Symposium LL, 'Scientific Basis for Nuclear Waste Management XXXVI', was held November 25-30 at the 2012 MRS Fall Meeting in Boston, Massachusetts. This Symposium continues to set the research agenda in the field of radioactive waste management, charting the development of waste processing, conditioning, packaging and disposal. Symposium XXXVI featured 77 presentations, delivered over four days during the 2012 MRS Fall Meeting, from participants in Australia, Austria, Finland, France, Japan, Russia, Spain, Sweden, Switzerland, the United Kingdom, and the United States of America. Sessions reported on advances in glass and ceramic wasteforms, conditioning of technetium, management of spent nuclear fuel, and geological disposal, plus a special joint session with Symposium HH, on radiation effects in nuclear materials. Each paper provides a snapshot of the exciting recent developments in each of these areas and the international progress toward achieving the safe, timely and cost-effective management and disposal of radioactive wastes.

Radioactive wastes are generated from a wide range of sources, including the power industry, and medical and scientific research institutions, presenting a range of challenges in dealing with a diverse set of radionuclides of varying concentrations. Conditioning technologies are essential for the encapsulation and immobilisation of these radioactive wastes, forming the initial engineered barrier required for their transportation, storage and disposal. The need to ensure the long term performance of radioactive waste forms is a key driver of the development of advanced conditioning technologies.
The Handbook of advanced radioactive waste conditioning technologies provides a comprehensive and systematic reference on the various options available and under development for the treatment and immobilisation of radioactive wastes. The book opens with an introductory chapter on radioactive waste characterisation and selection of conditioning technologies. Part one reviews the main radioactive waste treatment processes and conditioning technologies, including volume reduction techniques such as compaction, incineration and plasma treatment, as well as encapsulation methods such as cementation, calcination and vitrification. This coverage is extended in part two, with in-depth reviews of the development of advanced materials for radioactive waste conditioning, including geopolymers, glass and ceramic matrices for nuclear waste immobilisation, and waste packages and containers for disposal. Finally, part three reviews the long-term performance assessment and knowledge management techniques applicable to both spent nuclear fuels and solid radioactive waste forms.
With its distinguished international team of contributors, the Handbook of advanced radioactive waste conditioning technologies is a standard reference for all radioactive waste management professionals, radiochemists, academics and researchers involved in the development of the nuclear fuel cycle.
Provides a comprehensive and systematic reference on the various options available and under development for the treatment and immobilisation of radioactive wastesExplores radioactive waste characterisation and selection of conditioning technologies including the development of advanced materials for radioactive waste conditioningAssesses the main radioactive waste treatment processes and conditioning technologies, including volume reduction techniques such as compaction

Water, Land, and Forest Susceptibility and Sustainability, Volume 2: Insight Towards Management, Conservation and Ecosystem Services brings an interdisciplinary perspective to solving complex problems in sustainability, utilizing the latest research and technologies, and includes case studies that emphasize the applications of remote sensing, GIS, and image processing for addressing the current state and future needs to achieve sustainability. As forests, land, and water are among the most precious resources on earth, emphasizing the need to conserve them for future generations and, of course, a safe and sustainable planet. The assessment of the susceptibility of all these three precious resources must therefore be addressed to inform their sustainable management. This second volume focuses on environmental management, conservation, and ecosystem services and provides information on forest, land, and water resources, presenting in integrated manner various aspects of their characterization, susceptibility, and sustainability.

Marine Hydrocarbon Spill Assessments: From Risk of Spill through to Probabilities Estimates describes the methods used for estimating hydrocarbon spill risks and the potential consequences. Throughout the book, mathematical methodologies and algorithms are included to aid the reader in the solving of applied tasks presented. Marine Hydrocarbon Spill Assessments: From Risk of Spill through to Probabilities Estimates provides a fundamental understanding of the oil properties and processes which determine the persistence and impacts of oils in the marine environment. It informs the reader of the current research in hydrocarbon spill assessments, starting from an assessment of a risk of a spill, and moving on to modelling approaches to impact assessments, laboratory toxicity assessments, field impact assessments and response options, and prevention and contingency planning.

