As solid state chemistry becomes increasingly important, organometallic chemistry will play a key role in addressing complex structures and developing novel interface chemistry. In a collection of reviews, leading chemists Focus on X-ray diffraction, MAssbauer spectroscopy and solid-state NMR in an overview of state-of-the-art structure analysis techniques and chemical applications in the solid state. Solid State Organometallic Chemistry
* Summarizes the progress that has been made in physical models and physical measurements of organometallics in the solid state.
* Critically analyses X-ray diffraction techniques in advanced and single crystal structure determination.
* Discusses the potentials of MAssbauer spectroscopy, solid state NMR and X-ray spectroscopy in structural analysis.
* Includes ab initio calculations on bonding in transition metal complexes.
This book will be invaluable to organometallic and solid state chemists and will also be of interest to physicists as well as polymer and materials scientists.

The long-term future for coal looks bleak. The recent UN climate change conference in Paris called for an end to the use of fossil fuels. However, coal remains one of the world’s most important sources of energy, fuelling more than 40% of electricity generation worldwide, with many developing nations relying almost wholly on coal-fuelled electricity. Coal has been the fastest growing energy source in recent years and is essential for many industrial activities, but the coal industry is hugely damaging for the environment. A major driver in climate change and causing around 40% of the world’s carbon dioxide emissions, coal fuel comes at a high environmental price. Furthermore, mining and air pollution kill thousands each year. A timely addition to the series, this book critically reviews the role of coal in the 21st century, examining energy needs, usage and health implications. With case studies and an examination of future developments and economics, this text provides an essential update on an environmental topic the world cannot ignore.

Fischer-Tropsch Synthesis (FTS) has been used on a commercial scale for more than eighty years. It was initially developed for strategic reasons because it offered a source of transportation fuels that was independent from crude oil. Unlike crude, Fischer-Tropsch synthetic crude is rich in olefins and oxygenates, while being sulphur and nitrogen free. Consequently, the catalysis involved in refining it is significantly different and only a few catalysts have been developed for the purpose. Until now, an account of this topic has been missing from the literature, despite mounting interest in the technology. This is the first book to provide a review and analysis of the literature (journal and patent) on the catalysis needed to refine syncrude to transportation fuels. It specifically highlights the impact of oxygenates and how oxygenates affect selectivity and deactivation. This aspect is also related to the refining of biomass derived liquids. Topics covered include: dimerisation / oligomerisation, isomerisation / hydroisomerisation, catalytic cracking / hydrocracking and hydrogenation, catalytic reforming, aromatic alkylation, etherification, dehydration, and some oxygenate and wax specific conversions.

Underground Coal Gasification (UCG) is carried out in unmined coal seams, using wells drilled from the surface and converting coal into synthesis gas. The gas can be used for power generation and synthesis of automotive fuels, fertilizers and other products. UCG offers financial, social, and environmental benefits over conventional coal extraction and utilization methods and may play a critical role in ensuring energy security in the future. Underground Coal Gasification and Combustion provides an overview of underground coal gasification technology, its current status and future directions. Comprehensive in approach, the book covers history, science, technology, hydrogeology, rock mechanics, environmental performance, economics, regulatory and commercial aspects of UCG projects. The first book on the subject in forty years, it is unique in analysing more than a century of global UCG developments by experts from Australia, Canada, Poland, Russia, Ukraine, United Kingdom, the USA and Uzbekistan.

Low-Rank Coals for Power Generation, Fuel and Chemical Production provides a thorough introduction to lignite (brown coal) and subbituminous coals and explores how they can be used efficiently and economically in place of hard coal. The book examines the undesirable characteristics of low-quality coals, such as high moisture content, low calorific value, and aggressive ash characteristics, and the resulting refinements to standard technologies and practices required for successful combustion, gasification, and pyrolysis. The first part of this book provides a comprehensive and systematic review of the properties of low-rank coals and corresponding preparation methods, such as drying, cleaning, and upgrading. Power generation from low-rank coals is the focus of Part 2, with chapter topics ranging from high efficiency pulverized coal combustion and circulating fluidized bed combustion to emerging areas such as chemical looping and oxyfuel combustion. The final contributions address the important subjects of coal-to-liquids,polygeneration and coke production using low-rank coals, as well as the critical issue of carbon capture and storage. This book is a valuable resource for power generation engineers and researchers seeking to maximize the opportunities provided by these cheaper coal feedstocks for efficient and environmentally compatible power generation.

