Symposium LL, 'Scientific Basis for Nuclear Waste Management XXXVI', was held November 25-30 at the 2012 MRS Fall Meeting in Boston, Massachusetts. This Symposium continues to set the research agenda in the field of radioactive waste management, charting the development of waste processing, conditioning, packaging and disposal. Symposium XXXVI featured 77 presentations, delivered over four days during the 2012 MRS Fall Meeting, from participants in Australia, Austria, Finland, France, Japan, Russia, Spain, Sweden, Switzerland, the United Kingdom, and the United States of America. Sessions reported on advances in glass and ceramic wasteforms, conditioning of technetium, management of spent nuclear fuel, and geological disposal, plus a special joint session with Symposium HH, on radiation effects in nuclear materials. Each paper provides a snapshot of the exciting recent developments in each of these areas and the international progress toward achieving the safe, timely and cost-effective management and disposal of radioactive wastes.

Radioactive wastes are generated from a wide range of sources, including the power industry, and medical and scientific research institutions, presenting a range of challenges in dealing with a diverse set of radionuclides of varying concentrations. Conditioning technologies are essential for the encapsulation and immobilisation of these radioactive wastes, forming the initial engineered barrier required for their transportation, storage and disposal. The need to ensure the long term performance of radioactive waste forms is a key driver of the development of advanced conditioning technologies.
The Handbook of advanced radioactive waste conditioning technologies provides a comprehensive and systematic reference on the various options available and under development for the treatment and immobilisation of radioactive wastes. The book opens with an introductory chapter on radioactive waste characterisation and selection of conditioning technologies. Part one reviews the main radioactive waste treatment processes and conditioning technologies, including volume reduction techniques such as compaction, incineration and plasma treatment, as well as encapsulation methods such as cementation, calcination and vitrification. This coverage is extended in part two, with in-depth reviews of the development of advanced materials for radioactive waste conditioning, including geopolymers, glass and ceramic matrices for nuclear waste immobilisation, and waste packages and containers for disposal. Finally, part three reviews the long-term performance assessment and knowledge management techniques applicable to both spent nuclear fuels and solid radioactive waste forms.
With its distinguished international team of contributors, the Handbook of advanced radioactive waste conditioning technologies is a standard reference for all radioactive waste management professionals, radiochemists, academics and researchers involved in the development of the nuclear fuel cycle.
Provides a comprehensive and systematic reference on the various options available and under development for the treatment and immobilisation of radioactive wastesExplores radioactive waste characterisation and selection of conditioning technologies including the development of advanced materials for radioactive waste conditioningAssesses the main radioactive waste treatment processes and conditioning technologies, including volume reduction techniques such as compaction

Assuming no previous knowledge, this book provides comprehensive coverage for a first course in hazardous waste management for environmental engineers and managers. It is written primarily for generators of hazardous waste with a primary emphasis on source reduction, waste minimization, reuse, and recycling before waste disposal. The book provides guidance on how to determine the proper category of hazardous waste generators, with separate and distinct sets of requirements for the three different categories of generators, and gives basic supplemental guidance for transporters, storage, and disposal facilities. It covers proper completion of hazardous waste manifests and reports. The book explains record keeping, personnel training, and other requirements necessary to be in full compliance on inspections. A companion CD with regulatory forms, data is included.Selected Topics: Introductory history and overview of hazardous waste management laws, rules and regulations; a practical guide to complying with the regulations, including the identification of hazardous wastes; proper management of these wastes on-site; preparing generator annual reports, manifests, personnel safety training; hazardous waste management training for staff; proper record-keeping for future regulatory inspections.