The Microbiology of Nuclear Waste Disposal is a state-of-the-art reference featuring contributions focusing on the impact of microbes on the safe long-term disposal of nuclear waste. This book is the first to cover this important emerging topic, and is written for a wide audience encompassing regulators, implementers, academics, and other stakeholders. The book is also of interest to those working on the wider exploitation of the subsurface, such as bioremediation, carbon capture and storage, geothermal energy, and water quality. Planning for suitable facilities in the U.S., Europe, and Asia has been based mainly on knowledge from the geological and physical sciences. However, recent studies have shown that microbial life can proliferate in the inhospitable environments associated with radioactive waste disposal, and can control the long-term fate of nuclear materials. This can have beneficial and damaging impacts, which need to be quantified.

Nuclear Corrosion: Research, Progress and Challenges, part of the "Green Book" series of the EFC, builds upon the foundations of the very first book published in this series in 1989 ("Number 1 - Corrosion in the Nuclear Industry"). This newest volume provides an overview on state-of-the-art research in some of the most important areas of nuclear corrosion. Chapters covered include aging phenomena in light water reactors, reprocessing plants, nuclear waste disposal, and supercritical water and liquid metal systems. This book will be a vital resource for both researchers and engineers working within the nuclear field in both academic and industrial environments.

Emerging Natural and Tailored Nanomaterials for Radioactive Waste Treatment and Environmental Remediation: Principles and Methodologies, Volume 29 provides an overview of the most important radionuclide sources in the environment, their interaction with environmental media, and appropriate remediation techniques. The book focuses on the assessment of radionuclide sorption behavior in contaminated sites and the synthesis of new materials for radionuclides remediation through sorption concepts. Chapters investigate the main interaction mechanisms between toxic/radioactive metal ions with natural and manmade materials, natural clay minerals and oxides, and novel nanomaterials, such as ordered mesoporous silicas, carbon nanotubes, graphene, and metal-organic framework-based materials. Techniques and models discussed include kinetics analysis, thermodynamic analysis, surface complexation models, spectroscopic techniques, and theoretical calculations.

First published in 1986: The Purpose of this book is to provide working managers with a comprehensive introduction to practical operational aspects of hazardous waste management and with an extremely important foundation in relevant laws, rules and regulations.

Advanced separations technology is key to closing the nuclear fuel cycle and relieving future generations from the burden of radioactive waste produced by the nuclear power industry. Nuclear fuel reprocessing techniques not only allow for recycling of useful fuel components for further power generation, but by also separating out the actinides, lanthanides and other fission products produced by the nuclear reaction, the residual radioactive waste can be minimised. Indeed, the future of the industry relies on the advancement of separation and transmutation technology to ensure environmental protection, criticality-safety and non-proliferation (i.e., security) of radioactive materials by reducing their long-term radiological hazard. Advanced separation techniques for nuclear fuel reprocessing and radioactive waste treatment provides a comprehensive and timely reference on nuclear fuel reprocessing and radioactive waste treatment. Part one covers the fundamental chemistry, engineering and safety of radioactive materials separations processes in the nuclear fuel cycle, including coverage of advanced aqueous separations engineering, as well as on-line monitoring for process control and safeguards technology. Part two critically reviews the development and application of separation and extraction processes for nuclear fuel reprocessing and radioactive waste treatment. The section includes discussions of advanced PUREX processes, the UREX+ concept, fission product separations, and combined systems for simultaneous radionuclide extraction. Part three details emerging and innovative treatment techniques, initially reviewing pyrochemical processes and engineering, highly selective compounds for solvent extraction, and developments in partitioning and transmutation processes that aim to close the nuclear fuel cycle. The book concludes with other advanced techniques such as solid phase extraction, supercritical fluid and ionic liquid extraction, and biological treatment processes. With its distinguished international team of contributors, Advanced separation techniques for nuclear fuel reprocessing and radioactive waste treatment is a standard reference for all nuclear waste management and nuclear safety professionals, radiochemists, academics and researchers in this field.