The book reports on the results of the BrenaRo Winterschool 2011, held on November 21-22 in Aachen, Germany. The different chapters cover a number of aspects of the topic of energy generation, with a particular focus on energy generation from biomass. They presents new findings concerning engine development, process engineering, and biological and chemical conversion of biomass to fuels, and highlight the importance of an interdisciplinary approach, combining chemistry, biology and engineering research, to the use of renewable energy sources. All in all, this book provides readers with a snapshot of the state-of-the-art in renewable energy conversion, and gives an overview of the ongoing work in this field in Germany.

Focusing on the key challenges that still impede the realization of the billion-ton renewable fuels vision, this book integrates technological development and business development rationales to highlight the key technological.developments that are necessary to industrialize biofuels on a global scale. Technological issues addressed in this work include fermentation and downstream processing technologies, as compared to current industrial practice and process economics. Business issues that provide the lens through which the technological review is performed span the entire biofuel value chain, from financial mechanisms to fund biotechnology start-ups in the biofuel arena up to large green field manufacturing projects, to raw material farming, collection and transport to the bioconversion plant, manufacturing, product recovery, storage, and transport to the point of sale. Emphasis has been placed throughout the book on providing a global view that takes into account the intrinsic characteristics of various biofuels markets from Brazil, the EU, the US, or Japan, to emerging economies as agricultural development and biofuel development appear undissociably linked.

This book is an integrated approach towards the applications of coal (organic) petrology and discusses the role of this science in the field of coal and coal-related topics.
Coal petrology needs to be seen as a continuum of organic (macerals) and inorganic (minerals and trace elements) contributions to the total coal structure, with the overprint of coal rank. All this influences the behavior of coal in utilization, the coal by-products, the properties of coal as a reservoir for methane or a sequestration site for carbon dioxide, and the relationships of coal utilization with health and environmental issues.
The interaction of coal properties and coal utilization begins at the mine face. The breakage of the coal in mining influences its subsequent beneficiation. Beneficiation is fundamental to the proper combustion of coal and is vital to the preparation of the feedstock for the production of metallurgical coke. An understanding of basic coal properties is important for achieving reductions in trace element emissions and improving the efficiency of combustion and combined-cycle gasification. The production of methane from coal beds is related to the properties of the in situ coal. Similarly, coal bed sequestration of carbon dioxide produced from combustion is dependent on the reservoir properties. Environmental problems accompany coal on its way from the mine to the point of utilization and beyond. Health aspects related with coal mining and coal utilization are also included because, in planning for coal use, it is impossible to separate environmental and health issues from the discussion of coal utilization.
The book is aimed at a wide audience, ranging from researchers, lecturers and students to professionals in industry and discusses issues (such as the environmental, and health) that are of concern to the general public as a whole.
Key Features:
- This book focuses on the applications of coal (organic) petrology to our modern society.
- It is an integrated approach to help the reader appreciate the importance of coal quality and coal utilization. Coal composition (macerals, mineral, trace elements) and the overprint of coal rank are treated together.
- The book synthesises all the possibilities of the organic petrology as a tool for coal utilization in conventional applications (mining and beneficiation, coal combustion, gasification, liquefaction, carbonization), as a precursor of carbon materials and as a petroleum source and reservoir rock.
- The role of applied petrology in the characterization of solid by-products from coal utilization is also discussed.
- In addition, this book describes the present status of environmental and health problems linked to coal utilization and the ways in which such problems might be overcome in the future.

"A Thoughtful Discussion of a Timely Topic"

Evaluating a wealth of quantitative data, Biofuels: "Biotechnology, Chemistry, and Sustainable Development" discusses different types of biofuels, the science behind their production, the economics of their introduction to the marketplace, their environmental impacts, and their implications for world agriculture. It broadens the discussion on biofuels beyond bioethanol and biodiesel, taking into account the data, ideas, and bioproducts that have appeared over the last fifty years.