360 Degree Waste Management, Volume Two: Biomedical, Pharmaceutical, and Industrial Waste and Remediation presents an interdisciplinary approach to understanding various types of biomedical, pharmaceutical, and industrial waste, including their origin, management, recycling, disposal, effects on ecosystems, and social and economic impacts. By applying the concepts of sustainable, affordable and integrated approaches for the improvement of waste management, the book confronts social, economic and environmental challenges. Thus, researchers, waste managers and environmental engineers will find critical information to identify long-term answers to problems of waste management that require complex understanding and analysis. Presenting key concepts in the management of biomedical and industrial waste, Volume Two of this two volume series includes aspects on microbiology of waste management, advanced treatment processes, environmental impacts, technological developments, economics of waste management and future implications.

Water, Land, and Forest Susceptibility and Sustainability, Volume 2: Insight Towards Management, Conservation and Ecosystem Services brings an interdisciplinary perspective to solving complex problems in sustainability, utilizing the latest research and technologies, and includes case studies that emphasize the applications of remote sensing, GIS, and image processing for addressing the current state and future needs to achieve sustainability. As forests, land, and water are among the most precious resources on earth, emphasizing the need to conserve them for future generations and, of course, a safe and sustainable planet. The assessment of the susceptibility of all these three precious resources must therefore be addressed to inform their sustainable management. This second volume focuses on environmental management, conservation, and ecosystem services and provides information on forest, land, and water resources, presenting in integrated manner various aspects of their characterization, susceptibility, and sustainability.

Advanced Organic Waste Management: Sustainable Practices and Approaches provides an integrated holistic approach to the challenges associated with organic waste management, particularly related to sustainability, lifecycle assessment, emerging regulations, and novel approaches for resource and energy recovery. In addition to traditional techniques, such as anaerobic digestion, composting, innovative and emerging techniques of waste recycling like hydrothermal carbonization and vermicomposting are included. The book combines the fundamentals and practices of sustainable organic waste management with successful case studies from developed and developing countries, highlighting practical applications and challenges. Sections cover global organic waste generation, encompassing sources and types, composition and characteristics, focus on technical aspects related to various resource recovery techniques like composting and vermicomposting, cover various waste-to-energy technologies, illustrate various environmental management tools for organic waste, present innovative organic waste management practices and strategies complemented by detailed case studies, introduce the circular bioeconomy approach, and more.

Marine Hydrocarbon Spill Assessments: From Risk of Spill through to Probabilities Estimates describes the methods used for estimating hydrocarbon spill risks and the potential consequences. Throughout the book, mathematical methodologies and algorithms are included to aid the reader in the solving of applied tasks presented. Marine Hydrocarbon Spill Assessments: From Risk of Spill through to Probabilities Estimates provides a fundamental understanding of the oil properties and processes which determine the persistence and impacts of oils in the marine environment. It informs the reader of the current research in hydrocarbon spill assessments, starting from an assessment of a risk of a spill, and moving on to modelling approaches to impact assessments, laboratory toxicity assessments, field impact assessments and response options, and prevention and contingency planning.

The Microbiology of Nuclear Waste Disposal is a state-of-the-art reference featuring contributions focusing on the impact of microbes on the safe long-term disposal of nuclear waste. This book is the first to cover this important emerging topic, and is written for a wide audience encompassing regulators, implementers, academics, and other stakeholders. The book is also of interest to those working on the wider exploitation of the subsurface, such as bioremediation, carbon capture and storage, geothermal energy, and water quality. Planning for suitable facilities in the U.S., Europe, and Asia has been based mainly on knowledge from the geological and physical sciences. However, recent studies have shown that microbial life can proliferate in the inhospitable environments associated with radioactive waste disposal, and can control the long-term fate of nuclear materials. This can have beneficial and damaging impacts, which need to be quantified.

Nuclear Corrosion: Research, Progress and Challenges, part of the "Green Book" series of the EFC, builds upon the foundations of the very first book published in this series in 1989 ("Number 1 - Corrosion in the Nuclear Industry"). This newest volume provides an overview on state-of-the-art research in some of the most important areas of nuclear corrosion. Chapters covered include aging phenomena in light water reactors, reprocessing plants, nuclear waste disposal, and supercritical water and liquid metal systems. This book will be a vital resource for both researchers and engineers working within the nuclear field in both academic and industrial environments.

