the bestselling first: Adds new sections on environmental issues and recycling Provides more information on hydraulic hose and conveyor belting Expands the discussion of tire technologies and industrial rubber products Includes new information on synthetic elastomers Features extensive references for further reading and exploration Rubber Compounding: Chemistry and Applications, Second Edition supplies the industrial compounder, teacher, or other academic scientist with basic information on materials used in the rubber industry. In addition, the book addresses a gap in the body of literature available to the chemists in industry and academia.

A World History of Rubber helps readers understand and gain new insights into the social and cultural contexts of global production and consumption, from the nineteenth century to today, through the fascinating story of one commodity. * Divides the coverage into themes of race, migration, and labor; gender on plantations and in factories; demand and everyday consumption; World Wars and nationalism; and resistance and independence * Highlights the interrelatedness of our world long before the age of globalization and the global social inequalities that persist today * Discusses key concepts of the nineteenth and twentieth centuries, including imperialism, industrialization, racism, and inequality, through the lens of rubber * Provides an engaging and accessible narrative for all levels that is filled with archival research, illustrations, and maps

This is a practical guide to cost-effective formulating of rubber compounds to achieve optimal processing and performance. It provides a thorough discussion of the principles of rubber compounding, rubber testing, and how various compound changes will affect different properties and test measurements. Rubber compounding is discussed as a series of interdependent systems such as the elastomer system, the filler-oil system, the cure system, among others. A holistic approach is used to show how changes in these different systems will affect specific compound properties. Much attention is given to trade-offs in properties and emphasis is placed on finding the best balance for compound cost, processing properties, and product performance. New in this third edition: new and revised content on recycled rubber, precipitated silica and non-black fillers, and silicone elastomers.

Taking a mechanistic approach that emphasizes the physical behavior of rubber as it slides, Analyzing Friction in the Design of Rubber Products and Their Paired Surfaces integrates the engineering and scientific evidence demonstrating that the laws of metallic friction do not apply to rubber. The book also presents a newly developed, scientifically based unified theory of rubber friction that incorporates a fourth basic rubber friction force: surface deformation hysteresis.

With applications that phenomenologically treat both static and dynamic rubber friction, the book offers practical guidance for implementing the unified theory in the analysis and design processes. The use of this theory enables comprehensive calculations of rubber friction, thereby offering opportunities to enhance public safety. While the theory applies to all elastomeric products where friction is an issue, the author primarily focuses on:

- Analyzing friction in the design of rubber tires and their contacted pavements

- The geometric design of roadways

- Motor vehicle accident reconstruction

- Analyzing slip resistance in the design of footwear and their contacted walking surfaces

Supported by extensive analytical evidence, this book details what rubber friction is and why it behaves the way it does.

Elastomer-Based Composite Materials: Mechanical, Dynamic, and Microwave Properties and Engineering Applications is focused on elastomer-based composite materials comprising different types of reinforcing fillers. The book provides an informative examination of the possibilities for broadening the engineering applications of elastomer composites through using various types of hybrid fillers, ferrites, and ceramics, and also examines their synthesis and characterization. It discusses new hybrid fillers that have been synthesized by different techniques, e.g. impregnation of different substrates (carbon black, conductive carbon black, activated carbons, etc.) with silica or magnetite. These new fillers have been thoroughly characterized by standard techniques and by up-to-date methods, such as energy dispersive X-ray spectroscopy in scanning transmission electron microscopy (STEM-EDX), atomic absorption spectroscopy (AAS), and inductively coupled plasma-optical emission spectroscopy (ICP-OES). The effect of those fillers upon the curing properties, mechanical and dynamic parameters, electrical conductivity, and dielectric and microwave characteristics of elastomer-based composites is discussed in detail in this volume. The book also covers the influence of various types of ceramics (SiC, B4C, and TiB2) and barium and strontium hexaferrites upon the aforementioned properties of rubber composites in conjunction with a view toward solutions for environmental problems caused by waste tires. The book shows that pyrolysis-cum-water vapor is a suitable and environmentally friendly method for the conversion of the waste green tires into useful carbon-silica hybrid fillers. The properties of elastomer-based composites comprising different types of nanostructures (fullerenes, carbon nanotubes, graphene nanoplatelets), modified activated carbons, and calcined kaolin are also discussed. Special attention is paid to composites with lower levels of zinc oxide. The volume provides an abundance of knowledge on the detailed characterization of these fillers and on the curing, mechanical, dynamic mechanical, and dielectric and microwave properties of the elastomeric composites. The book surveys the most recent research activities of the authors, which will make it a vital reference source for scientists in both the academic and industrial sectors, as well as for individuals who are interested in rubber materials. It will be very useful for students, especially PhD students, scientists, lecturers, and engineers working or doing research in the field of polymer materials science, elastomer-based composites and nanocomposites and their engineering applications in the production of microwave absorbers and electromagnetic waves shielding materials, materials for electronics devices and telecommunications.

