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Books > Science & Mathematics > Chemistry > Organic chemistry > Organometallic chemistry
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Kinetically Controlled Stepwise Syntheses of a Heterometallic Complex and a Tetrahedral Chiral-at-Metal Complex (Hardcover, 1st ed. 2021)
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Kinetically Controlled Stepwise Syntheses of a Heterometallic Complex and a Tetrahedral Chiral-at-Metal Complex (Hardcover, 1st ed. 2021)
Series: Springer Theses
Expected to ship within 18 - 22 working days
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This book describes novel synthetic methodologies for two kinds of
structurally elaborate metal complexes: a heterometallic complex
and a tetrahedral chiral-at-metal complex. The book provides the
tools and inspiration to chemists for development of metal
complexes with wide structural diversity than had previously been
possible. For each of the two topics, existing synthetic methods
for similar compounds are discussed first, and then new strategies
are presented, followed by the demonstration of the synthesis of
novel compounds supported by experimental results. Both of the
final products in this research, a Co-Ni heterometallic complex
covered in the first topic and a tetrahedral chiral-at-metal
complex in the second one are difficult to obtain by using common
synthetic methods for thermodynamic reasons. This research achieved
highly selective syntheses of these compounds using newly designed
strategies that enable precise kinetic control. Such an approach
will be useful for synthesizing other new metal complexes. Since
the last century, organic chemistry has flourished with the
development of a variety of synthetic techniques that make precise
kinetic control possible. Coordination chemistry of 3d or
main-group transition metals has been mainly based on simple
one-step reactions that yield only thermodynamic products. The
publication of this book helps pave the way to kinetically
controlled precise syntheses of various metal complexes.
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