Metal carbene complexes have made their way from organometallic
curiosities to valuable reagents and catalysts. They offer novel
synthetic opportunities in carbon-carbon bond formation based on
either carbene-centered reactions or on metal-templated processes
which makes them indispensable in modern synthetic methodology. The
most prominent metal carbenes are now either commercially available
or easy to synthesize and handle with modern laboratory techniques.
This volume organized in eight chapters written by the leading
scientists in the field illustrates the theoretical background,
non-classical nucleophilic and cycloaddition patterns,
chromium-templated benzannulation and photo-induced reactions,
rhodium-catalyzed carbene transfer as well as the principles and
applications of olefin metathesis which has coined the progress in
synthetic methodology over the past decade. Designed for
researchers in academia and industry as well as graduate students
it presents the state-of-the-art potential of carbene complexes in
modern organic synthesis.
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