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Organometallic Chemistry - Volume 39 (Hardcover)
Loot Price: R11,445
Discovery Miles 114 450
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Organometallic Chemistry - Volume 39 (Hardcover)
Series: Specialist Periodical Reports, Volume 39
Expected to ship within 12 - 17 working days
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A series of critical reviews and perspectives focussing on specific
aspects of organometallic chemistry interfacing with other fields
of study are provided. For this volume, the critical reviews cover
topics such as the activation of "inert" carbon-hydrogen bonds,
ligand design and organometallic radical species. For example,
Charlie O'Hara discusses how mixed-metal compounds may perform the
highly selective activation of C-H bonds and, in particular, how
synergic relationships between various metals are crucial to this
approach. The chemistry of a remarkable series of air-stable chiral
primary phosphine ligands is discussed in some depth by Rachel
Hiney, Arne Ficks, Helge M(3)ller-Bunz, Declan Gilheany and Lee
Higham. This article focuses on the preparation of these ligands
and also how they may be applied in various catalytic applications.
Bas De Bruin reports on how ligand radical reactivity can be
employed in synthetic organometallic chemistry and catalysis to
achieve selectivity in radical-type transformations. As well as
highlighting ligand-centered radical transformations in open-shell
transition metals, an overview of the catalytic mechanism of
Co(II)-catalysed olefin cyclopropanation is given, showing that
enzyme-like cooperative metal-ligand-radical reactivity is no
longer limited to real enzymes. Valuable and informative
comprehensive reviews in the field of organometallic chemistry are
also covered in this volume. For example, organolithium and
organocuprate chemistry are reviewed by Joanna Haywood and Andrew
Wheatley; aspects in Group 2 (Be-Ba) and Group 12 (Zn-Hg) compounds
by Robert Less, Rebecca Melen and Dominic Wright; metal clusters by
Mark Humphrey and Marie Cifuentes; and recent developments in the
chemistry of the elements of Group 14 - focusing on
low-coordination number compounds by Richard Layfield. This volume
therefore covers many synthetic and applied aspects of modern
organometallic chemistry which ought to be of interest to
inorganic, organic and applied catalysis fields.
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