"An Insider's Look at the Biotech Industry"

Written by a seasoned expert in the biotech industry, the book analyzes in detail the present status and future prospects of biofuels, from ethanol and biodiesel to biotechnological routes to biohydrogen. It emphasizes the ways biotechnology can improve process economics as well as facilitate sustainable agroindustries and crucial elements of a biobased economy. The author also explores the additional innovations required in microbial and plant biotechnology, metabolic engineering, bioreactor design, and the genetic manipulation of novel biomass species of plants, such as softwoods and algae.

"The Role of Biofuels in the Future"

With over 1,000 references and nearly 200 graphs and tables of data, this well-researched, comprehensive work examines the past and present of various biofuels while considering the future of a biocommodity economy.

Dr. J. S. Laskowski has written several papers on frother-collector interactions and the effect of such interactions on flotation kinetics, and on frothers chemistry and frothing. He is founder and Editor-in-Chief of the journal, Coal Preparation. Dr. E. T. Woodburn has published numerous papers on flotation froth and flotation kinetics.
Frothing in Flotation, published in honor of Jan Leja, appeared in 1989. Many important contributions on various aspects of flotation froth properties and behavior and the relationship between froth appearance and flotation performance have appeared since, and this volume intends to summarize these achievements. Flotation kinetics involves a number of mass transfer processes with some of them being critically determined by the behavior of froth. Since froth is complex, and controlled experimentation is difficult, the froth phase was, until recently, either ignored or treated entirely empirically. With wide applications of flotation columns, the behavior of the froth is now often recognized as being dominant in determining flotation performance, and the research in this area is one of the most actively pursued.

Within technical overview sections on such emerging areas as bioprocessing, bioconversion, biosolubilization, biosystems and biocleaning, this handsomely illustrated reference specifically surveys pioneering work in the genetic production of sulfatase enzymes for removing organic sulfur from coal; r

Biomass is a widely available resource, that can be characterized by its high production potential. Enabling the production of different types of biofuels, biomass can be used in both spark-ignition and compression-ignition engines. There is extensive knowledge of the biofuel production process, and technologies enabling the production of biofuels with high caloric value and better physicochemical properties are developed. The biggest barrier in the development of a biofuels market is not the lack of know-how, but economic and political aspects. Biomass for Biofuels presents technological aspects of biomass conversion into advanced biofuels. Also discussed are the influence of growing biofuels markets on the natural environment and social relations as well as economic aspects of acquisition of biomass and its processing into biofuels. In addition biomass characteristics are presented. A definition is provided, and its chemical composition and properties detailed. The focus is on lignocellulosic biomass, whose complex structure is a limiting factor for biofuels production via biological processes. For that reason, echanical, chemical and physicochemical methods that enable an increased availability for the microorganisms used for biomass conversion to biofuels are discussed.

This unique handbook presents both the theory and application of biomass combustion and co-firing, from basic principles to industrial combustion and environmental impact, in a clear and comprehensive manner. It offers a solid grounding on biomass combustion, and advice on improving combustion systems. Written by leading international academics and industrial experts, and prepared under the auspices of the IEA Bioenergy Implementing Agreement, the handbook is an essential resource for anyone interested in biomass combustion and co-firing technologies varying from domestic woodstoves to utility-scale power generation. The book covers subjects including biomass fuel pre-treatment and logistics, modelling the combustion process and ash-related issues, as well as featuring an overview of the current R&D needs regarding biomass combustion.

This unique handbook presents both the theory and application of biomass combustion and co-firing, from basic principles to industrial combustion and environmental impact, in a clear and comprehensive manner. It offers a solid grounding on biomass combustion, and advice on improving combustion systems. Written by leading international academics and industrial experts, and prepared under the auspices of the IEA Bioenergy Implementing Agreement, the handbook is an essential resource for anyone interested in biomass combustion and co-firing technologies varying from domestic woodstoves to utility-scale power generation. The book covers subjects including biomass fuel pre-treatment and logistics, modelling the combustion process and ash-related issues, as well as featuring an overview of the current R&D needs regarding biomass combustion.

