This book is a systematic compilation of the most recent body of
knowledge in the rapidly developing research area of greenhouse gas
interaction with clay systems. Unexpected results of the most
recent studies - such as unusually high sorption capacity and
sorption hysteresis of swelling clays -stimulated theoretical
activity in this fascinating field. Classical molecular dynamics
(MD) explains swelling caused by intercalation of water molecules
and to a certain degree of CO2 molecules in clay interlayer.
However, unusual frequency shifts in the transient infrared
fingerprints of the intercalated molecules and the following
accelerated carbonation can be tackled only via quantum mechanical
modeling. This book provides a streamlined (from simple to complex)
guide to the most advanced research efforts in this field.
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