This book offers a comprehensive account of energetic materials, including their synthesis, computational modeling, applications, associated degradation mechanisms, environmental consequences and fate and transport. This multi-author contributed volume describes how armed forces around the world are moving their attention from legacy explosive compounds, which are heat and shock sensitive (thus posing greater challenges in terms of handling and storage), to the insensitive munitions compounds/formulations such as insensitive munitions explosive (IMX) and the Picatinny Arsenal Explosive (PAX) series of compounds. The description of energetic materials focuses on explosives, pyrotechnic compositions, and propellants. The contributors go on to explain how modern generation energetic compounds must be insensitive to shock and heat but at the same time yield more energy upon explosion. Nanoinspired and/or co-crystallized energetic materials offer another route to generate next-generation energetic materials, and this authoritative book bridges a large gap in the literature by providing a comprehensive analysis of these compounds. Additionally, it includes a valuable overview of energetic materials, a detailed discussion of recent advances on future energetic compounds, nanotechnology in energetic materials, environmental contamination and toxicity, assessment of munitions lethality, the application quantitative structure-activity relationship (QSAR) in design of energetics and the fate and transport of munition compounds in the environment.

This is the first comprehensive overview of this topic. It serves as a single source for information about the properties, preparation, and uses of all relevant primary explosives. The first chapter provides background such as the basics of initiation and differences between requirements on primary explosives used in detonators and igniters. The authors then clarify the influence of physical characteristics on explosive properties, focusing on those properties required for primary explosives. Furthermore, the issue of sensitivity is discussed. All the chapters on particular groups of primary explosives are structured in the same way, including introduction, physical and chemical properties, explosive properties, preparation and documented use. The authors thoroughly verified all data and information. A unique feature of this book are original microscopic images of some explosives.

This book reviews the development of research into the explosive loading of structures, mainly since the beginning of the twentieth century. Major contributions in the fields of measurement, analysis and prediction are discussed. Dynamic loading from conventional high explosives is examined, as well as the effects of liquid propellant, dust, gas, vapour, and fuel/air explosions. Subjects include blast in tunnels, underground and underwater explosions, pressure measurement and blast stimulation. Explosive effects on civil buildings, civil bridges, aircraft and ships are summarized, including the estimation of residual strength. The concluding passages refer to structural safety and reliability.

The sensitivity of an explosive is not a well defined property of the material but rather a complex pattern of behavior. Unlike the response to strong, planar shocks which is for the most part predictable and reproducible, explosives' response to multidimensional and weaker stimuli is much more complicated.

The present volume is the first compendium to assemble in a single text our present knowledge about the vast range of non-shock ignition mechanisms and responses, where initiation is not prompt, and involves a series of steps that may or may not lead to a steady detonation.

The 11 extensive chapters in this volume are: Context and Complexity of Non-Shock Initiation (B. W. Asay), Transport Phenomena for Non-Shock Initiation Processes (L. Perry), The Chemical Kinetics of Solid Thermal Explosions (B. F. Henson), Classical Theory of Thermal Criticality (L. G. Hill), Deflagration Phenomena in Energetic Materials (S. I. Jackson), Mechanical and Thermal Damage (G. R. Parker and P. J. Rae), Cook-off (B. W. Asay), The Deflagration-to-Detonation Transition (J. M. McAfee), Friction (P. M. Dickson), Impact and Shear Ignition by Non-Shock Mechanisms (J. E. Kennedy), Spark and Laser Ignition (J. E. Kennedy).

Each chapter is self-contained and can be read independently of the others, though, they are thematically interrelated. They offer a timely reference, for postgraduate students as well as professional scientists and engineers, by laying out the foundations and discussing the latest developments including yet unresolved challenging problems.

Nuclear quadrupole resonance (NQR) a highly promising new technique for bulk explosives detection: relatively inexpensive, more compact than NMR, but with considerable selectivity. Since the NQR frequency is insensitive to long-range variations in composition, mixing explosives with other materials, such as the plasticizers in plastic explosives, makes no difference. The NQR signal strength varies linearly with the amount of explosive, and is independent of its distribution within the volume monitored. NQR spots explosive types in configurations missed by the X-ray imaging method.

But if NQR is so good, why it is not used everywhere? Its main limitation is the low signal-to-noise ratio, particularly with the radio-frequency interference that exists in a field environment, NQR polarization being much weaker than that from an external magnetic field. The distinctive signatures are there, but are difficult to extract from the noise. In addition, the high selectivity is partly a disadvantage, as it is hard to build a multichannel system necessary to cover a wide range of target substances. Moreover, substances fully screened by metallic enclosures, etc. are difficult to detect. A workshop was held at St Petersburg in July 2008 in an attempt to solve these problems and make NQR the universal technique for the detection of bombs regardless of type. This book presents the essentials of the papers given there.