As the need to control process emissions has increased, so have the number of FGD treatment and control strategies. The effectiveness of these treatments vary greatly, depending the types and levels of the materials, as well as the size of the facility. Profiles in Flue Gas Desulfurization will help engineers and managers identify the technologies that best fit their plant and/or processes. It's a quick and easy reference to all "tail-end" SO2 control processes currently in commercial use or "on the brink," providing an effective "snapshot" of where this technology stands in industry today. The technologies are divided into waste producing processes, where the end product is a "clean waste," and byproduct processes, where the end product has market value. Each technology profile includes a schematic depicting its major equipment components and arrangement, laid out side-by-side with descriptive text on how the process works, where and how it is currently being utilized, its operational requirements, advantages and limitations for typical applications, and a brief list of principal suppliers.

Biohydrogen: For Future Engine Fuel Demands covers the production, purification, storage, pipeline transport, usage, and safety of biohydrogen. Hydrogen promises to be the most significant fuel source of the future, due to its global availability and the fact that water is its only by-product. Biofuels such as bioethanol, biodiesel, bio-oil, and biohydrogen are produced using technologies for thermochemically and biologically converting biomass. Hydrogen fuel production technologies can make use of either non-renewable sources, or renewable sources such as wind, solar, and biorenewable resources.

Biohydrogen: For Future Engine Fuel Demands reviews all of the modern biomass-based transportation fuels, including bioethanol, biodiesel, biogas, biohydrogen, and fuel cells. The book also discusses issues of biohydrogen economy, policy and environmental impact. Biohydrogen looks set to be the fuel of choice in the future, replacing both fossil fuels and biorenewable liquid fuels.

Lignites are a fuel resource upon which there has been heavy reliance for a long time in several parts of the world. Indeed, lignite (also known as low-rank coal, brown coal or braunkohle), has been used for electricity generation in some regions for a century or more. These coals can, after a mild drying process, be used directly as a fuel and this remains the dominant form of usage. The coals can however be beneficiated in a number of ways including moulding into briquettes for export. Other new technologies applied to brown coals include slurrying and solar drying to make a hard product also suitable for export. Very importantly, over a period of 70+ years there has been hydrogenation of such coals to make liquid fuels. This volume covers all aspects of the subject from the nature of lignites in situ to detailed coverage of fuel usage including figures for electricity generation and carbon dioxide release. Processing technologies including briquetting and carbonisation are described as are gasification, to make a fuel gas or a synthesis gas, and their conversion to liquid fuels.The book provides an international review, setting in context the use of lignite in various regions of the world. Where appropriate the book includes information about industrial plant and processes and uses information from key research and development. It also considers the important issue of carbon dioxide emissions which in the past has sometimes worked against lignite utilisation. This issue is covered with some emphasis and also deals with carbon capture and sequestration from power plants. Co-firing of lignites with biomass is also considered. This is the only recent comprehensive volume on the subject, bringing together for the first time a full account of this important fuel.

This book includes 19 chapters contributed by the world's leading experts on pretreatment methods for biomass. It extensively covers the different types of biomass (e.g. molasses, sugar beet pulp, cheese whey, sugarcane residues, palm waste, vegetable oil, straws, stalks and wood), various pretreatment approaches (e.g. physical, thermal, chemical, physicochemical and biological) and methods that show the subsequent production of biofuels and chemicals such as sugars, ethanol, extracellular polysaccharides, biodiesel, gas and oil. In addition to traditional methods such as steam, hot-water, hydrothermal, diluted-acid, organosolv, ozonolysis, sulfite, milling, fungal and bacterial, microwave, ultrasonic, plasma, torrefaction, pelletization, gasification (including biogas) and liquefaction pretreatments, it also introduces and discusses novel techniques such as nano and solid catalysts, organic electrolyte solutions and ionic liquids. This book offers a review of state-of-the-art research and provides guidance for the future paths of developing pretreatment techniques of biomass for biofuels, especially in the fields of biotechnology, microbiology, chemistry, materials science and engineering. It intends to provide a systematic introduction of pretreatment techniques. It is an accessible reference work for students, researchers, academicians and industrialists in biorefineries. Zhen Fang is a Professor of Bioenergy and the leader and founder of the biomass group at the Xishuangbanna Tropical Botanical Garden of the Chinese Academy of Sciences. He is also an adjunct full Professor of Life Sciences at the University of Science and Technology of China.

