This book presents the fundamentals of novel gate dielectrics that are being introduced into semiconductor manufacturing to ensure the continuous scaling of CMOS devices. As this is a rapidly evolving field of research we choose to focus on the materials that determine the performance of device applications. Most of these materials are transition metal oxides. Ironically, the d-orbitals responsible for the high dielectric constant cause severe integration difficulties, thus intrinsically limiting high-k dielectrics. Though new in the electronics industry many of these materials are well-known in the field of ceramics, and we describe this unique connection. The complexity of the structure-property relations in TM oxides requires the use of state-of-the-art first-principles calculations. Several chapters give a detailed description of the modern theory of polarization, and heterojunction band discontinuity within the framework of the density functional theory. Experimental methods include oxide melt solution calorimetry and differential scanning calorimetry, Raman scattering and other optical characterization techniques, transmission electron microscopy, and X-ray photoelectron spectroscopy.

Many of the problems encountered in the world of CMOS are also relevant for other semiconductors such as GaAs. A comprehensive review of recent developments in this field is thus also given. The book will be of interest to those actively engaged in gate dielectric research, and to graduate students in Materials Science, Materials Physics, Materials Chemistry, and Electrical Engineering.

Today large numbers of geoscientists apply thermodynamic theory to solu tions of a variety of problems in earth and planetary sciences. For most problems in chemistry, the application of thermodynamics is direct and rewarding. Geoscientists, however, deal with complex inorganic and organic substances. The complexities in the nature of mineralogical substances arise due to their involved crystal structure and multicomponental character. As a result, thermochemical solutions of many geological-planetological problems should be attempted only with a clear understanding of the crystal-chemical and thermochemical character of each mineral. The subject of physical geochemistry deals with the elucidation and application of physico-chemical principles to geosciences. Thermodynamics of mineral phases and crystalline solutions form an integral part of it. Developments in mineralogic thermody namics in recent years have been very encouraging, but do not easily reach many geoscientists interested mainly in applications. This series is to provide geoscientists and planetary scientists with current information on the develop ments in thermodynamics of mineral systems, and also provide the active researcher in this rapidly developing field with a forum through which he can popularize the important conclusions of his work. In the first several volumes, we plan to publish original contributions (with an abundant supply of back ground material for the uninitiated reader) and thoughtful reviews from a number of researchers on mineralogic thermodynamics, on the application of thermochemistry to planetary phase equilibria (including meteorites), and on kinetics of geochemical reactions."

According to Bernie Meyerson, IBM's chief technology of?cer, the traditional sc- ing of semiconductor manufacturing processes died somewhere between the 1- and 90-nanometer nodes. One of the prime reasons is the low dielectric constant of SiO - thechoice dielectricof all modern electronics. This book presents materials 2 fundamentals of the novel gate dielectrics that are being introduced into semic- ductor manufacturing to ensure the Moore's law scaling of CMOS devices. This is a very rapidly evolving?eld of research and we try to focus on the basicundersta- ing of structure, thermodynamics, and electronic properties of these materials that determine their performance in the device applications. Thevolume was conceivedin 2001 afteraSymposium on Alternative Gate - electrics we had at the American Physical Society March Meeting in Seattle, upon the suggestion of the Kluwer editor Sabine Freisem. After several discussions we decided that such a bookindeed would be useful as long as we could focus on the fundamental side of the problem and keep the level of the discussion accessible to graduate students andavariety of professionals from different ?elds. The problem of?nding a replacement for SiO asa gate dielectric bringstogether inaunique way 2 many fundamental disciplines. At the same time this problem is truly applied and practical. It looked unlikelythat the perfect new material would be foundfast; rather there would be a series of evolving candidate materialsand approaches.

With an approach that stresses the fundamental solid state behaviour of minerals, and with emphasis on both theory and experiment, this text surveys the physics and chemistry of earth materials. It starts with a systematic tour of crystal chemistry of both simple and complex structures (with completely new structural drawings) and discusses how structural and thermodynamic information is obtained experimentally. The quantitative concepts of chemical bonding band theory, molecular orbit and ionic models are reviewed. The book goes on to discuss physical properties and to relate microscopic features to macroscopic thermodynamic behaviour. The book then discusses high pressure phase transitions, amorphous materials and solid state reactions, and concludes with a look at the interface between mineral physics and materials science. Highly illustrated throughout, this book is designed to fill the gap between undergraduate texts and specialized review volumes, for students in earth sciences and materials science.

Resonance phenomena have been the topic of a number of reviews, and separate questions have been elucidated in some monographs. But the absence of a bal anced integral account of the current status of the problem hinders the orientation in this area. The present book is an attempt to fill this gap. The results of investigations of the resonance scattering of electrons by atoms and ions are considered. We compare different theoretical methods of descrip tion of resonance phenomena, for example, the close-coupling method, R-matrix method, and diagonalization method. Special attention is paid to the analysis of the accuracy of the theoretical calculations and experimental data. Besides the conventional analytical solutions of a multiparticle problem, more recently developed methods, made possible by high speed computers, are discussed in detail. Several computer programs are scrutinized. This book is intended for physicists engaged in the problems of electronic and atomic collisions, and related areas such as plasma and laser physics. It should be of interest to university students and postgraduates."

With an approach that stresses the fundamental solid state behaviour of minerals, and with emphasis on both theory and experiment, this text surveys the physics and chemistry of earth materials. It starts with a systematic tour of crystal chemistry of both simple and complex structures (with completely new structural drawings) and discusses how structural and thermodynamic information is obtained experimentally. The quantitative concepts of chemical bonding band theory, molecular orbit and ionic models are reviewed. The book goes on to discuss physical properties and to relate microscopic features to macroscopic thermodynamic behaviour. The book then discusses high pressure phase transitions, amorphous materials and solid state reactions, and concludes with a look at the interface between mineral physics and materials science. Highly illustrated throughout, this book is designed to fill the gap between undergraduate texts and specialized review volumes, for students in earth sciences and materials science.