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Nafion Nanocomposite Membranes for the Direct Methanol Fuel Cell (Paperback)
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Nafion Nanocomposite Membranes for the Direct Methanol Fuel Cell (Paperback)
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Direct methanol fuel cells are seen as an attractive potential
replacement for lithium ion batteries in small portable electronic
devices. Crucial to the operation of direct methanol fuel cells is
the proton exchange membrane, which conducts protons from the anode
to the cathode, while acting as an insulator to electrons. The
proton exchange membrane should also act as a physical barrier to
the methanol and water at the anode, and the air or oxygen at the
cathode, however the most commonly used proton exchange membrane,
Nafion, suffers from significant methanol permeation from the anode
to the cathode during operation. This work examined the effect of
modifying Nafion membranes through in situ sol gel synthesis of
silicon oxide nanoparticles with varying surface chemistry and
microstructure. Detailed structural characterisation of the
composite structure was undertaken using a wide variety of
techniques including small angle X-ray and neutron scattering,
wide-angle X-ray scattering, thermal analysis techniques and
positron annihilation lifetime spectroscopy. Transport properties
of the composite membranes were evaluated by impedance spectroscopy
and pervaporation techniques.
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