This volume, The Science of Algal Fuels (volume 25 of COLE), contains 26 chapters dealing with biofuels contributed by experts from numerous countries and covers several aspects of algal products, one being "oilgae from algae," mainly oils and fuels for engines. Among the prominent algal groups that participate in this process are the diatoms and green algae (Chlorophyceae). Their metabolism and breeding play an important role in biomass and extraction of crude oil and algal fuel. There is a strong relation between solar energy influencing algal culture and the photobiology of lipid metabolism. Currently, many international meetings and conferences on biofuel are taking place in many countries, and several new books and proceedings of conferences have appeared on this topic. All this indicates that this field is "hot" and in the forefront of applied bioscience.

The long-held tenets of the energy sector are being rewritten in the twenty-first century. The rise of unconventional oil and gas and of renewables is transforming our economies and improving our understanding of the distribution of the world's energy resources and their impacts. A complete knowledge of the dynamics underpinning energy markets is necessary for decision-makers reconciling economic, energy, and environmental objectives. Those that anticipate global energy developments successfully can derive an advantage, while those that fail to do so risk making poor policy and investment decisions. Focused on solving the key challenges impeding the realization of advanced cellulosic biofuels and bioproducts in rural areas, Biomass and Biofuels: Advanced Biorefineries for Sustainable Production and Distribution provides comprehensive information on sustainable production of biomass feedstock, supply chain management of feedstocks to the biorefinery site, advanced conversion processes, and catalysts/biocatalysts for production of fuels and chemicals using conventional and integrated technologies. The book also presents detailed coverage of downstream processing, and ecological considerations for refineries processing lignocellulosic and algal biomass resources. Discussions of feedstock raw materials, methods for biomass conversion, and its effective integration to make biorefinery more sustainable - economically, environmentally, and socially - give you the tools to make informed decisions.

The opportunity of repowering the existing condensing power stations by means of gas turbogenerators offers an important opportunity to considerably improvement of their energy efficiency. The Modernization Potential of Gas turbines in the Coal-Fired Power Industry presents the methodology, calculation procedures and tools used to support enterprise planning for adapting power stations to dual-fuel gas-steam combined-cycle technologies. Both the conceptual and practical aspects of the conversion of existing coal-fired power plants is covered. Discussions of the feasibility, advantages and disadvantages and possible methods are supported by chapters presenting equations of energy efficiency for the conditions of repowering a power unit by installing a gas turbogenerator in a parallel system and the results of technical calculations involving the selection heating structures of heat recovery steam generators. A methodology for analyzing thermodynamic and economic effectiveness for the selection of a structure of the heat recovery steam generator for the repowered power unit is also explained. The Modernization Potential of Gas turbines in the Coal-Fired Power Industry is an informative monograph written for researchers, postgraduate students and policy makers in power engineering.

Biohydrogen: For Future Engine Fuel Demands covers the production, purification, storage, pipeline transport, usage, and safety of biohydrogen. Hydrogen promises to be the most significant fuel source of the future, due to its global availability and the fact that water is its only by-product. Biofuels such as bioethanol, biodiesel, bio-oil, and biohydrogen are produced using technologies for thermochemically and biologically converting biomass. Hydrogen fuel production technologies can make use of either non-renewable sources, or renewable sources such as wind, solar, and biorenewable resources.

Biohydrogen: For Future Engine Fuel Demands reviews all of the modern biomass-based transportation fuels, including bioethanol, biodiesel, biogas, biohydrogen, and fuel cells. The book also discusses issues of biohydrogen economy, policy and environmental impact. Biohydrogen looks set to be the fuel of choice in the future, replacing both fossil fuels and biorenewable liquid fuels.

