Solid Fuels and Heavy Hydrocarbon Liquids: Thermal Characterisation and Analysis, Second Edition integrates the developments that have taken place since publication of the first edition in 2006. This updated material includes new insights that help unify the thermochemical reactions of biomass and coal, as well as new developments in analytical techniques, including new applications in size exclusion chromatography, several mass spectrometric techniques, and new applications of nuclear magnetic spectroscopy to the characterization of heavy hydrocarbon liquids The topics covered are essential for the energy and fuels research community, including academics, students, and research engineers working in the power, oil and gas, and renewable energy industries.

Research in environmental justice reveals that low-income and minority neighborhoods in our nation's cities are often the preferred sites for landfills, power plants, and polluting factories. Those who live in these sacrifice zones are forced to shoulder the burden of harmful environmental effects so that others can prosper. "Mountains of Injustice "broadens the discussion from the city to the country by focusing on the legacy of disproportionate environmental health impacts on communities in the Appalachian region, where the costs of cheap energy and cheap goods are actually quite high. Through compelling stories and interviews with people who are fighting for environmental justice, "Mountains of Injustice "contributes to the ongoing debate over how to equitably distribute the long-term environmental costs and consequences of economic development.

Biomass obtained from agricultural residues or forest can be used to produce different materials and bioenergy required in a modern society. As compared to other resources available, biomass is one of the most common and widespread resources in the world. Thus, biomass has the potential to provide a renewable energy source, both locally and across large areas of the world. It is estimated that the total investment in the biomass sector between 2008 and 2021 will reach the large sum of $104 billion. Presently bioenergy is the most important renewable energy option and will remain so the near and medium-term future. Previously several countries try to explore the utilization of biomass in bioenergy and composite sector. Biomass has the potential to become the world s largest and most sustainable energy source and will be very much in demand. Bioenergy is based on resources that can be utilized on a sustainable basis all around the world and can thus serve as an effective option for the provision of energy services. In addition, the benefits accrued go beyond energy provision, creating unique opportunities for regional development. The present book will provide an up-to-date account of non-wood, forest residues, agricultural biomass (natural fibers), and energy crops together with processing, properties, and its applications to ensure biomass utilization and reuse. All aspects of biomass and bioenergy and their properties and applications will be critically re-examined. The book consists of three sections, presenting Non wood and forest products from forestry, arboriculture activities or from wood processing, agricultural biomass (natural fibers) from agricultural harvesting or processing and finally energy crops: high yield crops and grasses grown especially for energy production. "

Biomass obtained from agricultural residues or forest can be used to produce different materials and bioenergy required in a modern society. As compared to other resources available, biomass is one of the most common and widespread resources in the world. Thus, biomass has the potential to provide a renewable energy source, both locally and across large areas of the world. It is estimated that the total investment in the biomass sector between 2008 and 2021 will reach the large sum of $104 billion. Presently bioenergy is the most important renewable energy option and will remain so the near and medium-term future. Previously several countries try to explore the utilization of biomass in bioenergy and composite sector. Biomass has the potential to become the world s largest and most sustainable energy source and will be very much in demand. Bioenergy is based on resources that can be utilized on a sustainable basis all around the world and can thus serve as an effective option for the provision of energy services. In addition, the benefits accrued go beyond energy provision, creating unique opportunities for regional development.The present book will provide an up-to-date account of non-wood, forest residues, agricultural biomass (natural fibers), and energy crops together with processing, properties and its applications to ensure biomass utilization and reuse. All aspects of biomass and bioenergy and their properties and applications will be critically re-examined. The book consists of three sections, presenting Non wood and forest products from forestry, arboriculture activities or from wood processing, agricultural biomass (natural fibers) from agricultural harvesting or processing and finally energy crops: high yield crops and grasses grown especially for energy production."