Achieving environmental sustainability with rapid industrialization is a major challenge of current scenario worldwide. As globally evident, industries are the key economic drivers, but are also the major polluters as untreated/partially treated effluents discharged from the industries is usually thrown into the aquatic resources and also dumped unattended. Industrial effluents are considered as the major sources of environmental pollution as these contains highly toxic and hazardous pollutants, which reaches far off areas due to the medium of dispersion and thus, create ecological nuisance and health hazards in living beings. Hence, there is an urgent to find ecofriendly solution to deal with industrial waste, and develop sustainable methods for treating/detoxifying wastewater before its release into the environment. Being a low cost and eco-friendly clean technology, bioremediation can be a sustainable alternative to conventional remediation technologies for treatment and management of industrial wastes to protect public health and environment. Therefore, this book (Volume I) covers the bioremediation of different industrial wastes viz. tannery wastewater, pulp and paper mill wastewater, distillery wastewater, acid mine tailing wastes, and many more; which are lacking in a comprehensive manner in previous literature at one place. A separate chapter dedicated to major industries and type of waste produced by them is also included. This book will appeal to students, researchers, scientists, industry persons and professionals in field of microbiology, biotechnology, environmental sciences, eco-toxicology, environmental remediation and waste management and other relevant areas, who aspire to work on the biodegradation and bioremediation of industrial wastes for environmental safety.

Healthy environment is important for any kind of biota on earth. It provides the basic elements of life such as clean water, fresh air, fertile soil and supports ecosystem of the food chain. Pollution drastically alters quality of the environment by changing the physico-chemical and biological aspects of these components. Accordingly, toxic metals, combustible and putrescible substances, hazardous wastes, explosives and petroleum products are all examples of inorganic and organic compounds that cause contaminations. Specifically, pollution of toxic and heavy metal in the environment is a growing problem worldwide, currently at an alarming rate. Toxic metals threaten the aquatic ecosystems, agriculture and ultimately human health. Traditional treatment techniques offer certain advantages such as rapid processing, ease of operation and control and flexibility. But, they could not maintain the quality of the environment due to the high operational costs of chemicals used, high energy consumption and handling costs for sludge disposal and overburden of chemical substances which irreversibly affect and destroy biodiversity, which ultimately render the soil useless as a medium for plant growth. Therefore, bioremediation and biotechnology, carried out by living assets to clean up, stabilize and restore contaminated ecosystems, have emerged as promising, environmental friendly and affordable approaches. Furthermore, the use of microbes, algae, transgenic plants and weeds adapted to stressful environments could be employed to enhance accumulation efficiency. Hence, sustainable and inexpensive processes are fast emerging as a viable alternative to conventional remediation methods, and will be most suitable for developing countries. In the current volume, we discuss pollution remediation challenges and how living organisms and the latest biotechnological techniques could be helpful in remediating the pollution in ecofriendly and sustainable ways.

Decommissioning nuclear facilities is a relatively new field, which has developed rapidly in the last ten years. It involves materials that may be highly radioactive and therefore require sophisticated methods of containment and remote handling. The wastes arising from decommissioning are hazardous and have to be stored or disposed of safely in order to protect the environment and future generations. Nuclear decommissioning work must be carried out to the highest possible standards to protect workers, the general public and the environment. This book describes the techniques used for dismantling redundant nuclear facilities, the safe storage of radioactive wastes and the restoration of nuclear licensed sites.
* Describes the techniques used for dismantling nuclear facilities, safe storage of radioactive wastes, and the restoration of nuclear licensed facilities.
* Provides the reader with decommissioning experience accumulated over 15 years by UKAEA.
* Contains valuable information to personnel new to decommissioning and waste management.

Nuclear Decommissioning Case Studies: Characterization, Waste Management, Reuse and Recycle, Author’s Statement on the Sustainability of Nuclear Decommissioning, Volume Six presents a selection of global case studies that focus on a range of technologies for the decontamination, dismantling, spent fuel treatment and recycling of nuclear decommissioning. The book presents best practices by analyzing errors and inadequacies, leading the reader to sound decision-making. The events covered in this publication range from national and local legislation, to regulatory positions, statements or recommendations, licensing steps and transition phases. Decommissioning experts, including regulators, operators, waste managers, researchers and academics will find this book to be suitable supplementary material to Michele Laraia’s reference works on the theory and applications of nuclear decommissioning. Alongside the other case studies books in this series, readers will obtain an understanding of various key case studies-what happened and what we can learn from them, to help supplement, solidify and strengthen their understanding of the topic.

