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During the last 25 years (after the growth of the first
pseudomorphic GeSi strained layers on Si by Erich Kasper in
Germany) we have seen a steady accu- mulation of new materials and
devices with enhanced performance made pos- sible by strain.
1989-1999 have been very good years for the strained-Iayer-
devices. Several breakthroughs were made in the growth and doping
technology of strained layers. New devices were fabricated as a
results of these break- throughs. Before the advent of strain layer
epitaxy short wavelength (violet to green) and mid-IR (2 to 5 f.
Lm) regions of the spectrum were not accessi- ble to the photonic
devices. Short wavelength Light Emitting Diodes (LEDs) and Laser
Diodes (LDs) have now been developed using III-Nitride and II-VI
strained layers. Auger recombination increases rapidly as the
bandgap narrows and temperature increases. Therefore it was
difficult to develop mid-IR (2 to 5 f. Lm range) lasers. The effect
of strain in modifying the band-structure and suppressing the Auger
recombination has been most spectacular. It is due to the strain
mediated band-structure engineering that mid-IR lasers with good
per- formance have been fabricated in several laboratories around
the world. Many devices based on strained layers have reached the
market place. This book de- scribes recent work on the growth,
characterization and properties o(compound semiconductors strained
layers and devices fabricated using them.
During the last 25 years (after the growth of the first
pseudomorphic GeSi strained layers on Si by Erich Kasper in
Germany) we have seen a steady accu- mulation of new materials and
devices with enhanced performance made pos- sible by strain.
1989-1999 have been very good years for the strained-Iayer-
devices. Several breakthroughs were made in the growth and doping
technology of strained layers. New devices were fabricated as a
results of these break- throughs. Before the advent of strain layer
epitaxy short wavelength (violet to green) and mid-IR (2 to 5 f.
Lm) regions of the spectrum were not accessi- ble to the photonic
devices. Short wavelength Light Emitting Diodes (LEDs) and Laser
Diodes (LDs) have now been developed using III-Nitride and II-VI
strained layers. Auger recombination increases rapidly as the
bandgap narrows and temperature increases. Therefore it was
difficult to develop mid-IR (2 to 5 f. Lm range) lasers. The effect
of strain in modifying the band-structure and suppressing the Auger
recombination has been most spectacular. It is due to the strain
mediated band-structure engineering that mid-IR lasers with good
per- formance have been fabricated in several laboratories around
the world. Many devices based on strained layers have reached the
market place. This book de- scribes recent work on the growth,
characterization and properties o(compound semiconductors strained
layers and devices fabricated using them.
The EC programme on Photovoltaic Power Generation has two distinct
parts pilot Projects and R&D contracts on cells, processes,
materials, IOOdules and systems. The pilot projects are managed in
a totally different w~ fran the R&D contracts. Enphasis ,is put
on all aspects of the system such as pcwer conditioning,
environmental factors, structures, etc. The aim is to examine all
different system aspects, to inprove the performance and the
reliability of the overall photovoltaic system and to reduce its
cost. A canprehensive overview of the PV pilot programme of the
European Gammunities was given in volume 1 of this Series C.
R&D contracts, on the other hand, are intended to advance our
kn0w- The ledge on all canponents in order to reduce the cost,
mainly of the photovoltaic IOOdules. This book reports on the
results presented at the sixth contractors' meeting, held about six
IlDnths before the end of the current R&D programme.
Amorphous silicon PV panel mass production will require to mas ter
plasma chemical deposition in terms of large sizes, cost,
maintenance and all other problems related to industrialization.
Since plasma deposition is a novel technique, the development of
all this production related know how involves a considerable
technical research effort. The major problems related to the design
of a production deposi tion machine are the following - deposition
should be uniform on very large area substrate (typical dimension 1
meter) ; - the deposited amorphous silicon should have good
electronic properties (density of state of the order or less than
16 3 10 cm /eV) and very low impurities concentrations (for exam
ple oxygen atomic concentration should idealy be less than 0. 01 %)
; - the film stress should be limited, the density of ponctual
defects (particulates) should remain reasonable (less than 2 per
100 cm ) ; - dopant level control should be stable and efficient ;
- silane consumption should remain reasonably efficient - financial
cost being important the machine productivity should be high hence
deposition rate optimized ; - downtime due to maintenance should be
reduced to a minimum. We present here some results on the R&D
effort addressed to the above mentioned problems. An original
single chamber was designed. This machine will be made available on
the market for R&D purposes by a process machine company.
Finally the maintenance problem is considered. Plasma cleaning
based on a fluorine containing etchant gases is studied and
evaluated. 2.
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