One of the very few books devoted to the chemistry, materials and processing of liquid silicone rubber The scientific literature with respect to liquid silicone rubber is collected in this monograph. The text focuses on the fundamental issues such as properties, curing methods, special materials, as well as the latest developments, and provides a broad overview of the materials used therein. In particular, materials and compositions for liquid functional rubbers are discussed. Methods of curing and special properties are also described, such as tracking and erosion resistance, adhesion properties, storage and thermal stability. Methods of curing are precision casting, hybrid additive manufacturing, peroxide curing, ultraviolet curing, liquid injection moulding, or hot embossing. The book includes applications including automotive and underwater applications, electrical and optical uses, as well as medical uses.

This book provides a critical review of the equilibrium elastic properties of rubber, together with the kinetic-theory background. It is suitable for the non-specialist and the emphasis is on the physical reality embodied in the mathematical formulations. Polymer science had developed greatly since the second edition of this text in 1958, and the two main advances - the refinements of the network theory and associated thermodynamic analysis, and the development of the phenomenological or non-molecular approach to the subject - are both reflected in the structure of this third edition.

Originally published in 1913, this book provides a comprehensive discussion of rubber cultivation and the rubber industry. The text was written to appeal to as wide a readership as possible, combining an accurate account of the scientific side of rubber planting with practical information for the prospective planter. Illustrative figures and a bibliography are included. This book will be of value to anyone with an interest in the rubber industry, botany and the history of science.

Rubber elasticity is an important sub-field of polymer science. This book is in many ways a sequel to the authors' previous, more introductory book, Rubberlike Elasticity: A Molecular Primer (Wiley-Interscience, 1988), and will in some respects replace the now classic book by L.R.G. Treloar, The Physics of Rubber Elasticity (Oxford, 1975). The present book has much in common with its predecessor, in particular its strong emphasis on molecular concepts and theories. Similarly, only equilibrium properties are covered in any detail. Though this book treats much of the same subject matter, it is a more comprehensive, more up-to-date, and somewhat more sophisticated treatment.

Rubber is used in a vast number of products, from tyres on vehicles to disposable surgical gloves. Increasingly both manufacturers and legislators are realising that recycling is essential for environmental sustainability and can improve the cost of manufacture. The volume of rubber waste produced globally makes it difficult to manage as accumulated waste rubber, especially in the form of tyres, can pose a significant fire risk. Recycling rubber not only prevents this problem but can produce new materials with desirable properties that virgin rubbers lack. This book presents an up-to-date overview of the fundamental and applied aspects of renewability and recyclability of rubber materials, emphasising existing recycling technologies with significant potential for future applications along with a detailed outline of new technology based processing of rubber to reuse and recycle. This book will be of interest to researchers in both academia and industry as well as postgraduate students working in polymer chemistry, materials processing, materials science and engineering.