This book is intended to present for the first time experimental
methods to measure equilibria states of pure and mixed gases being
adsorbed on the surface of solid materials. It has been written for
engineers and scientists from industry and academia who are
interested in adsorption based gas separation processes and/or in
using gas adsorption for characterization of the porosity of solid
materials. This book is the result of a fruitful collaboration of a
theoretician (JUK) and an experimentalist (RS) over more than
twelve years in the field of gas adsorption systems at the
Institute of Fluid- and Thermodynamics (IFT) at the University of
Siegen, Siegen, Germany. This collaboration resulted in the
development of several new methods to measure not only pure gas
adsorption, but gas mixture or coadsorption equilibria on inert
porous solids. Also several new theoretical results could be
achieved leading to new types of so-called adsorption isotherms
based on the concepts of molecular association and -
phenomenologically speaking - on that of thermodynamic phases of
fractal dimension. Naturally, results of international
collaboration of the authors over the years (1980-2000) also are
included.
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