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Oxygenates by Homologation or CO Hydrogenation with Metal Complexes (Paperback, Softcover reprint of the original 1st ed. 1994)
Loot Price: R2,873
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Oxygenates by Homologation or CO Hydrogenation with Metal Complexes (Paperback, Softcover reprint of the original 1st ed. 1994)
Series: Catalysis by Metal Complexes, 16
Expected to ship within 10 - 15 working days
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Born and initially developed in various industrial laboratories,
mainly in U.S.A. and Gennany, homogeneous phase catalytic carbon
monoxide hydrogenation and alcohols and their derivatives
carbonylation and homologation, have generally been considered and
reviewed separately in the course of their 40 years history without
concern for common aspects in the chemical transfonnations and in
catalysis. Thanks to researchers of Japanese companies
participating in the National C 1 Chemistry Project (1980-1987) the
scientific and technical approaches in this field have been unified
and applied in parallel, in the light of some common aspects of the
chemical reactions and mechanisms. Now, at a moment when research
seems becahned, a general presentation and discussion of the most
recent topics might be an useful basis for further development of
this chemistry. To delimit and simplify the discussion of the
chemical aspects and the nature of the catalysts involved, the
present review is limited to reactions employing homogeneous metal
complexes for the direct conversion of syngas to oxygenates and to
the hydrocarbonylation of these last to homologous derivatives.
Since the previous practically contemporary reviews by Dombek [in
Adv. Organomet. Chern. (1983)] on CO hydrogenation and by the
present authors [in Asp.Homog.Catal.(Reidel Pu.l984)] on alcohol
homologation fully cover the literature up to 1982, here we mainly
refer to work done after 1982, and consider the cited reviews as
covering the historical development of research in the 1940- 1980
period.
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