This book collects lectures of an international NATO-Russian Advanced Research Workshop on Detection and Disposal of Improvised Explosives (IE) used by terrorists. The disposal of IE is especially dangerous, because they are often much more unstable and mechanically more sensitive than commercial or military explosives. This text covers detection of explosives by different analytical methods and the different shape and compositions of the explosive charge, and offers up-to-date advice on handling and disposal.

This book collects lectures of an international NATO-Russian Advanced Research Workshop on Detection and Disposal of Improvised Explosives (IE) used by terrorists. The disposal of IE is especially dangerous, because they are often much more unstable and mechanically more sensitive than commercial or military explosives. This text covers detection of explosives by different analytical methods and the different shape and compositions of the explosive charge, and offers up-to-date advice on handling and disposal.

Gunpowder studies are still in their infancy despite the long-standing civil and military importance of this explosive since its discovery in China in the mid-ninth century AD. In this second volume by contributors who meet regularly at symposia of the International Committee for the History of Technology (ICOHTEC), the research is again rooted in the investigation of the technology of explosives manufacture, but the fact that the chapters range in scope from the Old World to the New, from sources of raw materials in south-east Asia to the complications of manufacture in the West, shows that the story is more than the simple one of how an intriguing product was made. This volume is the first to develop the implications of the subject, not just in the sense of relating it to changing military technologies, but in that of seeing the securing of gunpowder supplies as fundamental to the power of the state and imperial pretensions.The search for saltpetre, for example, an essential ingredient of gunpowder, became a powerful engine of sea-going European trade from the early seventeenth century. Smaller states like Venice were unable to form these distant connections, and so to sustain a gunpowder army. Stronger states like France and Britain were able to do so, and became even more powerful as the demand for improved explosives fostered national strengths - leading to a development of the sciences, especially chemistry, in the former case, and of manufacturing techniques in the latter.

The fast detection of explosives from the vapor phase would be one way to enhance the protection of society against terrorist attacks. Up to now the problem of detection of explosives, especially the location of explosives whether at large areas e. g. station halls, theaters or hidden in cars, aircraft cargo, baggage or explosives hidden in crowds e. g. suicide bombers or bombs in bags has not been solved. Smelling of explosives like dogs do seems to be a valuable tool for a security chain. In general different strategies can be adopt to the basic problem of explosive detection: * bulk detection * vapor detection Normally meetings cover both aspects and applications of the detection. Even though both methods might fulfill special aspects of a general security chain the underlying scientific questions differ strongly. Because of that the discussions of the scientists and practitioners from the different main directions are sometimes only less specific. Therefore the NATO Advisory Panel in Security-Related Civil Science and Technology proposed a small series of NATO ARW's which focuses on the different scientific aspects of explosives detection methods. This book is based on material presented at the first NATO ARW of this series in Moscow which covered the topic: Vapor and trace detection of explosives. The second ARW was held in St. Petersburg and treated the topic Bulk detection methods. The third workshop was held in Warwick and focused on electronic noses which cover a somewhat different aspect of vapor detection.

The fast detection of explosives from the vapor phase would be one way to enhance the protection of society against terrorist attacks. Up to now the problem of detection of explosives, especially the location of explosives whether at large areas e. g. station halls, theaters or hidden in cars, aircraft cargo, baggage or explosives hidden in crowds e. g. suicide bombers or bombs in bags has not been solved. Smelling of explosives like dogs do seems to be a valuable tool for a security chain. In general different strategies can be adopt to the basic problem of explosive detection: * bulk detection * vapor detection Normally meetings cover both aspects and applications of the detection. Even though both methods might fulfill special aspects of a general security chain the underlying scientific questions differ strongly. Because of that the discussions of the scientists and practitioners from the different main directions are sometimes only less specific. Therefore the NATO Advisory Panel in Security-Related Civil Science and Technology proposed a small series of NATO ARW's which focuses on the different scientific aspects of explosives detection methods. This book is based on material presented at the first NATO ARW of this series in Moscow which covered the topic: Vapor and trace detection of explosives. The second ARW was held in St. Petersburg and treated the topic Bulk detection methods. The third workshop was held in Warwick and focused on electronic noses which cover a somewhat different aspect of vapor detection.