Bio-Based Materials and Wastes for Energy Generation and Resource Management is the fifth and final volume in the series, Advanced Zero Waste Tools: Present and Emerging Waste Management Practices. It addresses processes and practices for utilizing bio-based materials and wastes to support efforts to promote a more sustainable society and provide readers with a better understanding of the major mechanisms required to achieve zero waste in different fields. This book covers numerous mechanisms supported by scientific evidence and case studies, as well as in-depth flowcharts and process diagrams to allow for readers to adopt these processes. Summarizing present and emerging zero waste tools on the scale of both experimental and theoretical models, Advanced Zero Waste Tools is the first step toward understanding the state-of-the-art practices in making the zero waste goal a reality. In addition to environmental and engineering principles, it also covers economic, toxicologic, and regulatory issues, making it an important resource for researchers, engineers, and policymakers working toward environmental sustainability.

The latest edition of this book brings together a wide range of occupational safety and health recommendations and practices directly applying to hazardous waste site cleanups. In addition to providing the most current information on maximum protection for cleanup personnel, this book is a practical, authoritative guide for those involved in cleanup operations.
The completely updated third edition cites the newest OSHA and NIOSH recommendations that have developed over the past decade and explores the new federal emphasis in hazardous waste site cleanups such as radiation safety, toxicology, unexploded ordnance, OSHA training, EPA training, and site health and safety plans.
Covers a wide array of occupational safety and health practices and recommendations applicable to hazardous waste clean-up
Provides the most up-to-date information on maximum protection for workers
Cites the newest OSHA and NIOSH recommendations and explores federal government emphases in the area

Many engineers, from the chemical and process industries, waste treatment system management and design to the clean-up of contaminated sites, are engaged in careers that address hazardous wastes. However, no single book is available that explains how to manage the risks of those wastes. At best it is dealt with in diverse sections of books on the general field of environmental engineering, and in various treatments of the subject of risk, statistics and hazard assessment.
This is a reference and text that blends together theoretical explanations, techniques and case study examples to complement practical knowledge. These include problems with solutions, case studies of current and landmark hazardous waste problems, a companion website, and reference sections that will make certain that this text stays on the practicing engineer's bookshelf.
- Addresses a subject of theoretical and regulatory importance
- The only book to take this approach
- Includes textbook case studies and examples as well as practical advice

The Treatment of Pharmaceutical Wastewater: Innovative Technologies and the Adaptation of Treatment Systems covers the various aspects of pharmaceutical sources, treatment technologies, their harmful effects on the natural environment, and new technological developments and upgrading of existing treatment systems. This book highlights the 3Rs (reduce, reuse, recycle) applied to treatment and resource recovery systems for pharmaceutical treatment. Case studies are included to enable fuller understanding of the practical aspects of treatment and modeling. This helpful guide is for civil and environmental engineers and researchers who want to understand the complex nature and treatment schemes for pharmaceutical wastewaters.

In this book, editor G Rasul Chaudhry presents a wide range of topics authored by researchers at the cutting edge of biodegradation and bioremediation. The book includes recent research describing how microorganisms clean soil and water, and how they remove toxic substances. It also presents information on how genetics and molecular biological methods are used to improve the ability of microorganisms to degrade a variety of substances.

Hazardous Waste Compliance concentrates on government regulations as they relate to hazardous waste and other hazardous materials. The main focus of this book is on how to comply with these requirements as well as on other best management practices (BMP), which will ensure worker safety and business protection from the risk of the commercial penalties associated with regulations breaches.
The authors provide the reader with useful techniques to enhance worker protection and promote efficiency, productivity and cost effectiveness, along with achieving the necessary quality standards for the work being performed. The authors further outline and define methods to help reduce worker injury and illness, the scope and application of HAZWOPER, and ways to implement hazardous material related requirements through enhancements of existing programs.
In addition, detailed discussion helps to provide methods to help promote consistency in health and safety program development for handling hazardous materials, encourage a high standard for health and safety, and share lessons learned to help provide approaches that have been implemented on hazardous waste and other sites.