This book includes 19 chapters contributed by the world's leading experts on pretreatment methods for biomass. It extensively covers the different types of biomass (e.g. molasses, sugar beet pulp, cheese whey, sugarcane residues, palm waste, vegetable oil, straws, stalks and wood), various pretreatment approaches (e.g. physical, thermal, chemical, physicochemical and biological) and methods that show the subsequent production of biofuels and chemicals such as sugars, ethanol, extracellular polysaccharides, biodiesel, gas and oil. In addition to traditional methods such as steam, hot-water, hydrothermal, diluted-acid, organosolv, ozonolysis, sulfite, milling, fungal and bacterial, microwave, ultrasonic, plasma, torrefaction, pelletization, gasification (including biogas) and liquefaction pretreatments, it also introduces and discusses novel techniques such as nano and solid catalysts, organic electrolyte solutions and ionic liquids. This book offers a review of state-of-the-art research and provides guidance for the future paths of developing pretreatment techniques of biomass for biofuels, especially in the fields of biotechnology, microbiology, chemistry, materials science and engineering. It intends to provide a systematic introduction of pretreatment techniques. It is an accessible reference work for students, researchers, academicians and industrialists in biorefineries. Zhen Fang is a Professor of Bioenergy and the leader and founder of the biomass group at the Xishuangbanna Tropical Botanical Garden of the Chinese Academy of Sciences. He is also an adjunct full Professor of Life Sciences at the University of Science and Technology of China.

This study focuses on the physical aspects of ultrasonic de-ashing and de-sulfurization, such as cavitation, streaming and their combined effects. Ambedkar Balraj proposes an ultrasound-assisted coal particle breakage mechanism and explores aqueous and solvent-based ultrasonic techniques for de-ashing and de-sulfurization. Ambedkar designs a Taguchi L-27 fractional-factorial matrix to assess the individual effects of key process variables. In this volume he also describes process optimization and scale-up strategies. The author provides a mechanism-based model for ultrasonic reagent-based coal de-sulfurization, proposes a flow diagram for ultrasonic methods of high-throughput coal-wash and discusses the benefits of ultrasonic coal-wash. Coal will continue to be a major fuel source for the foreseeable future and this study helps improve its use by minimising ash and sulfur impurities.

This book contains papers presented at the Engineering Foundation Conference on mineral matter in fuels held on November 2-7, 1997 in Kona, Hawaii. The conference is one of a continuing series that was initiated by the CEGB Mar- wood Engineering Laboratories in 1963. The conference was to be eventually organised by the Engineering Foundation as the need for multi-disciplinary work related to c- trolling ash effects in combustors became apparent. The conference covers both the science and the applications. The papers also present case histories, particularly for current fuel technologies, developments in advanced technologies for power generation and mathematical modelling of these processes. Developments since 1963 have been slow, but steady, due to the complexity of the chemical and physical processes involved. However, the research presented here displays great improvement in our understanding of the mechanisms by which mineral matter will influence fuel use. Steve Benson from EERC presented a review and current status of issues related to ash deposition in coal combustion and gasification. The application of new analytical tools, which have been detailed in the previous conferences, is presented. These include CCSEM, as well as new techniques for char- terising sintering of ash, such as TMA, image analysis, X-ray diffraction crystallography and thermal analysis. The new analytical techniques were extended to encompass widely differing fuels such as biomass. Ole H Larsen from ELSAM Denmark presented a review of these advanced techniques.

Focusing on the key challenges that still impede the realization of the billion-ton renewable fuels vision, this book integrates technological development and business development rationales to highlight the key technological.developments that are necessary to industrialize biofuels on a global scale. Technological issues addressed in this work include fermentation and downstream processing technologies, as compared to current industrial practice and process economics. Business issues that provide the lens through which the technological review is performed span the entire biofuel value chain, from financial mechanisms to fund biotechnology start-ups in the biofuel arena up to large green field manufacturing projects, to raw material farming, collection and transport to the bioconversion plant, manufacturing, product recovery, storage, and transport to the point of sale. Emphasis has been placed throughout the book on providing a global view that takes into account the intrinsic characteristics of various biofuels markets from Brazil, the EU, the US, or Japan, to emerging economies as agricultural development and biofuel development appear undissociably linked.

This volume, The Science of Algal Fuels (volume 25 of COLE), contains 26 chapters dealing with biofuels contributed by experts from numerous countries and covers several aspects of algal products, one being "oilgae from algae," mainly oils and fuels for engines. Among the prominent algal groups that participate in this process are the diatoms and green algae (Chlorophyceae). Their metabolism and breeding play an important role in biomass and extraction of crude oil and algal fuel. There is a strong relation between solar energy influencing algal culture and the photobiology of lipid metabolism. Currently, many international meetings and conferences on biofuel are taking place in many countries, and several new books and proceedings of conferences have appeared on this topic. All this indicates that this field is "hot" and in the forefront of applied bioscience.

