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Inherently Conducting Polymers - Processing, Fabrication, Applications, Limitations (Hardcover)
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Inherently Conducting Polymers - Processing, Fabrication, Applications, Limitations (Hardcover)
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"From the Forward: "
Processing, fabrication, applications, and limitations of
inherently conducting polymers are covered in this book.
Electrically conducting polymers have many potential applications
and thus are a focus of research interest. Such polymers depend on
a conjugated backbone that can be doped with highly reactive
materials to increase conductivity, but this backbone is also the
source of instability in these materials.
The work described concentrates on solving these instability
problems, using various doping techniques to yield polymers more
stable than polyacetylene, (CH)x, the first extensively
characterized covalent organic polymer. Several methods of
synthesizing conjugated polymers and ways of doping the conjugated
backbone are described. The stability of pristine and doped
polymers is examined in ambient atmosphere and under thermal
treatment, and several stabilization techniques are discussed,
including chemical doping, ion implantation, plastification,
copolymerization, antioxidative treatments, surface protection, and
the use of crown ethers.
Although considerable progress has been made, a fully stable,
highly conductive polymer still awaits development. Various
possible uses of such a polymer and the conditions for successful
applications are described, as are the relative advantages and
disadvantages of currently available polymers.
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