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Manipulation and Dilution Tools for Ruling Abundant Species "NMR is
dead" was the slogan heard in the late 1960s at least among
physicists, until John S. Waugh and his co-workers initiated a
series of new NMR experiments, which employed the coherent
modulation of interactions by strong radiofrequency fields. A
wealth of new phenomena was observed, which are summarized in the
introduction for the convenience of the unbiased reader, whereas
Section 2 collects the basic spin interactions observed in solids.
Line-narrowing effects in dipolar coupled solids by the application
of multiple pulse experiments are extensively discussed in Section
3. Numerous extensions of the basic Waugh, Huber, and Haeberlen
experiment have been developed by different groups and have been
applied to the nuclei IH, 9Be, 19F, 27Al, 31p, 63CU in solids.
Application of this technique to a variety of systems is still in
progress and should reveal interesting insights into weak spin
interactions in solids. It was soon realized that rare spins could
be used as monitors for molecular fields in the solid state;
however, rare spin observation is difficult because of the small
signal-to-noise ratio. Pines, Gibby, and Waugh introduced a new
concept of cross-polarization, based on ideas of Hahn and
co-workers, which allows the detection ofrare spins with increased
sensitivity. The dynamics involved are treated in detail. Other
sections merely list results obtained by the techniques described
and demonstrate their usefulness in the investigation of dynamical
problems in molec ular and solid state physics."
At the International Winter School on "Electronic Properties of
Polymers and Related Compounds" particular attention was paid to a
very new and special field in polymer research. It is concerned
with the study of the electronic structure of polymers and with
physical and chemical properties directly re lated to this
structure. In particular, tutorial and research contributions on
electrical, electrochemical, optical, magnetic, lattice dynamical
and structural properties were presented. In addition, review
reports on related topics such as charge transfer complexes and
linear-chain compounds (transi tion-metal trichalcogenides) were
included. In two discussion meEjtings, the special role of
polyacetylene and possible present and future applications of the
electronic properties of polymers, as e.g. conductors or as
electrodes in electrochemical cells, were elucidated. The
electronic properties of polymers cover a wide range of research
problems which are of particular interest for polymers with a
1T-electron system. Thus, a great part of the work presented was
concerned with conjuga ted systems. Additional presentations dealt
with other systems such as bio polymers, photopolymers or
electrets, which are of significant scientific and technical
importance. It was demonstrated how their electronic proper ties
are increasingly being investigated from a fundamental point of
view by applying known concepts of snlid-state science."
This book reviews the current understanding of electronic, optical
and magnetic properties of conjugated polymers in both the
semiconducting and metallic states. It introduces in particular
novel phenomena and concepts in these quasi one-dimensional
materials that differ from the well-established concepts valid for
crystalline semiconductors. After a brief introductory chapter, the
second chapter presents basic theore tical concepts and treats in
detail the various models for n-conjugated polymers and the
computational methods required to derive observable quantities.
Specific spatially localized structures, often referred to as
solitons, polarons and bipolarons, result naturally from the
interaction between n-electrons and lattice displacements. For a
semi-quantitative understanding of the various measure ments,
electron-electron interactions have to be incorporated in the
models; this in turn makes the calculations rather complicated. The
third chapter is devoted to the electrical properties of these
materials. The high metallic conductivity achieved by doping gave
rise to the expression conducting polymers, which is often used for
such materials even when they are in their semiconducting or
insulating state. Although conductivity is one of the most
important features, the reader will learn how difficult it is to
draw definite conclusions about the nature of the charge carriers
and the microscopic transport mechanism solely from electrical
measurements. Optical properties are discussed in the fourth
chapter."
The field of Nuclear Magnetic Resonance (NMR) has developed at a
fascinating pace during the last decade. It always has been an
extremely valuable tool to the organic chemist by supplying
molecular "finger print" spectra at the atomic level. Unfortunately
the high resolution achievable in liquid solutions could not be
obtained in solids and physicists and physical chemists had to live
with unresolved lines open to a wealth of curve fitting procedures
and a vast amount of speculations. High resolution NMR in solids
seemed to be a paradoxon. Broad structure less lines are usually
encountered when dealing with NMR in solids. Only with the recent
advent of mUltiple pulse, magic angle, cross-polarization,
two-dimen sional and multiple-quantum spectroscopy and other
techniques during the last decade it became possible to resolve
finer details of nuclear spin interactions in solids. I have felt
that graduate students, researchers and others beginning to get
involved with these techniques needed a book which treats the
principles, theo retical foundations and applications of these
rather sophisticated experimental techniques. Therefore I wrote a
monograph on the subject in 1976. Very soon new ideas led to the
developement of "two-dimensional spectroscopy" and
"multiple-quantum spectroscopy," topics which were not covered in
the first edition of my book. Moreover an exponential growth of
literature appeared in this area of research leaving the beginner
in an awkward situation of tracing back from a current article to
the roots of the experiment."
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