Volume 25: Optical Methods of Investigating Solid Bodies (Paperback, 1965 ed.)

The principal results of the work are as follows: 1. A simplified technique was devised for obtaining Raman spectra of powders. 2. The Raman and infrared absorption spectra of the following oxides were investigated: AsP3' SbP3' As 0 * SbP5. Te02. Ge02 (two forms) in the crystalline state, and ASP3' Ge02' Te0 in the glassy state. 2 5 2 3. The vibrational spectra of the crystalline and glassy forms of the oxides ASP3' Ge02' Te02 are simi- lar in many main respects, indicating a similarity of their structural units which determine the vibrational spec- tra of these substances. 4. By a study of the vibrational spectrum it was shown that arsenious anhydride has a molecular structure and consists of As0 molecules having symmetry of the point group Td' The force constants and vibration fre- 4 6 quencies of the As 0 molecule were calculated. and the vibrational spectrum of arsenious anhydride was re- 4 6 liably interpreted with the aid of these results. 5. A similar result was obtained for antimonous anhydride. consisting of Sb0 molecule.s with symmetry 4 6 ofthe point group Td. The force constants for this molecule were found and the vibrational spectrum was calculated.

General

Imprint:	Springer-Verlag New York
Country of origin:	United States
Series:	The Lebedev Physics Institute Series, 25
Release date:	April 2013
First published:	1965
Editors:	D V Skobel'tsyn
Dimensions:	279 x 210 x 11mm (L x W x T)
Format:	Paperback
Pages:	188
Edition:	1965 ed.
ISBN-13:	978-1-4684-7208-0
Categories:	Books > Science & Mathematics > Physics > Optics (light)
LSN:	1-4684-7208-9
Barcode:	9781468472080

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