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The Synergy Between Dynamics and Reactivity at Clusters and Surfaces (Paperback, Softcover reprint of the original 1st ed. 1995)
Loot Price: R1,551
Discovery Miles 15 510
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The Synergy Between Dynamics and Reactivity at Clusters and Surfaces (Paperback, Softcover reprint of the original 1st ed. 1995)
Series: NATO Science Series C, 465
Expected to ship within 10 - 15 working days
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The analogy between the chemistry of molecular transition metal
clusters and the processes of chemisorption and catalysis at metal
surfaces (the Cluster Surface analogy) has for a number of years
provided an interplay between experimental and theoretical
inorganic and physical chemists. This collaborative approach has
born fruit in the use of well defined modes of metal-ligand bonding
in discrete molecular clusters, models for metal-ligand binding on
surfaces. Some of the key topics discussed in The Synergy between
Dynamics and Reactivity at Clusters and Surfaces are: (1)
Mechanisms of the fluxional behaviour in clusters in the liquid
phase and the connections with diffusion processes on extended
surfaces. The role of metal-metal bond breaking in diffusion. (2)
Analogies in the structure of chemisorbed species and related
ligands on metallic clusters. (3) Analogies between benzene surface
chemistry on extended metal surfaces and on metal surfaces in
molecular cluster compounds with particular reference to structural
distortions. (4) The role of mobile precursors for dissociation of
chemisorption on extended metals and on clusters. Are there
analogies in the ligand attachment during cluster compound
synthesis? (5) The role of defect sites on metal surfaces in
catalyzing chemical reactions and the connection to the special
bonding properties of sites on metal clusters having lowest
metal-metal coordination. (6) The size of metal clusters needed to
mimic surface phenomena on bulk metal surfaces. Different sites
needed for different phenomena.
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