Provides a comprehensive overview of regulatory requirements in the industry
Real-life experiences are presented in the form of case histories
A training aid for both new and experienced site workers

TheI&ECSYMPOSIUMfromwhichthisvolumewasderivedfeatured519presen- tationsat88technicalsessionsduringathree-daymeetingonSeptember17-20, 1996in Birmingham,Alabamawith580registrants. Thefinalselectionsforthechaptersincluded hereinwerebasedonpeerreview,scientificmerit,theeditors'perceptionsoflastingvalue orinnovativefeatures, andthegeneralapplicabilityofeitherthetechnologyitselforthe scientificmethodsandscholarlydetailsprovidedbytheauthors. Thevolume isacontinuationofathemeinitiatedin 1990. Itspredecessors,Emerg- ing Technologies in Hazardous Waste Management, ACS Symposium Series No. 422 (1990), EmergingTechnologiesinHazardous WasteManagementII,ACSSymposiumSe- ries No. 468 (1991), Emerging Technologies in Hazardous WasteManagement III, ACS SymposiumSeriesNo. 518(1993), EmergingTechnologiesinHazardous WasteManage- mentIV, ACSSymposium Series No. 554 (1994),Emerging Technologies in Hazardous WasteManagement V. ACSSymposiumSeriesNo. 607(1995), andEmergingTechnolo- gies in Hazardous Waste Management VI, American AcademyofEnvironmental Engi- neersPublication (1996), arerelatedcontributionsonhazardouswastemanagement,but eachvolumeisessentiallydifferent. Byinspection,thereadermayquicklyrecognizethis diversity,andalsoconcludethatnosinglevolumecandojusticetothebreadthanddepth oftechnologiesbeingdevelopedandappliedinpractice. Thecontributionspresented in thisvolumearedivided intofourseparatebutcom- plementary sections, including: (1) Chemical and Thermal Treatment; (2) Biochemical Treatment;(3)SeparationTechnologies;and(4)RadioactiveWasteTreatment. D. WilliamTedder FrederickG. Pohland GeorgiaInstituteofTechnology UniversityofPittsburgh Atlanta, Georgia30332-0100 Pittsburgh,Pennsylvania15261-2294 v ACKNOWLEDGMENTS The Industrial & Engineering Chemistry (I&EC) Division ofACS organized and sponsored the symposium. ACS Corporate Associates was a majorfinancial cosponsor; theAmericanInstituteofChemicalEngineers(AIChE)EnvironmentalSciencesDivision, theAIChECenterforWasteReductionTechnologies,theAmericanAcademyofEnviron- mental Engineers,andtheJointAssociationfor theAdvancementsofSupercriticalFluid Technologywerenominalcosponsors;andEnviroExpocositedanexhibition. Thisgener- osity was essential to the overall successofthe symposium and is gratefully acknow- ledged. vii CONTENTS I. EmergingTechnologiesinHazardousWasteManagementVII:AnOverview...FrederickG. PohlandandD. WilliamTedder ChemicalandThermalMethods 2. GranularIronOxideasaCatalystinChemicalOxidationofOrganic Contaminants...9 MiratD. Gurol,Shu-SungLin,andNileshBhat 3. AnElectronBeamGeneratedPlasmaReactorforDecompositionof HalogenatedVOCs 23 S. A. Vitale, K. Hadidi,D. R. Cohn, L. Bromberg,andP. Falkos 4. IncinerationandThermalTreatmentofChemicalAgentsandChemicalWeapons 33 F. C. GouldinandE. M. Fisher 5. PredictingStabilityConstantsofVariousChelatingAgentsUsingQSAR Technology 49 R. W. Okey,S. Lin,andP. K. A. Hong 6. MineralizationofHazardousChemicalsbyHemeReaction ...69 GuyoungKang,JimoJung,KapsongPark,andDavidK. Stevens BiochemicalTreatment 7. AnaerobicTransformationsofCarbonTetrachloride:CombinedBacterialand AbioticProcesses 81 FlynnW. Picardal,SanggooKim,AnnaRadue,andDeberaBackhus 8. BiorecoveryofMetalsfromAcidMineDrainage...91 RakeshGovind,UmaKumar,RamaPuligadda,JimmyAntia,and HenryTabak ix x Contents 9. BiotreatmentofMinewater-ContainingCyanidesbyUsingImmobilizedCell Technology 103 Onguri K. Vijaya,G. R. V. Babu,JackAdams,JamesH. Wolfram,and KiritD. Chapatwala 10. Augmentationofin-SituSubsoilRemediationUsingColloidalGasDispersions 113 P. G. Chaphalkar,K. T. Valsaraj,D. Roy, W. D. Constant,andP. Lee 11. EffectofSorptionontheMicrobialReductiveDechlorinationofSoil-Bound Chloroalkenes 127 SpyrosG. PavlostathisandPingZhuang SeparationTechnologies 12. TheRemovalofVOCsfromExhaustAirandVapourCondensatesby MembraneProcesses ...