This book provides an overview of state-of-the-art technologies for energy conversion from waste, as well as a much-needed guide to new and advanced strategies to increase Waste-to-Energy (WTE) plant efficiency. Beginning with an overview of municipal solid waste production and disposal, basic concepts related to Waste-To-Energy conversion processes are described, highlighting the most relevant aspects impacting the thermodynamic efficiency of WTE power plants. The pervasive influences of main steam cycle parameters and plant configurations on WTE efficiency are detailed and quantified. Advanced hybrid technology applications, particularly the Hybrid Combined Cycle concept, are examined in detail, including an illuminating compare-and-contrast study of two basic types of hybrid dual-fuel combined cycle arrangements: steam/water side integrated HCC and windbox repowering.

Biofuel is a renewable energy source produced from natural materials. The benefits of biofuels over traditional petroleum fuels include greater energy security, reduced environmental impact, foreign exchange savings, and socioeconomic issues related to the rural sector. The most common biofuels are produced from classic food crops that require high-quality agricultural land for growth. However, bioethanol can be produced from plentiful, domestic, cellulosic biomass resources such as herbaceous and woody plants, agricultural and forestry residues, and a large portion of municipal and industrial solid waste streams. There is also a growing interest in the use of vegetable oils for making biodiesel. "Biofuels: Securing the Planet's Future Energy Needs" discusses the production of transportation fuels from biomass (such as wood, straw and even household waste) by Fischer-Tropsch synthesis. The book is an important text for students and researchers in energy engineering, as well as professional fuel engineers.

As solid state chemistry becomes increasingly important, organometallic chemistry will play a key role in addressing complex structures and developing novel interface chemistry. In a collection of reviews, leading chemists Focus on X-ray diffraction, MAssbauer spectroscopy and solid-state NMR in an overview of state-of-the-art structure analysis techniques and chemical applications in the solid state. Solid State Organometallic Chemistry
* Summarizes the progress that has been made in physical models and physical measurements of organometallics in the solid state.
* Critically analyses X-ray diffraction techniques in advanced and single crystal structure determination.
* Discusses the potentials of MAssbauer spectroscopy, solid state NMR and X-ray spectroscopy in structural analysis.
* Includes ab initio calculations on bonding in transition metal complexes.
This book will be invaluable to organometallic and solid state chemists and will also be of interest to physicists as well as polymer and materials scientists.

The long-term future for coal looks bleak. The recent UN climate change conference in Paris called for an end to the use of fossil fuels. However, coal remains one of the world’s most important sources of energy, fuelling more than 40% of electricity generation worldwide, with many developing nations relying almost wholly on coal-fuelled electricity. Coal has been the fastest growing energy source in recent years and is essential for many industrial activities, but the coal industry is hugely damaging for the environment. A major driver in climate change and causing around 40% of the world’s carbon dioxide emissions, coal fuel comes at a high environmental price. Furthermore, mining and air pollution kill thousands each year. A timely addition to the series, this book critically reviews the role of coal in the 21st century, examining energy needs, usage and health implications. With case studies and an examination of future developments and economics, this text provides an essential update on an environmental topic the world cannot ignore.

Fischer-Tropsch Synthesis (FTS) has been used on a commercial scale for more than eighty years. It was initially developed for strategic reasons because it offered a source of transportation fuels that was independent from crude oil. Unlike crude, Fischer-Tropsch synthetic crude is rich in olefins and oxygenates, while being sulphur and nitrogen free. Consequently, the catalysis involved in refining it is significantly different and only a few catalysts have been developed for the purpose. Until now, an account of this topic has been missing from the literature, despite mounting interest in the technology. This is the first book to provide a review and analysis of the literature (journal and patent) on the catalysis needed to refine syncrude to transportation fuels. It specifically highlights the impact of oxygenates and how oxygenates affect selectivity and deactivation. This aspect is also related to the refining of biomass derived liquids. Topics covered include: dimerisation / oligomerisation, isomerisation / hydroisomerisation, catalytic cracking / hydrocracking and hydrogenation, catalytic reforming, aromatic alkylation, etherification, dehydration, and some oxygenate and wax specific conversions.