This book contains papers presented at the NATO Advanced Research Workshop titled "Application of Gun and Rocket Propellants in Commercial Explosives." (SST.ARW975981) The workshop was organized in collaboration with codirector Dr. Bronislav V. Matseevich (KNIIM) and held in Krasnoarmeisk, Moscow Region, Russia, October 18-21, 1999. About 70 participants from 11 different countries took part in the meeting (Russia, Belarus, Czech Republic, Germany, Belgium, China, USA, Spain, Israel, Ukraine and the Netherlands). The workshop was principally the continuation of a previous NATO workshop on Conversion Concepts for Commercial Application and Disposal Technologies of Energetic Systems" held at Moscow, Russia, May 17-19, 1994 in the specific area of the reuse of gun and rocket propellants as ingredients in commercial explosives. Oldrich Machacek Vll ACKNOWLEDGMENTS I would like to thank Dr. B.V. Matseevich, Director of the Krasnoarmeisk Scientific Research Institute of Mechanization ("KNIIM") for his extensive involvement as co-director in organizing the Advanced Research Workshop in Krasnoarmeisk, Russia. Special thanks goes to Dr. V.P. Glinskij, Dr. LV. Vasiljeva and A.I. Fedonina from KNIIM and Dr. B. Vetlicky for invaluable assistance in preparation and the smooth operation ofthe workshop.

This book treats the experimental methods used to determine the physical properties of explosives and explosions - physical principles, operating procedures and evaluations of results. Aimed at practicing engineers as well as experimental physicists who investigate the effects of explosions, this book will be of interest to research laboratories, manufacturers of explosives, military training establishments, technical laboratories and so forth.

This comprehensive book presents a detailed account of research and recent developments in the field of green energetic materials, including pyrotechnics, explosives and propellants. This area is attracting increasing interest in the community as it undergoes a transition from using traditional processes, to more environmentally-friendly procedures. The book covers the entire line of research from the initial theoretical modelling and design of new materials, to the development of sustainable manufacturing processes. It also addresses materials that have already reached the production line, as well as considering future developments in this evolving field.

This book provides chemists with technical insight on pyrotechnics and explosives. It emphasizes basic chemical principles and practical, hands-on knowledge in the preparation of energetic materials. It examines the interactions between and adaptations of pyrotechnics to changing technology in areas such as obscuration science and low-signature flame emission. The updated third edition discusses chemical and pyrotechnic principles, components of high-energy materials, elements of ignition, propagation, and sensitivity. It offers heat compositions, including ignition mixes, delays, thermites, and propellants and investigates the production of smoke and sound as well as light and color.

This entertaining and informative book tells the dramatic tale of explosives from gunpowder to the H-bomb. Laying the emphasis on the lives of the people involved, on the diverse uses of explosives and on their social and historical impact, the author relates a story of remarkable international and human endeavour. Many of those involved - Roger Bacon, Guy Fawkes, Alfred Nobel, Robert Oppenheimer - are famed worldwide; others, such as C F Schonbein, William Bickford, Sir Frederick Abel and Charles E Munroe, though less well-known, also played critical roles. Alongside their achievements, this book highlights the uses and impact of explosives in both war and terrorism, and in civil engineering, quarrying, mining, demolition, fireworks manufacture and shooting for sport. In many cases explosives are seen to have had a significant historical impact as, for example, in the early use of gunpowder in the American Civil War, the defeat of the Spanish Armada, and the worldwide opening up of canals and railways.

From prehistory to the present-day conservation movement, Pyne explores the efforts of successive American cultures to master wildfire and to use it to shape the landscape.

"On rare occasions, the historical literature is enriched by the introduction of a broad new field for study, by a book that dramatically expands the boundaries of scholarly investigation. Stephen Pyne's Fire in America is such a book. It achieves the Promethean goal of bringing fire to history". -- Science

"Stephen J. Pyne compels our admiration for his gargantuan ambition and richly informed intelligence. He tells us more than anyone else to date has about the role of fire in the landscape, tells us we have been wrong in assuming a pristine state of nature before the white man's invasion, tells us what fire has meant to the rise of civilization and this nation. No one interested in environmental history can afford to ignore this massive achievement". -- Journal of American History

The book discusses new scientific developments in analysis of explosives and their applications. The areas of application include law enforcement, aviation security and environmental protection, subjects which are closely related to explosives analysis. The book is organised in six chapters covering explosive compounds and mixtures, chromatographic methods, mass spectrometric methods, analysis of explosives residues, environmental analysis of explosives and detection of hidden explosives. Modern Methods and Applications in Analysis of Explosives is written as a reference book for chemists in analytical and forensic laboratories, and for graduate students in analytical chemistry and forensic sciences.