Hitherto the disposal of munitions was mostly concerned with obsolete stocks, but the political developments in the states of the former Soviet Union have necessitated the disposal of vast quantities of current and obsolete stocks. Obviously, open burning/open detonation cannot be used on such a large scale, not least for environmental considerations. There are two main technical problems associated with the disposal of munitions on the scale required. First, the materials are not simple wastes or rubbish. Their handling, storage, packaging and transportation are subject to very rigid regulation, and justifiably so, for obvious reasons. Second, they are very valuable goods, for which a high price has been paid by the holding states' economic systems. Mere destruction would mean the irretrievable loss of the value invested. But therein lies the problem. Goods like steel or brass scrap can easily be reclaimed, but hypergols and other rocket fuels (for instance) represent a true chemical challenge, while, under certain conditions, explosives may be diverted to civilian use. This, in summary, is the problem that the present book deals with: the two-pronged attack involving demilitarization and recycling technologies.

This book explores state-of-art techniques based on methodological and modeling aspects of solid and hazardous waste management, specifically focusing on the recent trends in data acquisition and robust modeling of the results obtained. In addition to an in-depth description of the recent regulatory paradigm for solid waste disposal and revealing insights into solid waste management models, the book also addresses significant case history and remediation methodologies for sustainable development in emerging economies like India, China and Brazil. The main emphasis is on a suitable regulatory framework with site-specific baseline calibration and aimed at the robust modeling of contaminant transport and its remediation. This is based on instructive case history in various locations/regions worldwide. The focus on recent modeling and quantification methods is the backbone of the book. One of the major aspects discussed is the application of non-invasive methods for studies related to the Earth's interior, which are increasingly preferred over invasive techniques thanks to their economic utility, as well as robust techniques for the interpretation of geophysical data. The increasing demand for groundwater and energy resources, especially for rapidly emerging countries with large populations like India and China, has made it vital to derive safe utilization approaches for our resources, including suitable waste disposal and remediation methodologies that can be adopted for 'contaminated sites.'

Advanced Organic Waste Management: Sustainable Practices and Approaches provides an integrated holistic approach to the challenges associated with organic waste management, particularly related to sustainability, lifecycle assessment, emerging regulations, and novel approaches for resource and energy recovery. In addition to traditional techniques, such as anaerobic digestion, composting, innovative and emerging techniques of waste recycling like hydrothermal carbonization and vermicomposting are included. The book combines the fundamentals and practices of sustainable organic waste management with successful case studies from developed and developing countries, highlighting practical applications and challenges. Sections cover global organic waste generation, encompassing sources and types, composition and characteristics, focus on technical aspects related to various resource recovery techniques like composting and vermicomposting, cover various waste-to-energy technologies, illustrate various environmental management tools for organic waste, present innovative organic waste management practices and strategies complemented by detailed case studies, introduce the circular bioeconomy approach, and more.