Emerging Natural and Tailored Nanomaterials for Radioactive Waste Treatment and Environmental Remediation: Principles and Methodologies, Volume 29 provides an overview of the most important radionuclide sources in the environment, their interaction with environmental media, and appropriate remediation techniques. The book focuses on the assessment of radionuclide sorption behavior in contaminated sites and the synthesis of new materials for radionuclides remediation through sorption concepts. Chapters investigate the main interaction mechanisms between toxic/radioactive metal ions with natural and manmade materials, natural clay minerals and oxides, and novel nanomaterials, such as ordered mesoporous silicas, carbon nanotubes, graphene, and metal-organic framework-based materials. Techniques and models discussed include kinetics analysis, thermodynamic analysis, surface complexation models, spectroscopic techniques, and theoretical calculations.

Advanced separations technology is key to closing the nuclear fuel cycle and relieving future generations from the burden of radioactive waste produced by the nuclear power industry. Nuclear fuel reprocessing techniques not only allow for recycling of useful fuel components for further power generation, but by also separating out the actinides, lanthanides and other fission products produced by the nuclear reaction, the residual radioactive waste can be minimised. Indeed, the future of the industry relies on the advancement of separation and transmutation technology to ensure environmental protection, criticality-safety and non-proliferation (i.e., security) of radioactive materials by reducing their long-term radiological hazard. Advanced separation techniques for nuclear fuel reprocessing and radioactive waste treatment provides a comprehensive and timely reference on nuclear fuel reprocessing and radioactive waste treatment. Part one covers the fundamental chemistry, engineering and safety of radioactive materials separations processes in the nuclear fuel cycle, including coverage of advanced aqueous separations engineering, as well as on-line monitoring for process control and safeguards technology. Part two critically reviews the development and application of separation and extraction processes for nuclear fuel reprocessing and radioactive waste treatment. The section includes discussions of advanced PUREX processes, the UREX+ concept, fission product separations, and combined systems for simultaneous radionuclide extraction. Part three details emerging and innovative treatment techniques, initially reviewing pyrochemical processes and engineering, highly selective compounds for solvent extraction, and developments in partitioning and transmutation processes that aim to close the nuclear fuel cycle. The book concludes with other advanced techniques such as solid phase extraction, supercritical fluid and ionic liquid extraction, and biological treatment processes. With its distinguished international team of contributors, Advanced separation techniques for nuclear fuel reprocessing and radioactive waste treatment is a standard reference for all nuclear waste management and nuclear safety professionals, radiochemists, academics and researchers in this field.

First published in 1986: The Purpose of this book is to provide working managers with a comprehensive introduction to practical operational aspects of hazardous waste management and with an extremely important foundation in relevant laws, rules and regulations.

Decommissioning nuclear facilities is a relatively new field, which has developed rapidly in the last ten years. It involves materials that may be highly radioactive and therefore require sophisticated methods of containment and remote handling. The wastes arising from decommissioning are hazardous and have to be stored or disposed of safely in order to protect the environment and future generations. Nuclear decommissioning work must be carried out to the highest possible standards to protect workers, the general public and the environment. This book describes the techniques used for dismantling redundant nuclear facilities, the safe storage of radioactive wastes and the restoration of nuclear licensed sites.
* Describes the techniques used for dismantling nuclear facilities, safe storage of radioactive wastes, and the restoration of nuclear licensed facilities.
* Provides the reader with decommissioning experience accumulated over 15 years by UKAEA.
* Contains valuable information to personnel new to decommissioning and waste management.

Reprocessing and Recycling of Spent Nuclear Fuel presents an authoritative overview of spent fuel reprocessing, considering future prospects for advanced closed fuel cycles. Part One introduces the recycling and reprocessing of spent nuclear fuel, reviewing past and current technologies, the possible implications of Generation IV nuclear reactors, and associated safely and security issues. Parts Two and Three focus on aqueous-based reprocessing methods and pyrochemical methods, while final chapters consider the cross-cutting aspects of engineering and process chemistry and the potential for implementation of advanced closed fuel cycles in different parts of the world.