How gunpowder technology exploded heroes, heroics, and war stories from 1400 to 1700, and how German writers tried to glue them back together Guns have been linked with masculinity since their earliest days on European battlefields, and surviving treatises on gunpowder from the early fifteenth century describe in detail the kinds of strong, sober, and God-fearing men who could be trusted to use this new weapon. As the destructive capacity and military tactical value of gunpowder became more evident to European peoples over time, writers--especially German ones--expressed increasing anxiety aboutthe disruptive potential that gunpowder weapons held for warrior masculinity, martial ethics, and the aesthetic traditions of war stories. Focused on early modern German texts of all kinds, including military manuals,poems, theological treatises, novels, and broadsheets, Gunpowder, Masculinity, and Warfare in German Texts, 1400-1700 traces the cultural and literary history of gunpowder in German-speaking lands from the Hussite Wars into the literary aftermath of the Thirty Years War. Taking a long view of this textual and material history, author Patrick Brugh reveals that early conversations about firearms resonate with those today, including debates on such topics as questions of masculine ethos and gun violence, the rights to self-defense and to bear arms, and the way new technologies change how we tell stories. PATRICK BRUGH is an affiliate assistant professor of Genderand Sexuality Studies at Loyola University Maryland and an administrator at Johns Hopkins University.

Energetic Nanomaterials: Synthesis, Characterization, and Application provides researchers in academia and industry the most novel and meaningful knowledge on nanoenergetic materials, covering the fundamental chemical aspects from synthesis to application. This valuable resource fills the current gap in book publications on nanoenergetics, the energetic nanomaterials that are applied in explosives, gun and rocket propellants, and pyrotechnic devices, which are expected to yield improved properties, such as a lower vulnerability towards shock initiation, enhanced blast, and environmentally friendly replacements of currently used materials. The current lack of a systematic and easily available book in this field has resulted in an underestimation of the input of nanoenergetic materials to modern technologies. This book is an indispensable resource for researchers in academia, industry, and research institutes dealing with the production and characterization of energetic materials all over the world.

Nuclear quadrupole resonance (NQR) a highly promising new technique for bulk explosives detection: relatively inexpensive, more compact than NMR, but with considerable selectivity. Since the NQR frequency is insensitive to long-range variations in composition, mixing explosives with other materials, such as the plasticizers in plastic explosives, makes no difference. The NQR signal strength varies linearly with the amount of explosive, and is independent of its distribution within the volume monitored. NQR spots explosive types in configurations missed by the X-ray imaging method.

But if NQR is so good, why it is not used everywhere? Its main limitation is the low signal-to-noise ratio, particularly with the radio-frequency interference that exists in a field environment, NQR polarization being much weaker than that from an external magnetic field. The distinctive signatures are there, but are difficult to extract from the noise. In addition, the high selectivity is partly a disadvantage, as it is hard to build a multichannel system necessary to cover a wide range of target substances. Moreover, substances fully screened by metallic enclosures, etc. are difficult to detect. A workshop was held at St Petersburg in July 2008 in an attempt to solve these problems and make NQR the universal technique for the detection of bombs regardless of type. This book presents the essentials of the papers given there.

Detection and quantification of trace chemicals is a major thrust of analytical chemistry. In recent years much effort has been spent developing detection systems for priority pollutants. Less mature are the detections of substances of interest to law enforcement and security personnel: in particular explosives. This volume will discuss the detection of these, not only setting out the theoretical fundamentals, but also emphasizing the remarkable developments in the last decade. Terrorist events airplanes blown out of the sky (PanAm 103 over Lockerbie) and attacks on U.S. and European cities (Trade Center in New York and the Murrah Federal Building in Oklahoma City, railways in London and Madrid)--emphasize the danger of concealed explosives. However, since most explosives release little vapor, it was not possible to detect them by technology used on most organic substances. After PanAm 103 was downed over Scotland, the U.S. Congress requested automatic explosive detection equipment be placed in airports. This volume outlines the history of explosive detection research, the developments along the way, present day technologies, and what we think the future holds.

