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Energy Storage and Redistribution in Molecules (Paperback, Softcover reprint of the original 1st ed. 1983)
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Energy Storage and Redistribution in Molecules (Paperback, Softcover reprint of the original 1st ed. 1983)
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We characterize an isolated molecule by its compos t on, i.e. the
number and types of atoms forming the molecule, its structure, i.e.
the geometrical arrangement of the composite atoms with respect to
each other, and its possible, i.e. quantum mechanically allowed,
stationary energy states. Conceptually we separate the latter,
being aware that this is an approximation, into electronic,
vibrational and rotational states, including fine and hyperfine
structure splittings. To be sure, there is an intimate relation
between molecular structure and molecular energy states, in fact it
is this relation we use, when we obtain structural information
through spectroscopy, where we determine transitions between
various stationary states of the molecule. The concepts above have
proven extremely useful in chemistry and spectroscopy, however, the
awareness of the limitations of these concepts has grown in recent
years with the increasing recognition of (i) fluctional molecules,
(ii) multiphoton absorption processes and (iii) influences due to
the surroundings on "isolated" molecules.
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