In this book, editor G Rasul Chaudhry presents a wide range of topics authored by researchers at the cutting edge of biodegradation and bioremediation. The book includes recent research describing how microorganisms clean soil and water, and how they remove toxic substances. It also presents information on how genetics and molecular biological methods are used to improve the ability of microorganisms to degrade a variety of substances.

TheI&ECSYMPOSIUMfromwhichthisvolumewasderivedfeatured519presen- tationsat88technicalsessionsduringathree-daymeetingonSeptember17-20, 1996in Birmingham,Alabamawith580registrants. Thefinalselectionsforthechaptersincluded hereinwerebasedonpeerreview,scientificmerit,theeditors'perceptionsoflastingvalue orinnovativefeatures, andthegeneralapplicabilityofeitherthetechnologyitselforthe scientificmethodsandscholarlydetailsprovidedbytheauthors. Thevolume isacontinuationofathemeinitiatedin 1990. Itspredecessors,Emerg- ing Technologies in Hazardous Waste Management, ACS Symposium Series No. 422 (1990), EmergingTechnologiesinHazardous WasteManagementII,ACSSymposiumSe- ries No. 468 (1991), Emerging Technologies in Hazardous WasteManagement III, ACS SymposiumSeriesNo. 518(1993), EmergingTechnologiesinHazardous WasteManage- mentIV, ACSSymposium Series No. 554 (1994),Emerging Technologies in Hazardous WasteManagement V. ACSSymposiumSeriesNo. 607(1995), andEmergingTechnolo- gies in Hazardous Waste Management VI, American AcademyofEnvironmental Engi- neersPublication (1996), arerelatedcontributionsonhazardouswastemanagement,but eachvolumeisessentiallydifferent. Byinspection,thereadermayquicklyrecognizethis diversity,andalsoconcludethatnosinglevolumecandojusticetothebreadthanddepth oftechnologiesbeingdevelopedandappliedinpractice. Thecontributionspresented in thisvolumearedivided intofourseparatebutcom- plementary sections, including: (1) Chemical and Thermal Treatment; (2) Biochemical Treatment;(3)SeparationTechnologies;and(4)RadioactiveWasteTreatment. D. WilliamTedder FrederickG. Pohland GeorgiaInstituteofTechnology UniversityofPittsburgh Atlanta, Georgia30332-0100 Pittsburgh,Pennsylvania15261-2294 v ACKNOWLEDGMENTS The Industrial & Engineering Chemistry (I&EC) Division ofACS organized and sponsored the symposium. ACS Corporate Associates was a majorfinancial cosponsor; theAmericanInstituteofChemicalEngineers(AIChE)EnvironmentalSciencesDivision, theAIChECenterforWasteReductionTechnologies,theAmericanAcademyofEnviron- mental Engineers,andtheJointAssociationfor theAdvancementsofSupercriticalFluid Technologywerenominalcosponsors;andEnviroExpocositedanexhibition. Thisgener- osity was essential to the overall successofthe symposium and is gratefully acknow- ledged. vii CONTENTS I. EmergingTechnologiesinHazardousWasteManagementVII:AnOverview...FrederickG. PohlandandD. WilliamTedder ChemicalandThermalMethods 2. GranularIronOxideasaCatalystinChemicalOxidationofOrganic Contaminants...9 MiratD. Gurol,Shu-SungLin,andNileshBhat 3. AnElectronBeamGeneratedPlasmaReactorforDecompositionof HalogenatedVOCs 23 S. A. Vitale, K. Hadidi,D. R. Cohn, L. Bromberg,andP. Falkos 4. IncinerationandThermalTreatmentofChemicalAgentsandChemicalWeapons 33 F. C. GouldinandE. M. Fisher 5. PredictingStabilityConstantsofVariousChelatingAgentsUsingQSAR Technology 49 R. W. Okey,S. Lin,andP. K. A. Hong 6. MineralizationofHazardousChemicalsbyHemeReaction ...69 GuyoungKang,JimoJung,KapsongPark,andDavidK. Stevens BiochemicalTreatment 7. AnaerobicTransformationsofCarbonTetrachloride:CombinedBacterialand AbioticProcesses 81 FlynnW. Picardal,SanggooKim,AnnaRadue,andDeberaBackhus 8. BiorecoveryofMetalsfromAcidMineDrainage...91 RakeshGovind,UmaKumar,RamaPuligadda,JimmyAntia,and HenryTabak ix x Contents 9. BiotreatmentofMinewater-ContainingCyanidesbyUsingImmobilizedCell Technology 103 Onguri K. Vijaya,G. R. V. Babu,JackAdams,JamesH. Wolfram,and KiritD. Chapatwala 10. Augmentationofin-SituSubsoilRemediationUsingColloidalGasDispersions 113 P. G. Chaphalkar,K. T. Valsaraj,D. Roy, W. D. Constant,andP. Lee 11. EffectofSorptionontheMicrobialReductiveDechlorinationofSoil-Bound Chloroalkenes 127 SpyrosG. PavlostathisandPingZhuang SeparationTechnologies 12. TheRemovalofVOCsfromExhaustAirandVapourCondensatesby MembraneProcesses ...