- Written by experts in the field who set out both the scientific issues and the practical context with authority
- Discusses and describes the threat
- Describes the theoretical background and practical applications of both trace and bulk explosives detection"

This book begins with an account of the evolution of improvised explosive devices using a number of micro case studies to explore how and why actors have initiated IED campaigns; how new and old technologies and expertise have been exploited and how ethical barriers to IED development and deployment have been dealt with. It proceeds to bring the evidence from the case studies together to identify themes and trends in IED development, before looking at what can realistically be done to mitigate the threat of IEDs in the new wars of the twenty first century. The book suggests that the advance and availability of a combination of technological factors, in conjunction with changes in the nature of contemporary conflicts, have led to the emergence of IEDs as the paradigmatic weapons of new wars. However their prevalence in contemporary and future conflicts is not inevitable, but rather depends on the willingness of multiple sets of actors at different levels to build a web of preventative measures to mitigate - if not eradicate - IED development and deployment.

This volume provides an overview of current research and recent advances in the area of energetic materials, focusing on explosives and propellants. The contents and format reflect the fact that theory, experiment and computation are closely linked in this field.
The challenge of developing energetic materials that are less sensitive to accidental stimuli continues to be of critical importance. This volume opens with discussions of some determinants of sensitivity and its correlations with various molecular and crystal properties. The next several chapters deal in considerable detail with different aspects and mechanisms of the initiation of detonation, and its quantitative description. The second half of this volume focuses upon combustion. Extensive studies model ignition and combustion, with applications to different propellants. The final chapter is an exhaustive computational treatment of the mechanism and kinetics of combustion initiation reactions of ammonium perchlorate.
Overall, this volume illustrates the progress that has been made in the field of energetic materials and some of the areas of current activity. It also indicates the challenges involved in characterizing and understanding the properties and behaviour of these compounds. The work is a unique state-of-the-art treatment of the subject, written by pre-eminent researchers in the field.
- Overall emphasis is on theory and computation, presented in the context of relevant experimental work
- Presents a unique state-of-the-art treatment of the subject
- Contributors are preeminent researchers in the field

This unique book is a store of less well-known explosion and
detonation phenomena, including also data and experiences related to
safety risks. It highlights the shortcomings of the current
engineering codes based on a classical plane wave model of the
phenomenon, and why these tools must fail.
For the first time all the explosion phenomena are described in terms
of proper assemblages of hot spots, which emit pressure waves and
associated near field terms in flow. Not all of the approaches are
new. Some even date back to the 19th century or earlier.. What is new
is the application of these approaches to explosion phenomena. In
order to make these tools easily available to the current detonation
physicist, basic acoustics is therefore also addressed.
Whereas the current plane wave, homogeneous flow detonation physics
is an excellent engineering tool for numerical predictions under
given conditions, the multi-hot-spot-model is an additional tool for
analyzing phenomena that cannot be explained by classical
calculations. The real benefit comes from being able to understand,
without any artificial assumptions, the whole phenomenology of
detonations and explosions. By specifying pressure generating
mechanisms, one is able to see that the current treatment of the
detonics of energetic materials is only a very special - but powerful
- case of explosion events and hazards. It becomes clear that
physical explosions must be taken into account in any safety
considerations. In these terms it is easy to understand why even
liquid carbon dioxide and inert silo materials can explode.
A unique collection of unexpected events, which might surprise even
specialists, has resulted from the evaluation of the model. Therefore
this book is valuable for each explosion and safety scientist for the
understanding and forecasting of unwanted events. The text mainly
addresses the next generation of explosion and detonation scientists,
with the goal of promoting the science of detonation on a new
physical basis. For this reason gaps in current knowledge are also
addressed. The science of explosions is not fully mature, but is
still in its beginning - and the tools necessary for furthering the
understanding of these phenomena have been with us for centuries.

This timely book covers the most recent developments in the chemical detection of explosives in a variety of environments. Beginning with a broad view of the need for and the potential applications of chemical sensing, the book considers the issue of how to effectively include chemical sensing into systems designed to find hidden explosives devices. Offering a firsthand look at the latest technologies direct from those who are actively developing them, the book features: A look at the history of the field, including the contributions of recent programs A brief explanation of the chemistry of various explosives and differences in the place where they may be detected An introduction to the problems presented by trace element sensing An overview and comparison of the technologies currently being used and developed Case studies of field experiences with chemical sensors A look at the emerging threat of non-traditional explosives

This book is an important reference for explosives engineers, systems engineers involved in the development of related devices, government agencies and NGOs involved in demining efforts, military and law enforcement specialists in mines and explosive ordinance disposal (EOD), as well as environmental scientists and chemists involved in explosives research.

In addition to providing field workers with knowledge that will help them decide where and how to search for explosives using chemical sensors. It will provide them with an understanding of the potential and the limitations of chemical sensing in their search for and identification of dangerous devices.