The book reports on the results of the BrenaRo Winterschool 2011, held on November 21-22 in Aachen, Germany. The different chapters cover a number of aspects of the topic of energy generation, with a particular focus on energy generation from biomass. They presents new findings concerning engine development, process engineering, and biological and chemical conversion of biomass to fuels, and highlight the importance of an interdisciplinary approach, combining chemistry, biology and engineering research, to the use of renewable energy sources. All in all, this book provides readers with a snapshot of the state-of-the-art in renewable energy conversion, and gives an overview of the ongoing work in this field in Germany.

"A Thoughtful Discussion of a Timely Topic"

Evaluating a wealth of quantitative data, Biofuels: "Biotechnology, Chemistry, and Sustainable Development" discusses different types of biofuels, the science behind their production, the economics of their introduction to the marketplace, their environmental impacts, and their implications for world agriculture. It broadens the discussion on biofuels beyond bioethanol and biodiesel, taking into account the data, ideas, and bioproducts that have appeared over the last fifty years.

"An Insider's Look at the Biotech Industry"

Written by a seasoned expert in the biotech industry, the book analyzes in detail the present status and future prospects of biofuels, from ethanol and biodiesel to biotechnological routes to biohydrogen. It emphasizes the ways biotechnology can improve process economics as well as facilitate sustainable agroindustries and crucial elements of a biobased economy. The author also explores the additional innovations required in microbial and plant biotechnology, metabolic engineering, bioreactor design, and the genetic manipulation of novel biomass species of plants, such as softwoods and algae.

"The Role of Biofuels in the Future"

With over 1,000 references and nearly 200 graphs and tables of data, this well-researched, comprehensive work examines the past and present of various biofuels while considering the future of a biocommodity economy.

Dr. J. S. Laskowski has written several papers on frother-collector interactions and the effect of such interactions on flotation kinetics, and on frothers chemistry and frothing. He is founder and Editor-in-Chief of the journal, Coal Preparation. Dr. E. T. Woodburn has published numerous papers on flotation froth and flotation kinetics.
Frothing in Flotation, published in honor of Jan Leja, appeared in 1989. Many important contributions on various aspects of flotation froth properties and behavior and the relationship between froth appearance and flotation performance have appeared since, and this volume intends to summarize these achievements. Flotation kinetics involves a number of mass transfer processes with some of them being critically determined by the behavior of froth. Since froth is complex, and controlled experimentation is difficult, the froth phase was, until recently, either ignored or treated entirely empirically. With wide applications of flotation columns, the behavior of the froth is now often recognized as being dominant in determining flotation performance, and the research in this area is one of the most actively pursued.

Within technical overview sections on such emerging areas as bioprocessing, bioconversion, biosolubilization, biosystems and biocleaning, this handsomely illustrated reference specifically surveys pioneering work in the genetic production of sulfatase enzymes for removing organic sulfur from coal; r

Biomass is a widely available resource, that can be characterized by its high production potential. Enabling the production of different types of biofuels, biomass can be used in both spark-ignition and compression-ignition engines. There is extensive knowledge of the biofuel production process, and technologies enabling the production of biofuels with high caloric value and better physicochemical properties are developed. The biggest barrier in the development of a biofuels market is not the lack of know-how, but economic and political aspects. Biomass for Biofuels presents technological aspects of biomass conversion into advanced biofuels. Also discussed are the influence of growing biofuels markets on the natural environment and social relations as well as economic aspects of acquisition of biomass and its processing into biofuels. In addition biomass characteristics are presented. A definition is provided, and its chemical composition and properties detailed. The focus is on lignocellulosic biomass, whose complex structure is a limiting factor for biofuels production via biological processes. For that reason, echanical, chemical and physicochemical methods that enable an increased availability for the microorganisms used for biomass conversion to biofuels are discussed.

This unique handbook presents both the theory and application of biomass combustion and co-firing, from basic principles to industrial combustion and environmental impact, in a clear and comprehensive manner. It offers a solid grounding on biomass combustion, and advice on improving combustion systems. Written by leading international academics and industrial experts, and prepared under the auspices of the IEA Bioenergy Implementing Agreement, the handbook is an essential resource for anyone interested in biomass combustion and co-firing technologies varying from domestic woodstoves to utility-scale power generation. The book covers subjects including biomass fuel pre-treatment and logistics, modelling the combustion process and ash-related issues, as well as featuring an overview of the current R&D needs regarding biomass combustion.