Hitherto the disposal of munitions was mostly concerned with obsolete stocks, but the political developments in the states of the former Soviet Union have necessitated the disposal of vast quantities of current and obsolete stocks. Obviously, open burning/open detonation cannot be used on such a large scale, not least for environmental considerations. There are two main technical problems associated with the disposal of munitions on the scale required. First, the materials are not simple wastes or rubbish. Their handling, storage, packaging and transportation are subject to very rigid regulation, and justifiably so, for obvious reasons. Second, they are very valuable goods, for which a high price has been paid by the holding states' economic systems. Mere destruction would mean the irretrievable loss of the value invested. But therein lies the problem. Goods like steel or brass scrap can easily be reclaimed, but hypergols and other rocket fuels (for instance) represent a true chemical challenge, while, under certain conditions, explosives may be diverted to civilian use. This, in summary, is the problem that the present book deals with: the two-pronged attack involving demilitarization and recycling technologies.

This companion to Accounting for Resources, 1 tracks the life cycle of specific elements, such as chlorine and heavy metals, in order to estimate the generation and dissipative losses of material wastes. The book begins with a succinct review of the life-cycle analysis methodology and evaluates some of its weaknesses in estimating the generation of waste. The authors propose a new quantitative measure of the potential for environmental harm of waste materials. They include case studies to add weight to their proposal. Four horizontal life-cycle case studies are included; one for chlorine and chlorine chemicals; one for mercury; one for arsenic and cadmium; and the other for copper, lead and zinc. The book also includes a longitudinal study of heavy metals use and dissipation, during the period 1880-1980 with reference to the Hudson-Raritan basin. The book concludes with an overview, including some recommendations for future research and for policy changes with respect to governmental statistical data collection and organization.

Every day throughout Britain, by road, by rail and by sea, there are large numbers of routine movements of radioactive cargo. Materials at all stages of the nuclear cycle, from uranium ore to nuclear waste, from nuclear warheads to radioactive isotopes used in medicine, are constantly on the move. In normal circumstances handling low-level material exposes workers to small doses of radiation, but a serious accident could lead to widespread contamination and to the major risk of additional deaths from cancer. The accident record is not good. There are repeated small accidents and many people believe that the major accident is simply waiting to happen. This book gives a thorough account of what is moved, by wham and far what purpose. It considers the risks, including that of terrorism, the safety record and the precautions. It also highlights the perils of the secrecy surrounding the industry: for example, local councils are responsible for coping with any accident, but are not told when or where nuclear movements are taking place. Martin Bond's careful work is a large step towards order in a chaotic industry. Originally published in 1992