The demand for coal use (for electricity generation) and coal products, particularly liquid fuels and chemical feedstocks, is increasing throughout the world. Traditional markets such as North America and Europe are experiencing a steady increase in demand whereas emerging Asian markets, such as India and China, are witnessing a rapid surge in demand for clean liquid fuels. A detailed and comprehensive overview of the chemistry and technology of coal in the twenty-first century, The Chemistry and Technology of Coal, Third Edition also covers the relationship of coal industry processes with environmental regulations as well as the effects of combustion products on the atmosphere. Maintaining and enhancing the clarity of presentation that made the previous editions so popular, this book: Examines the effects of combustion products on the atmosphere Details practical elements of coal evaluation procedures Clarifies misconceptions concerning the organic structure of coal Discusses the physical, thermal, electrical, and mechanical properties of coal Analyzes the development and current status of combustion and gasification techniques In addition to two new chapters, Coal Use and the Environment and Coal and Energy Security, much of the material in this edition been rewritten to incorporate the latest developments in the coal industry. Citations from review articles, patents, other books, and technical articles with substantial introductory material are incorporated into the text for further reference. The Chemistry and Technology of Coal, Third Edition maintains its initial premise: to introduce the science of coal, beginning with its formation in the ground to the production of a wide variety of products and petrochemical intermediates in the twenty-first century. The book will prove useful for scientists and engineers already engaged in the coal and/or catalyst manufacturing industry looking for a general overview or update on the clean coal technology as well as professional researchers and students in chemistry and engineering.

"Explores Worldwide Trends Involving the Production and Use of Biofuels"

With the depletion of oil resources as well as the negative environmental impact of fossil fuels, there is much interest in alternative energy sources. Focusing on some of the most important alternate energy sources for the foreseeable future, the Handbook of Plant-Based Biofuels provides state-of-the-art information on the status of the production of biofuels, in particular, bioethanol and biodiesel.

"Introduction to Biofuels"

After profiling plant-based biofuels, the book gives an overview of the production of biofuels from biomass materials by thermochemical and biochemical methods. It examines the thermochemical conversion of biomass to liquids and gaseous fuels.

"Production of Bioethanol"

The handbook then analyzes current biomass-to-ethanol programs, followed by a discussion on ethanol fermentation from molasses and process practices applied for the improvement of ethanol production by ethanologenic microorganisms. It also explains the hydrolysis and fermentation of ethanol from starchy and lignocellulosic biomasses.

"Production of Biodiesel"

In the final chapters, the contributors discuss current perspectives and the future of biodiesel production. They explore biodiesel production substrates, the lipase-catalyzed preparation of biodiesel, and biodiesel production with supercritical fluid technologies.

As an increasing number of professionals and graduate students enter the field of solid-based power generation, they all require an command of process and equipment, as well as the theory behind it all. However, their informational needs and understanding differ based on their experience and the task at hand.

Solid Fuels Combustion and Gasification: Modeling, Simulation, and Equipment Operations, Second Edition explores evolving solid fuel combustion and gasification techniques that are leading to much lower sulfur and nitrogen oxide emissions. It also shows how to increase the efficiency of processes dealing with materials such as coal, biomass, solid residues, etc. Many of the successes of these methods are the result of process optimization resulting from mathematical modeling and simulation. This book introduces and explores these techniques, taking a moderate approach that is neither too narrow nor too basic, making it useful to graduate students, engineers, and professionals.

It illustrates the modeling and constructive and operational aspects of equipment used in combustion and gasification of solid fuels. It was written based on the idea that developing models and computer simulators is the optimal method to acquire real and testable understanding of a subject in the area of processing.

Model complexity is extended only as far as needed to achieve a reasonable representation of the equipment described in the book, and the author provides specific and carefully selected case studies that:

• Cover many industrial processes involving combustion or gasification of solid fuels
• Provide easy-to-follow examples on how to set simplifying assumptions regarding the operation of real industrial equipment
• Enable relatively quick introduction of fundamental equations without the need for unnecessarily complex treatments

The main strategy of the book is to teach by example, and the basic methods illustrated here can be used for modeling a wide range of processes and equipment commonly found in industry. It is a carefully constructed volume which presents essential concepts that minimize the need for other texts, and it can also be used as an introduction to more complex models.