This unique handbook presents both the theory and application of biomass combustion and co-firing, from basic principles to industrial combustion and environmental impact, in a clear and comprehensive manner. It offers a solid grounding on biomass combustion, and advice on improving combustion systems. Written by leading international academics and industrial experts, and prepared under the auspices of the IEA Bioenergy Implementing Agreement, the handbook is an essential resource for anyone interested in biomass combustion and co-firing technologies varying from domestic woodstoves to utility-scale power generation. The book covers subjects including biomass fuel pre-treatment and logistics, modelling the combustion process and ash-related issues, as well as featuring an overview of the current R&D needs regarding biomass combustion.

Explore a thorough and up to date overview of the current knowledge, developments and outstanding challenges in turbulent combustion and application. The balance among various renewable and combustion technologies are surveyed, and numerical and experimental tools are discussed along with recent advances. Covers combustion of gaseous, liquid and solid fuels and subsonic and supersonic flows. This detailed insight into the turbulence-combustion coupling with turbulence and other physical aspects, shared by a number of the world leading experts in the field, makes this an excellent reference for graduate students, researchers and practitioners in the field.

As the need to control process emissions has increased, so have the number of FGD treatment and control strategies. The effectiveness of these treatments vary greatly, depending the types and levels of the materials, as well as the size of the facility. Profiles in Flue Gas Desulfurization will help engineers and managers identify the technologies that best fit their plant and/or processes. It's a quick and easy reference to all "tail-end" SO2 control processes currently in commercial use or "on the brink," providing an effective "snapshot" of where this technology stands in industry today. The technologies are divided into waste producing processes, where the end product is a "clean waste," and byproduct processes, where the end product has market value. Each technology profile includes a schematic depicting its major equipment components and arrangement, laid out side-by-side with descriptive text on how the process works, where and how it is currently being utilized, its operational requirements, advantages and limitations for typical applications, and a brief list of principal suppliers.

Lignites are a fuel resource upon which there has been heavy reliance for a long time in several parts of the world. Indeed, lignite (also known as low-rank coal, brown coal or braunkohle), has been used for electricity generation in some regions for a century or more. These coals can, after a mild drying process, be used directly as a fuel and this remains the dominant form of usage. The coals can however be beneficiated in a number of ways including moulding into briquettes for export. Other new technologies applied to brown coals include slurrying and solar drying to make a hard product also suitable for export. Very importantly, over a period of 70+ years there has been hydrogenation of such coals to make liquid fuels. This volume covers all aspects of the subject from the nature of lignites in situ to detailed coverage of fuel usage including figures for electricity generation and carbon dioxide release. Processing technologies including briquetting and carbonisation are described as are gasification, to make a fuel gas or a synthesis gas, and their conversion to liquid fuels.The book provides an international review, setting in context the use of lignite in various regions of the world. Where appropriate the book includes information about industrial plant and processes and uses information from key research and development. It also considers the important issue of carbon dioxide emissions which in the past has sometimes worked against lignite utilisation. This issue is covered with some emphasis and also deals with carbon capture and sequestration from power plants. Co-firing of lignites with biomass is also considered. This is the only recent comprehensive volume on the subject, bringing together for the first time a full account of this important fuel.

Biohydrogen: For Future Engine Fuel Demands covers the production, purification, storage, pipeline transport, usage, and safety of biohydrogen. Hydrogen promises to be the most significant fuel source of the future, due to its global availability and the fact that water is its only by-product. Biofuels such as bioethanol, biodiesel, bio-oil, and biohydrogen are produced using technologies for thermochemically and biologically converting biomass. Hydrogen fuel production technologies can make use of either non-renewable sources, or renewable sources such as wind, solar, and biorenewable resources.

Biohydrogen: For Future Engine Fuel Demands reviews all of the modern biomass-based transportation fuels, including bioethanol, biodiesel, biogas, biohydrogen, and fuel cells. The book also discusses issues of biohydrogen economy, policy and environmental impact. Biohydrogen looks set to be the fuel of choice in the future, replacing both fossil fuels and biorenewable liquid fuels.