Increasing demand on industrial capacity has, as an unintended consequence, produced an accompanying increase in harmful and hazardous wastes. Derived from the second edition of the popular Handbook of Industrial and Hazardous Wastes Treatment, Hazardous Industrial Waste Treatment outlines the fundamentals and latest developments in hazardous waste treatment in various process industries, such as metal finishing, photographic processing, wood treatment, and explosives. Comprehensive in scope, the book provides information that is directly applicable to daily waste management problems throughout the industry. The book contains in-depth discussions of environmental pollution sources, waste characteristics, control technologies, management strategies, facility innovations, process alternatives, costs, case histories, effluent standards, and future trends for the process industry. It includes extensive bibliographies for each type of industrial process waste treatment or practice, invaluable information to anyone who needs to trace, follow, duplicate, or improve on a specific process waste treatment practice. A quick scan of the chapters and contributors reveals the depth and breadth of the book's coverage. Hazardous Industrial Waste Treatment provides technical and economical information on how to develop the most feasible total environmental control program that can benefit both industry and local municipalities.

This book explores state-of-art techniques based on methodological and modeling aspects of solid and hazardous waste management, specifically focusing on the recent trends in data acquisition and robust modeling of the results obtained. In addition to an in-depth description of the recent regulatory paradigm for solid waste disposal and revealing insights into solid waste management models, the book also addresses significant case history and remediation methodologies for sustainable development in emerging economies like India, China and Brazil. The main emphasis is on a suitable regulatory framework with site-specific baseline calibration and aimed at the robust modeling of contaminant transport and its remediation. This is based on instructive case history in various locations/regions worldwide. The focus on recent modeling and quantification methods is the backbone of the book. One of the major aspects discussed is the application of non-invasive methods for studies related to the Earth's interior, which are increasingly preferred over invasive techniques thanks to their economic utility, as well as robust techniques for the interpretation of geophysical data. The increasing demand for groundwater and energy resources, especially for rapidly emerging countries with large populations like India and China, has made it vital to derive safe utilization approaches for our resources, including suitable waste disposal and remediation methodologies that can be adopted for 'contaminated sites.'

Nuclear Decommissioning Case Studies: Characterization, Waste Management, Reuse and Recycle, Author’s Statement on the Sustainability of Nuclear Decommissioning, Volume Six presents a selection of global case studies that focus on a range of technologies for the decontamination, dismantling, spent fuel treatment and recycling of nuclear decommissioning. The book presents best practices by analyzing errors and inadequacies, leading the reader to sound decision-making. The events covered in this publication range from national and local legislation, to regulatory positions, statements or recommendations, licensing steps and transition phases. Decommissioning experts, including regulators, operators, waste managers, researchers and academics will find this book to be suitable supplementary material to Michele Laraia’s reference works on the theory and applications of nuclear decommissioning. Alongside the other case studies books in this series, readers will obtain an understanding of various key case studies-what happened and what we can learn from them, to help supplement, solidify and strengthen their understanding of the topic.

Bio-Based Materials and Wastes for Energy Generation and Resource Management is the fifth and final volume in the series, Advanced Zero Waste Tools: Present and Emerging Waste Management Practices. It addresses processes and practices for utilizing bio-based materials and wastes to support efforts to promote a more sustainable society and provide readers with a better understanding of the major mechanisms required to achieve zero waste in different fields. This book covers numerous mechanisms supported by scientific evidence and case studies, as well as in-depth flowcharts and process diagrams to allow for readers to adopt these processes. Summarizing present and emerging zero waste tools on the scale of both experimental and theoretical models, Advanced Zero Waste Tools is the first step toward understanding the state-of-the-art practices in making the zero waste goal a reality. In addition to environmental and engineering principles, it also covers economic, toxicologic, and regulatory issues, making it an important resource for researchers, engineers, and policymakers working toward environmental sustainability.